Annex (part 3) to the COMMISSION REGULATION (EU) …/… of XXX amending, for the purposes of its adaptation to technical and scientific progress, Regulation (EC) No 1272/2008 of the European Parliament and of the Council on classification, labelling and packaging of substances and mixtures - Main contents

Document date	26-07-2017
Publication date	27-07-2017
Reference	11526/17 ADD 3
From	European Commission
External link	original article
Original document in PDF

Council of the European Union

Brussels, 26 July 2017 (OR. en)

11526/17 ADD 3

COMPET 561 ENV 700 CHIMIE 71 MI 573 ENT 176

COVER NOTE

From: European Commission

date of receipt: 24 July 2017

To: General Secretariat of the Council

No. Cion doc.: D050725/02 - Annex (part 3)

Subject: Annex (part 3) to the COMMISSION REGULATION (EU) …/… of XXX amending, for the purposes of its adaptation to technical and scientific progress, Regulation (EC) No 1272/2008 of the European Parliament and of the Council on classification, labelling and packaging of substances and mixtures

Delegations will find attached document D050725/02 - Annex (part 3).

Encl.: D050725/02 - Annex (part 3)

D050725/02

Classification Labelling Specific Conc. Limits, M-factors Notes

Index No International Chemical Identification EC No CAS No

Hazard Class and Category Hazard Hazard Suppl. Hazard

Code(s) Statement

Pictogram, Signal

Code(s) Word Code(s)

statement statement Code(s) Code(s)

608-030-00-1 N-acetyl-N-[5-cyano-3-(2- 412-340-0 147741-93-3 Aquatic Acute 1 H400 GHS09 H410 dibutylamino-4-phenylthyazol-5-yl Aquatic Chronic 1 H410 Wng

methylene)-4-methyl-2,6-dioxo 1,2,3,6-tetrahydropyridin-1- yl]benzamide

608-031-00-7 2-benzyl-2-methyl-3-butenitrile 407-870-4 97384-48-0 Acute Tox. 4 * H302 GHS07 H302

Aquatic Chronic 3 H412 Wng H412

608-032-00-2 acetamiprid (ISO);

(E)-N 1 -[(6-chloro-3-pyridyl)methyl]- — 135410-20-7 Acute Tox. 4 * H302 GHS07 H302

1

N 2 -cyano-N -methylacetamidine Aquatic Chronic 3 H412 Wng H412

608-033-00-8 N-butyl-3-(2-chloro-4- 407-970-8 75511-91-0 Skin Sens. 1 H317 GHS07 H317 nitrophenylhydrazono)-1-cyano-2- Aquatic Chronic 3 H412 Wng H412 methylprop-1-ene-1,3-dicarboximide

608-034-00-3 chlorfenapyr (ISO); 4-bromo-2-(4- 122453-73-0 Acute Tox. 3 * H331 GHS06 H331 chlorophenyl)-1-ethoxymethyl-5- — Acute Tox. 4 * H302 GHS09 H302 M=100 trifluoromethylpyrrole-3-carbonitrile Aquatic Acute 1 H400 Dgr H410 Aquatic Chronic 1 H410

608-035-00-9 (±)-α-[(2-acetyl-5-methylphenyl)- 419-290-9 — Skin Sens. 1 H317 GHS07 H317 amino]-2,6-dichlorobenzene-aceto Aquatic Chronic 4 H413 Wng H413 nitrile

608-036-00-4 3-(2-{4-[2-(4- 419-060-8 79026-02-1 Aquatic Chronic 4 H413 — H413 cyanophenyl)vinyl]phenyl}vinyl)ben

zonitrile

608-037-00-X reaction mass of: (E)-2,12- 422-190-8 Aquatic Acute 1 H400 GHS09 H410 tridecadiennitrile; (E)-3,12- Aquatic Chronic 1 H410 Wng

tridecadiennitrile; (Z)-3,12- tridecadiennitrile

364

D050725/02

Classification Labelling Specific Conc. Limits, M-factors Notes

Index No International Chemical Identification EC No CAS No

Hazard Class and Category Hazard Suppl. Hazard

Code(s) Statement

Pictogram, Signal Hazard statement statement

Code(s) Word Code(s) Code(s) Code(s)

608-038-00-5 2,2,4-trimethyl-4-phenyl-butane 422-580-8 75490-39-0 Acute Tox. 4 * H302 GHS07 H302 nitrile Aquatic Chronic 2 H411 GHS09 H411 Wng

608-039-00-0 2-phenylhexanenitrile 423-460-8 3508-98-3 Acute Tox. 4 * H302 GHS07 H302

Aquatic Acute 1 H400 GHS09 H410 Aquatic Chronic 1 H410 Wng

608-040-00-6 4,4'-dithiobis(5-amino-1-(2,6- 423-490-1 130755-46-3 Aquatic Acute 1 H400 GHS09 H410 dichloro-4-(trifluoromethyl)phenyl)- Aquatic Chronic 1 H410 Wng

1H-pyrazole-3-carbonitrile)

608-041-00-1 4'-((2-butyl-4-oxo-1,3- 423-500-4 138401-24-8 Aquatic Acute 1 H400 GHS09 H410 diazaspiro[4.4]non-1-ene-3- Aquatic Chronic 1 H410 Wng

yl)methyl)(1,1'-biphenyl)-2- carbonitrile

608-042-00-7 (S)-2,2-diphenyl-2-(3- 421-810-4 194602-27-2 Acute Tox. 4 * H302 GHS05 H302 pyrrolidinyl)acetonitrile Eye Dam. 1 H318 GHS07 H318 hydrobromide Skin Sens. 1 H317 GHS09 H317 Aquatic Chronic 2 H411 Dgr H411

608-043-00-2 3-(cis-3-hexenyloxy)propanenitril 415-220-6 142653-61-0 Acute Tox. 3 * H331 GHS06 H331

Acute Tox. 4 * H302 GHS09 H302 Aquatic Acute 1 H400 Dgr H410 Aquatic Chronic 1 H410

608-044-00-8 2-cyclohexylidene-2- 423-740-1 10461-98-0 Acute Tox. 4 * H302 GHS07 H302 phenylacetonitrile Aquatic Chronic 2 H411 GHS09 H411 Wng

608-046-00-9 5-(4-chloro-2-nitro-phenylazo)-1,2- 425-310-7 77889-90-8 Aquatic Chronic 4 H413 — H413 dihydro-6-hydroxy-1,4-dimethyl-2-

oxo-pyridine-3-carbonitrile

608-047-00-4 2-piperidin-1-yl-benzonitrile 427-330-1 72752-52-4 Aquatic Chronic 2 H411 GHS09 H411

365

D050725/02

Classification Labelling Specific Conc. Limits, M-factors Notes

Index No International Chemical Identification EC No CAS No

Hazard Class and Category Hazard Suppl. Hazard

Code(s) Statement

Pictogram, Signal Hazard statement statement

Code(s) Word Code(s) Code(s) Code(s)

608-048-00-X 1-(3-cyclopentyloxy-4- 427-450-4 152630-47-2 Acute Tox. 4 * H302 GHS08 H302 methoxyphenyl)-4-oxo STOT RE 2 * H373** GHS07 H373** cyclohexanecarbonitrile Skin Sens. 1 H317 GHS09 H317 Aquatic Chronic 2 H411 Wng H411

608-049-00-5 2-(4-(4-(butyl-(1- 429-180-2 157362-53-3 Skin Sens. 1 H317 GHS07 H317 methylhexyl)amino)phenyl)-3- Aquatic Acute 1 H400 GHS09 H410 cyano-5-oxo-1,5-dihydropyrrol-2- Aquatic Chronic 1 H410 Wng

ylidene)propandinitrile

608-050-00-0 reaction mass of: 5-(2-cyano-4- 429-760-5 — Aquatic Chronic 4 H413 — H413 nitrophenylazo)-2-(2-(2-

hydroxyethoxy)ethylamino)-4- methyl-6- phenylaminonicotinonitrile; 5-(2-cyano-4-nitrophenylazo)-6-(2- (2-hydroxyethoxy)ethylamino)-4- methyl-2-phenylaminonicotinonitrile

608-051-00-6 (R)-4-(4-dimethylamino-1-(4- 430-760-2 219861-18-4 Acute Tox. 4 * H302 GHS07 H302 fluorophenyl)-1-hydroxybutyl)-3- Skin Sens. 1 H317 GHS09 H317 (hydroxymethyl)benzonitrile Aquatic Chronic 2 H411 Wng H411

608-052-00-1 (S)-4-(4-dimethylamino-1-(4- 430-770-7 128173-52-4 Acute Tox. 4 * H302 GHS07 H302 fluorophenyl)-1-hydroxybutyl)-3- Skin Sens. 1 H317 GHS09 H317 (hydroxymethyl)benzonitrile Aquatic Chronic 2 H411 Wng H411

608-053-00-7 (R,S)-4-(4-dimethylamino-1-(4- 430-780-1 103146-25-4 Acute Tox. 4 * H302 GHS07 H302 fluorophenyl)-1-hydroxybutyl)-3- Skin Sens. 1 H317 GHS09 H317 (hydroxymethyl)benzonitrile Aquatic Chronic 2 H411 Wng H411

608-054-00-2 (R,S)-4-(4-dimethylamino-1-(4- 430-790-6 — Acute Tox. 4 * H302 GHS05 H302 fluorophenyl)-1-hydroxybutyl)3- Eye Dam. 1 H318 GHS07 H318 (hydroxymethyl)benzonitrile Skin Sens. 1 H317 GHS09 H317 hemisulfate Aquatic Chronic 2 H411 Dgr H411

366

D050725/02

Classification Labelling Specific Conc. Limits, M-factors Notes

Index No International Chemical Identification EC No CAS No

Hazard Class and Category Hazard Hazard Suppl. Hazard

Code(s) Statement

Pictogram, Signal

Code(s) Word Code(s)

statement statement Code(s) Code(s)

608-056-00-3 N-methyl-N- 429-340-1 — Acute Tox. 4 * H302 GHS05 H302 cyanomethylmorpholiniummethylsul Eye Dam. 1 H318 GHS07 H318 fate Dgr

608-057-00-9 4-(cyanomethyl)-4- 431-200-1 208538-34-5 Acute Tox. 4 * H302 GHS05 H302 methylmorpholin-4-ium hydrogen Eye Dam. 1 H318 GHS07 H318 sulfate Skin Sens. 1 H317 Dgr H317

608-058-00-4 esfenvalerate (ISO); — 66230-04-4 Acute Tox. 3 * H331 GHS06 H331 M = 10000

(S)-α-cyano-3-phenoxybenzyl-(S)-2- Acute Tox. 3 * H301 GHS09 H301 (4-chlorophenyl)-3-methylbutyrate Skin Sens. 1 H317 Dgr H317 Aquatic Acute 1 H400 H410 Aquatic Chronic 1 H410

608-059-00-X 5-amino-1-(2,6-dichloro-4- 421-240-6 120068-79-3 Aquatic Chronic 2 H411 GHS09 H411

(trifluoromethyl)phenyl)-1H- pyrazole-3-carbonitrile

608-060-00-5 5-methyl-2-[(2-nitrophenyl)amino]- 421-300-1 138564-59-7 Aquatic Acute 1 H400 GHS09 H410

3-thiophenecarbonitrile Aquatic Chronic 1 H410 Wng

608-062-00-6 2-fluoro-4-hydroxybenzonitrile 422-810-7 82380-18-5 Acute Tox. 4 * H302 GHS05 H302

Eye Dam. 1 H318 GHS07 H318 Aquatic Chronic 2 H411 GHS09 H411 Dgr

608-063-00-1 (S)-α-hydroxy-3-phenoxy 441-070-6 61826-76-4 Acute Tox. 3 * H301 GHS06 H301 benzeneacetonitrile Eye Dam. 1 H318 GHS05 H318 Skin Sens. 1 H317 GHS09 H317 Aquatic Acute 1 H400 Dgr H410 Aquatic Chronic 1 H410

367

D050725/02

Classification Labelling Specific Conc. Limits, M-factors Notes

Index No International Chemical Identification EC No CAS No

Hazard Class and Category Hazard Pictogram, Signal Hazard Suppl. Hazard

Code(s) Statement statement Code(s) Word Code(s) statement Code(s) Code(s)

608-064-00-7 cyanomethyltrimethylammoniummet 433-720-2 — Aquatic Chronic 3 H412 — H412 hylsulfate

608-065-00-2 salts of bromoxynil with the Repr. 2 H361d *** GHS06 H361d *** M = 10 A exception of those specified — — Acute Tox. 2 * H330 GHS08 H330

elsewhere in this Annex Acute Tox. 3 * H301 GHS09 H301 Skin Sens. 1 H317 Dgr H317 Aquatic Acute 1 H400 H410 Aquatic Chronic 1 H410

608-066-00-8 salts of ioxynil with the exception of — — Repr. 2 H361d *** GHS06 H361d *** M = 10 A those specified elsewhere in this Acute Tox. 3 * H331 GHS08 H331

Annex Acute Tox. 3 * H301 GHS09 H301 Acute Tox. 4 * H312 Dgr H312 STOT RE 2 * H373 ** H373 ** Eye Irrit. 2 H319 H319 Aquatic Acute 1 H400 H410 Aquatic Chronic 1 H410

H *

609-001-00-6 1-nitropropane 203-544-9 108-03-2 Flam. Liq. 3 H226 GHS02 226

Acute Tox. 4 * H332 GHS07 H332 Acute Tox. 4 * H312 Wng H312 Acute Tox. 4 * H302 H302

609-002-00-1 2-nitropropane 201-209-1 79-46-9 Flam. Liq. 3 H226 GHS02 H226

Carc. 1B H350 GHS08 H350 Acute Tox. 4 * H332 GHS07 H332 Acute Tox. 4 * H302 Dgr H302

609-003-00-7 nitrobenzene 202-716-0 98-95-3 Carc. 2. Repr. 1B H351 GHS06 H351

Acute Tox. 3 H360F GHS08 H360F Acute Tox. 3 H301 Dgr H301 Acute Tox. 3 H331 H331 STOT RE 1 H311 H311 Aquatic Chronic 3 H372 (blood) H372 (blood) H412 H412

368

D050725/02

Classification Labelling Specific Conc. Limits, M-factors Notes

Index No International Chemical Identification EC No CAS No

Hazard Class and Category Hazard Hazard Suppl. Hazard

Code(s) Statement

Pictogram, Signal statement statement

Code(s) Word Code(s) Code(s) Code(s)

609-004-00-2 dinitrobenzene; [1] 246-673-6 [1] 25154-54-5 [1] Acute Tox. 2 * H330 GHS06 H330

1,4-dinitrobenzene; [2] 202-833-7 [2] 100-25-4 [2] Acute Tox. 1 H310 GHS08 H310 1,3-dinitrobenzene; [3] 202-776-8 [3] 99-65-0 [3] Acute Tox. 2 * H300 GHS09 H300 1,2-dinitrobenzene [4] 208-431-8 [4] 528-29-0 [4] STOT RE 2 * H373 ** Dgr H373 ** Aquatic Acute 1 H400 H410 Aquatic Chronic 1 H410

609-005-00-8 1,3,5-trinitrobenzene 202-752-7 99-35-4 Expl. 1.1 H201 GHS01 H201

Acute Tox. 2 * H330 GHS06 H330 Acute Tox. 1 H310 GHS08 H310 Acute Tox. 2 * H300 GHS09 H300 STOT RE 2 H373** Dgr H373** Aquatic Acute 1 H400 H410 Aquatic Chronic 1 H410

609-006-00-3 4-nitrotoluene 202-808-0 99-99-0 Acute Tox. 3 * H331 GHS06 H331

Acute Tox. 3 * H311 GHS08 H311 Acute Tox. 3 * H301 GHS09 H301 STOT RE 2 * H373 ** Dgr H373 ** Aquatic Chronic 2 H411 H411

609-007-00-9 2,4-dinitrotoluene; [1] 204-450-0 [1] 121-14-2 [1] Carc. 1B H350 GHS06 H350 dinitrotoluene [2] 246-836-1 [2] 25321-14-6 [2] Muta. 2 H341 GHS08 H341 Repr. 2 H361f*** GHS09 H361f*** Acute Tox. 3 * H331 Dgr H331 Acute Tox. 3 * H311 H311 Acute Tox. 3 * H301 H301 STOT RE 2 * H373** H373** Aquatic Acute 1 H400 H410 Aquatic Chronic 1 H410

369

D050725/02

Classification Labelling Specific Conc. Limits, M-factors Notes

Index No International Chemical Identification EC No CAS No

Hazard Class and Category Hazard Suppl. Hazard

Code(s) Statement

Pictogram, Signal Hazard statement statement

Code(s) Word Code(s) Code(s) Code(s)

609-008-00-4 2,4,6-trinitrotoluene; TNT 204-289-6 118-96-7 Expl. 1.1 H201 GHS01 H201

Acute Tox. 3 * H331 GHS06 H331 Acute Tox. 3 * H311 GHS08 H311 Acute Tox. 3 * H301 GHS09 H301 STOT RE 2 * H373 ** Dgr H373 ** Aquatic Chronic 2 H411 H411

609-009-00-X 2,4,6-trinitrophenol; 201-865-9 88-89-1 Expl. 1.1 H201 GHS01 H201 picric acid Acute Tox. 3 * H331 GHS06 H331 Acute Tox. 3 * H311 Dgr H311 Acute Tox. 3 * H301 H301

609-010-00-5 salts of picric acid — — Unst. Expl H201 GHS01 H201 T

Acute Tox. 3 * H331 GHS06 H331 Acute Tox. 3 * H311 Dgr H311 Acute Tox. 3 * H301 H301

609-011-00-0 2,4,6-trinitroanisole — 606-35-9 Expl. 1.1 H201 GHS01 H201

Acute Tox. 4 * H332 GHS07 H332 Acute Tox. 4 * H312 GHS09 H312 Acute Tox. 4 * H302 Wng H302 Aquatic Chronic 2 H411 H411

609-012-00-6 2,4,6-trinitro-m-cresol 210-027-1 602-99-3 Expl. 1.1 H201 GHS01 H201

Acute Tox. 4 * H332 GHS07 H332 Acute Tox. 4 * H312 Wng H312 Acute Tox. 4 * H302 H302

609-013-00-1 2,4,6-trinitro-m-xylene 211-187-5 632-92-8 Expl. 1.1 H201 GHS01 H201

Acute Tox. 4 * H332 GHS08 H332 Acute Tox. 4 * H312 GHS07 H312 Acute Tox. 4 * H302 Wng H302 STOT RE 2 * H373 ** H373 **

370

D050725/02

Classification Labelling Specific Conc. Limits, M-factors Notes

Index No International Chemical Identification EC No CAS No

Hazard Class and Category Hazard Hazard Suppl. Hazard

Code(s) Statement

Pictogram, Signal statement statement

Code(s) Word Code(s) Code(s) Code(s)

609-015-00-2 4-nitrophenol; 202-811-7 100-02-7 Acute Tox. 4 * H332 GHS08 H332 p-nitrophenol Acute Tox. 4 * H312 GHS07 H312 Acute Tox. 4 * H302 Wng H302 STOT RE 2 * H373 ** H373 **

609-016-00-8 dinitrophenol (reaction mass of 247-096-2 [1] 25550-58-7 [1] Acute Tox. 3 * H331 GHS06 H331 isomers); [1] 275-732-9 [2] 71629-74-8 [2] Acute Tox. 3 * H311 GHS08 H311 2,4(or 2,6)-dinitrophenol [2] Acute Tox. 3 * H301 GHS09 H301 STOT RE 2 * H373 ** Dgr H373 ** Aquatic Acute 1 H400 H410 Aquatic Chronic 1 H410

609-018-00-9 2,4,6-trinitroresorcinol; 201-436-6 82-71-3 Expl. 1.1 H201 GHS01 H201 styphnic acid Acute Tox. 4 * H332 GHS07 H332 Acute Tox. 4 * H312 Dgr H312 Acute Tox. 4 * H302 H302

lead 2,4,6-trinitro-m-phenylene dioxide; lead 2,4,6-

609-019-00-4 trinitroresorcinoxide; 239-290-0 15245-44-0 Unst. Expl H200 GHS01 H200 1 lead styphnate Repr. 1A H360Df GHS08 H360Df

Acute Tox. 4 * H332 GHS07 H332 Acute Tox. 4 * H302 GHS09 H302 STOT RE 2 * H373 ** Dgr H373 ** Aquatic Acute 1 H400 H410 Aquatic Chronic 1 H410

dioxide; Repr. 1A H360Df GHS08 H360Df lead 2,4,6-trinitroresorcinoxide; Acute Tox. 4 * H332 GHS07 H332 lead styphnate (≥ 20% phlegmatiser) Acute Tox. 4 * H302 GHS09 H302 STOT RE 2 * H373 ** Dgr H373 ** Aquatic Acute 1 H400 H410 Aquatic Chronic 1 H410

371

D050725/02

Classification Labelling Specific Conc. Limits, M-factors Notes

Index No International Chemical Identification EC No CAS No

Hazard Class and Category Hazard Suppl. Hazard

Code(s) Statement

Pictogram, Signal Hazard statement statement

Code(s) Word Code(s) Code(s) Code(s)

609-020-00-X DNOC (ISO); 208-601-1 534-52-1 Muta. 2 H341 GHS06 H341 EUH044

4,6-dinitro-o-cresol Acute Tox. 2 * H330 GHS08 H330 Acute Tox. 1 H310 GHS05 H310 Acute Tox. 2 * H300 GHS07 H300 Skin Irrit. 2 H315 GHS09 H315 Eye Dam. 1 H318 Dgr H318 Skin Sens. 1 H317 H317 Aquatic Acute 1 H400 H410 Aquatic Chronic 1 H410

609-021-00-5 sodium salt of DNOC; 219-007-7 [1] 2312-76-7 [1] Acute Tox. 3 * H331 GHS06 H331 sodium 4,6-dinitro-o-cresolate; [1] -[2] 5787-96-2 [2] Acute Tox. 3 * H311 GHS08 H311 potassium salt of DNOC; potassium Acute Tox. 3 * H301 GHS09 H301 4,6-dinitro-o-cresolate [2] STOT RE 2 * H373 ** Dgr H373 ** Aquatic Acute 1 H400 H410 Aquatic Chronic 1 H410

609-022-00-0 ammonium salt of DNOC; 221-037-0 2980-64-5 Acute Tox. 2 * H330 GHS06 H330 ammonium 4,6-dinitro-o-tolyl oxide Acute Tox. 1 H310 GHS08 H310 Acute Tox. 2 * H300 GHS09 H300 STOT RE 2 * H373 ** Dgr H373 ** Aquatic Acute 1 H400 H410 Aquatic Chronic 1 H410

609-023-00-6 dinocap (ISO); 254-408-0 39300-45-3 Repr. 1B H360D*** GHS08 H360D*** M=100

(RS)-2,6-dinitro-4-octylphenyl Acute Tox. 4 * H332 GHS07 H332 crotonates and (RS)-2,4-dinitro-6- Acute Tox. 4 * H302 GHS09 H302 octylphenyl crotonates in which STOT RE 2 * H373** Dgr H373** " octyl" is a reaction mass of 1- Skin Irrit. 2 H315 H315 methylheptyl, 1-ethylhexyl and 1- Skin Sens. 1 H317 H317 propylpentyl groups Aquatic Acute 1 H400 H410 Aquatic Chronic 1 H410

372

D050725/02

Classification Labelling Specific Conc. Limits, M-factors Notes

Index No International Chemical Identification EC No CAS No

Hazard Class and Category Hazard Hazard Suppl. Hazard

Code(s) Statement

Pictogram, Signal statement statement

Code(s) Word Code(s) Code(s) Code(s)

609-024-00-1 binapacryl (ISO); 207-612-9 485-31-4 Repr. 1B H360D *** GHS08 H360D ***

2-sec-butyl-4,6-dinitrophenyl-3- Acute Tox. 4 * H312 GHS07 H312 methylcrotonate Acute Tox. 4 * H302 GHS09 H302 Aquatic Acute 1 H400 Dgr H410 Aquatic Chronic 1 H410

609-025-00-7 dinoseb (ISO); 201-861-7 88-85-7 Repr. 1B H360Df GHS06 H360Df EUH044

6-sec-butyl-2,4-dinitrophenol Acute Tox. 3 * H311 GHS08 H311 Acute Tox. 3 * H301 GHS09 H301 Eye Irrit. 2 H319 Dgr H319 Aquatic Acute 1 H400 H410 Aquatic Chronic 1 H410

609-026-00-2 salts and esters of dinoseb, with the — — Repr. 1B H360Df GHS06 H360Df EUH044 A exception of those specified Acute Tox. 3 * H311 GHS08 H311

elsewhere in this Annex Acute Tox. 3 * H301 GHS09 H301 Eye Irrit. 2 H319 Dgr H319 Aquatic Acute 1 H400 H410 Aquatic Chronic 1 H410

609-027-00-8 dinocton; — 63919-26-6 Acute Tox. 4 * H302 GHS07 H302 reaction mass of isomers: Aquatic Acute 1 H400 GHS09 H410 methyl 2-octyl-4,6-dinitrophenyl Aquatic Chronic 1 H410 Wng

carbonate, methyl 4-octyl-2,6- dinitrophenyl carbonate

609-028-00-3 dinex (ISO); 205-042-5 131-89-5 Acute Tox. 3 * H331 GHS06 H331

2-cyclohexyl-4,6-dinitrophenol Acute Tox. 3 * H311 GHS09 H311 Acute Tox. 3 * H301 Dgr H301 Aquatic Acute 1 H400 H410 Aquatic Chronic 1 H410

373

D050725/02

Classification Labelling Specific Conc. Limits, M-factors Notes

Index No International Chemical Identification EC No CAS No

Hazard Class and Category Hazard Suppl. Hazard

Code(s) Statement

Pictogram, Signal Hazard statement statement

Code(s) Word Code(s) Code(s) Code(s)

609-029-00-9 salts and esters of dinex — — Acute Tox. 3 * H331 GHS06 H331 A

Acute Tox. 3 * H311 GHS09 H311 Acute Tox. 3 * H301 Dgr H301 Aquatic Acute 1 H400 H410 Aquatic Chronic 1 H410

609-030-00-4 dinoterb (ISO); 215-813-8 1420-07-1 Repr. 1B H360D *** GHS06 H360D *** EUH044

2-tert-butyl-4,6-dinitrophenol Acute Tox. 2 * H300 GHS08 H300 Acute Tox. 3 * H311 GHS09 H311 Aquatic Acute 1 H400 Dgr H410 Aquatic Chronic 1 H410

609-031-00-X salts and esters of dinoterb — — Repr. 1B H360D *** GHS06 H360D *** A

Acute Tox. 2 * H300 GHS08 H300 Acute Tox. 3 * H311 GHS09 H311 Aquatic Acute 1 H400 Dgr H410 Aquatic Chronic 1 H410

609-032-00-5 bromofenoxim (ISO); 236-129-6 13181-17-4 Acute Tox. 4 * H302 GHS07 H302

3,5-dibromo-4- Aquatic Acute 1 H400 GHS09 H410 hydroxybenzaldehyde-O-(2,4- Aquatic Chronic 1 H410 Wng

dinitrophenyl)-oxime

609-033-00-0 dinosam (ISO); — 4097-36-3 Acute Tox. 3 * H331 GHS06 H331

2-(1-methylbutyl)-4,6-dinitrophenol Acute Tox. 3 * H311 GHS09 H311

Acute Tox. 3 * H301 Dgr H301 Aquatic Acute 1 H400 H410 Aquatic Chronic 1 H410

609-034-00-6 salts and esters of dinosam — — Acute Tox. 3 * H331 GHS06 H331 A

Acute Tox. 3 * H311 GHS09 H311 Acute Tox. 3 * H301 Dgr H301 Aquatic Acute 1 H400 H410 Aquatic Chronic 1 H410

374

D050725/02

Classification Labelling Specific Conc. Limits, M-factors Notes

Index No International Chemical Identification EC No CAS No

Hazard Class and Category Hazard Pictogram, Signal Hazard Suppl. Hazard

Code(s) Statement statement statement Code(s) Word Code(s) Code(s) Code(s)

609-035-00-1 nitroethane 201-188-9 79-24-3 Flam. Liq. 3 H226 GHS02 H226 *

Acute Tox. 4 * H332 GHS07 H332 Acute Tox. 4 * H302 Wng H302

609-036-00-7 nitromethane 200-876-6 75-52-5 Flam. Liq. 3 H226 GHS02 H226 *

Acute Tox. 4 * H302 GHS07 H302 Wng

609-037-00-2 5-nitroacenaphthene 210-025-0 602-87-9 Carc. 1B H350 GHS08 H350

Dgr

609-038-00-8 2-nitronaphthalene 209-474-5 581-89-5 Carc. 1B H350 GHS08 H350

Aquatic Chronic 2 H411 GHS09 H411 Dgr

609-039-00-3 4-nitrobiphenyl 202-204-7 92-93-3 Carc. 1B H350 GHS08 H350

Aquatic Chronic 2 H411 GHS09 H411 Dgr

609-040-00-9 nitrofen (ISO); 217-406-0 1836-75-5 Carc. 1B H350 GHS08 H350

2,4-dichlorophenyl 4-nitrophenyl Repr. 1B H360D *** GHS07 H360D *** ether Acute Tox. 4 * H302 GHS09 H302 Aquatic Acute 1 H400 Dgr H410 Aquatic Chronic 1 H410

609-041-00-4 2,4-dinitrophenol 200-087-7 51-28-5 Acute Tox. 3 * H331 GHS06 H331

Acute Tox. 3 * H311 GHS08 H311 Acute Tox. 3 * H301 GHS09 H301 STOT RE 2 * H373 ** Dgr H373 ** Aquatic Acute 1 H400 H400

609-042-00-X pendimethalin (ISO); 254-938-2 40487-42-1 Skin Sens. 1 H317 GHS07 H317

N-(1-ethylpropyl)-2,6-dinitro-3,4- Aquatic Acute 1 H400 GHS09 H410 xylidine Aquatic Chronic 1 H410 Wng

609-043-00-5 quintozene (ISO); 201-435-0 82-68-8 Skin Sens. 1 H317 GHS07 H317 pentachloronitrobenzene Aquatic Acute 1 H400 GHS09 H410 Aquatic Chronic 1 H410 Wng

375

D050725/02

Classification Labelling Specific Conc. Limits, M-factors Notes

Index No International Chemical Identification EC No CAS No

Hazard Class and Category Hazard Hazard Suppl. Hazard

Code(s) Statement

Pictogram, Signal statement statement

Code(s) Word Code(s) Code(s) Code(s)

609-044-00-0 tecnazene (ISO); 204-178-2 117-18-0 Acute Tox. 4 * H302 GHS07 H302

1,2,4,5-tetrachloro-3-nitrobenzene Skin Sens. 1 H317 GHS09 H317 Aquatic Acute 1 H400 Wng H410 Aquatic Chronic 1 H410

609-045-00-6 reaction mass of: 4,6-dinitro-2-(3- — 8069-76-9 Acute Tox. 4 * H302 GHS07 H302 octyl)phenyl methyl carbonate and Aquatic Acute 1 H400 GHS09 H410 4,6-dinitro-2-(4-octyl)phenyl methyl Aquatic Chronic 1 H410 Wng

carbonate; dinocton-6

609-046-00-1 trifluralin (ISO) (containing <0.5 216-428-8 1582-09-8 Carc. 2 H351 GHS08 H351 M=10 ppm NPDA); Skin Sens. 1 H317 GHS07 H317

α, α, α-trifluoro-2,6-dinitro-N,N- Aquatic Acute 1 H400 GHS09 H410 dipropyl-p-toluidine (containing Aquatic Chronic 1 H410 Wng < 0,5 ppm NPDA); 2,6-dinitro-N,N-dipropyl-4- trifluoromethylaniline (containing < 0,5 ppm NPDA); N,N-dipropyl-2,6-dinitro-4- trifluoromethylaniline (containing < 0.5 ppm NPDA)

609-047-00-7 2-nitroanisole 202-052-1 91-23-6 Carc. 1B H350 GHS08 H350

Acute Tox. 4 * H302 GHS07 H302 Dgr

609-048-00-2 sodium 3-nitrobenzenesulphonate 204-857-3 127-68-4 Eye Irrit. 2 H319 GHS07 H319

Skin Sens. 1 H317 Wng H317

609-049-00-8 2,6-dinitrotoluene 210-106-0 606-20-2 Carc. 1B H350 GHS06 H350

Muta. 2 H341 GHS08 H341 Repr. 2 H361f *** Dgr H361f *** Acute Tox. 3 * H331 H331 Acute Tox. 3 * H311 H311 Acute Tox. 3 * H301 H301 STOT RE 2 * H373 ** H373 ** Aquatic Chronic 3 H412 H412

376

D050725/02

Classification Labelling Specific Conc. Limits, M-factors Notes

Index No International Chemical Identification EC No CAS No

Hazard Class and Category Hazard Hazard Suppl. Hazard

Code(s) Statement

Pictogram, Signal statement statement

Code(s) Word Code(s) Code(s) Code(s)

609-050-00-3 2,3-dinitrotoluene 210-013-5 602-01-7 Carc. 1B H350 GHS06 H350

Muta. 2 H341 GHS08 H341 Repr. 2 H361f *** GHS09 H361f *** Acute Tox. 3 * H331 Dgr H331 Acute Tox. 3 * H311 H311 Acute Tox. 3 * H301 H301 STOT RE 2 * H373 ** H373 ** Aquatic Acute 1 H400 H410 Aquatic Chronic 1 H410

609-051-00-9 3,4-dinitrotoluene 210-222-1 610-39-9 Carc. 1B H350 GHS06 H350

Muta. 2 H341 GHS08 H341 Repr. 2 H361f *** GHS09 H361f *** Acute Tox. 3 * H331 Dgr H331 Acute Tox. 3 * H311 H311 Acute Tox. 3 * H301 H301 STOT RE 2 * H373 ** H373 ** Aquatic Chronic 2 H411 H411

609-052-00-4 3,5-dinitrotoluene 210-566-2 618-85-9 Carc. 1B H350 GHS06 H350

Muta. 2 H341 GHS08 H341 Repr. 2 H361f *** Dgr H361f *** Acute Tox. 3 * H331 H331 Acute Tox. 3 * H311 H311 Acute Tox. 3 * H301 H301 STOT RE 2 * H373 ** H373 ** Aquatic Chronic 3 H412 H412

609-053-00-X hydrazine-trinitromethane 414-850-9 — Expl. 1.1 **** H201 GHS01 H201

Self-react. A H240 GHS06 H240 Carc. 1B H350 GHS08 H350 Acute Tox. 3 * H331 Dgr H331 Acute Tox. 3 * H301 H301 Skin Sens. 1 H317 H317

377

D050725/02

Classification Labelling Specific Conc. Limits, M-factors Notes

Index No International Chemical Identification EC No CAS No

Hazard Class and Category Hazard Hazard Suppl. Hazard

Code(s) Statement

Pictogram, Signal

Code(s) Word Code(s)

statement statement Code(s) Code(s)

609-054-00-5 2,3-dinitrophenol; [1] 200-628-7 [1] 66-56-8 [1] Acute Tox. 3 * H331 GHS06 H331

2,5-dinitrophenol; [2] 206-348-1 [2] 329-71-5 [2] Acute Tox. 3 * H311 GHS08 H311 2,6-dinitrophenol; [3] 209-357-9 [3] 573-56-8 [3] Acute Tox. 3 * H301 GHS09 H301 3,4-dinitrophenol; [4] 209-415-3 [4]-[5] 577-71-9 [4]-[5] STOT RE 2 * H373 ** Dgr H373 ** salts of dinitrophenol [5] Aquatic Chronic 2 H411 H411

609-055-00-0 2,5-dinitrotoluene 210-581-4 619-15-8 Carc. 1B Muta. 2 H350 GHS06 H350

Repr. 2 H341 GHS08 H341 Acute Tox. 3 * H361f *** GHS09 H361f *** Acute Tox. 3 * H331 Dgr H331 Acute Tox. 3 * H311 H311 STOT RE 2 * H301 H301 Aquatic Chronic 2 H373 ** H373 ** H411 H411

609-056-00-6 2,2-dibromo-2-nitroethanol 412-380-9 69094-18-4 Expl. 1.1 H201 GHS01 H201 * T

Carc. 2 H351 GHS08 H351 STOT SE 3; H335: Acute Tox. 4 * H302 GHS05 H302 C ≥ 1 % STOT RE 2 * H373 ** GHS07 H373 ** Skin Corr. 1A H314 GHS09 H314 Skin Sens. 1 H317 Dgr H317 Aquatic Acute 1 H400 H410 Aquatic Chronic 1 H410

609-057-00-1 3-chloro-2,4-difluoronitrobenzene 411-980-8 3847-58-3 Acute Tox. 4 * H302 GHS05 H302

Skin Corr. 1B H314 GHS07 H314 Skin Sens. 1 H317 GHS09 H317 Aquatic Acute 1 H400 Dgr H410 Aquatic Chronic 1 H410

609-058-00-7 2-nitro-2-phenyl-1,3-propanediol 410-360-4 5428-02-4 STOT RE 1 H372 ** GHS08 H372 ** EUH070

Acute Tox. 4 * H312 GHS07 H312 Acute Tox. 4 * H302 GHS09 H302 Skin Sens. 1 H317 Dgr H317 Aquatic Chronic 2 H411 H411

609-059-00-2 2-chloro-6-(ethylamino)-4- 411-440-1 131657-78-8 Acute Tox. 4 * H302 GHS07 H302 nitrophenol Skin Sens. 1 H317 GHS09 H317 Aquatic Chronic 2 H411 Wng H411

378

D050725/02

Classification Labelling Specific Conc. Limits, M-factors Notes

Index No International Chemical Identification EC No CAS No

Hazard Class and Category Hazard Pictogram, Signal Hazard Suppl. Hazard

Code(s) Statement statement Code(s) Word Code(s) statement Code(s) Code(s)

609-060-00-8 4-[(3-hydroxypropyl)amino]-3- 406-305-9 92952-81-3 Skin Irrit. 2 H315 GHS07 H315 nitrophenol Aquatic Chronic 2 H411 GHS09 H411 Wng

609-061-00-3 (E,Z)-4- 406-100-4 94097-88-8 Skin Sens. 1 H317 GHS07 H317 chlorophenyl(cyclopropyl)ketone O- Aquatic Acute 1 H400 GHS09 H410 (4-nitrophenylmethyl)oxime Aquatic Chronic 1 H410 Wng

609-062-00-9 2-bromo-2-nitropropanol 407-030-7 24403-04-1 Acute Tox. 3 * H311 GHS06 H311

Acute Tox. 4 * H302 GHS08 H302 STOT RE 2 * H373 ** GHS05 H373 ** Skin Corr. 1B H314 GHS09 H314 Skin Sens. 1 H317 Dgr H317 Aquatic Acute 1 H400 H410 Aquatic Chronic 1 H410

609-063-00-4 2-[(4-chloro-2- 413-280-8 59320-13-7 Acute Tox. 4 * H302 GHS07 H302 nitrophenyl)amino]ethanol Aquatic Chronic 2 H411 GHS09 H411 Wng

609-064-00-X mesotrione(ISO); — 104206-82-8 Aquatic Acute 1 H400 GHS09 H410

2-[4-(methylsulfonyl)-2- Aquatic Chronic 1 H410 Wng nitrobenzoyl]-1,3-cyclohexanedione

609-065-00-5 2-nitrotoluene 201-853-3 88-72-2 Carc. 1B H350 GHS08 H350

Muta. 1B H340 GHS07 H340 Repr. 2 H361f *** GHS09 H361f *** Acute Tox. 4 * H302 Dgr H302 Aquatic Chronic 2 H411 H411

609-066-00-0 lithium sodium 3-amino-10-{4-(10- 418-870-9 154212-58-5 Acute Tox. 4 * H332 GHS08 H332 amino-6,13-dichloro-4,11- Acute Tox. 4 * H312 GHS07 H312 disulfonatobenzo[5,6][1,4]oxazino[2, Acute Tox. 4 * H302 Dgr H302 3-b]phenoxazine-3-ylamino)-6- STOT SE 2 ** H371 ** H371 ** [methyl(2-sulfonato-ethyl)amino]-

1,3,5-triazin-2-ylamino}-6,13- dichlorobenzo[5,6][1,4]oxazino[2,3- b]phenoxazine-4,11-disulfonate

379

D050725/02

Classification Labelling Specific Conc. Limits, M-factors Notes

Index No International Chemical Identification EC No CAS No

Hazard Class and Category Hazard Pictogram, Signal Hazard Suppl. Hazard

Code(s) Statement Code(s) Word Code(s) statement statement Code(s) Code(s)

609-067-00-6 sodium and potassium 4-(3- 416-280-6 156769-97-0 Skin Sens. 1 H317 GHS07 H317 aminopropylamino)-2,6-bis[3(4- Wng

methoxy-2-sulfophenylazo)4- hydroxy-2-sulfo-7-naphthylamino]- 1,3,5-triazine

609-068-00-1 musk xylene; 201-329-4 81-15-2 Expl. 1.1 H201 GHS01 H201 T

5-tert-butyl-2,4,6-trinitro-m-xylene Carc. 2 H351 GHS08 H351 Aquatic Acute 1 H400 GHS09 H410 Aquatic Chronic 1 H410 Wng

609-069-00-7 musk ketone; 201-328-9 81-14-1 Carc. 2 H351 GHS08 H351

3,5-dinitro-2,6-dimethyl-4-tert- Aquatic Acute 1 H400 GHS09 H410 butylacetophenone; Aquatic Chronic 1 H410 Wng 4'-tert-butyl-2', 6'-dimethyl-3', 5'-dinitroacetophenone

609-070-00-2 1,4-dichloro-2-(1,1,2,3,3,3- 415-580-4 130841-23-5 Acute Tox. 4 * H302 GHS07 H302 hexafluoropropoxy)-5-nitrobenzene Skin Sens. 1 H317 GHS09 H317 Aquatic Acute 1 H400 Wng H410 Aquatic Chronic 1 H410

609-071-00-8 reaction mass of: 2-methylsulfanyl 423-520-3 156137-33-6 Skin Sens. 1 H317 GHS07 H317

4,6-bis-(2-hydroxy-4-methoxy Wng phenyl)-1,3,5-triazine; 2-(4,6-bis-methylsulfanyl-1,3,5- triazin-2-yl)-5-methoxy-phenol

609-072-00-3 4-mesyl-2-nitrotoluene 430-550-0 1671-49-4 Repr. 2 H361f*** GHS08 H361f***

Acute Tox. 4 * H302 GHS07 H302 Skin Sens. 1 H317 Wng H317 Aquatic Chronic 3 H412 H412

380

D050725/02

Classification Labelling Specific Conc. Limits, M-factors Notes

Index No International Chemical Identification EC No CAS No

Hazard Class and Category Hazard Pictogram, Signal Hazard Suppl. Hazard

Code(s) Statement statement statement Code(s) Word Code(s) Code(s) Code(s)

609-073-00-9 lithium potassium sodium N,N''- 427-850-9 — Skin Sens. 1 H317 GHS07 H317 bis{6-[7-[4-(4-chloro-1,3,5-triazin-2- Wng

yl)amino-4-(2- ureidophenylazo)]naphthalene-1,3,6- trisulfonato}-N'-(2- aminoethyl)piperazine

610-001-00-3 trichloronitromethane; 200-930-9 76-06-2 Acute Tox. 2 * H330 GHS06 H330 chloropicrin Acute Tox. 4 * H302 Dgr H302 Eye Irrit. 2 H319 H319 STOT SE 3 H335 H335 Skin Irrit. 2 H315 H315

610-002-00-9 1,1-dichloro-1-nitroethane 209-854-0 594-72-9 Acute Tox. 3 * H331 GHS06 H331

Acute Tox. 3 * H311 Dgr H311 Acute Tox. 3 * H301 H301

610-003-00-4 chlorodinitrobenzene — — Acute Tox. 3 * H331 GHS06 H331 C

Acute Tox. 3 * H311 GHS08 H311 Acute Tox. 3 * H301 GHS09 H301 STOT RE 2 * H373 ** Dgr H373 ** Aquatic Acute 1 H400 H410 Aquatic Chronic 1 H410

610-004-00-X 2-chloro-1,3,5-trinitrobenzene 201-864-3 88-88-0 Expl. 1.1 H201 GHS01 H201

Acute Tox. 2 * H330 GHS06 H330 Acute Tox. 1 H310 GHS09 H310 Acute Tox. 2 * H300 Dgr H300 Aquatic Acute 1 H400 H410 Aquatic Chronic 1 H410

381

D050725/02

Classification Labelling Specific Conc. Limits, M-factors Notes

Index No International Chemical Identification EC No CAS No

Hazard Class and Category Hazard Hazard Suppl. Hazard

Code(s) Statement

Pictogram, Signal statement statement

Code(s) Word Code(s) Code(s) Code(s)

610-005-00-5 1-chloro-4-nitrobenzene 202-809-6 100-00-5 Carc. 2 H351 GHS06 H351

Muta. 2 H341 GHS08 H341 Acute Tox. 3 * H331 GHS09 H331 Acute Tox. 3 * H311 Dgr H311 Acute Tox. 3 * H301 H301 STOT RE 2 * H373 ** H373 ** Aquatic Chronic 2 H411 H411

610-006-00-0 chloronitroanilines with the — — Acute Tox. 2 * H330 GHS06 H330 A C exception of those specified Acute Tox. 1 H310 GHS08 H310

elsewhere in this Annex Acute Tox. 2 * H300 GHS09 H300 STOT RE 2 * H373 ** Dgr H373 ** Aquatic Chronic 2 H411 H411

610-007-00-6 1-chloro-1-nitropropane 209-990-0 600-25-9 Acute Tox. 4 * H332 GHS07 H332 *

Acute Tox. 4 * H302 Wng H302

610-008-00-1 2,6-dichloro-4-nitroanisole 403-350-6 17742-69-7 Acute Tox. 3 * H301 GHS06 H301

Aquatic Chronic 2 H411 GHS09 H411 Dgr

610-009-00-7 2-chloro-4-nitroaniline 204-502-2 121-87-9 Acute Tox. 4 * H302 GHS07 H302

Aquatic Chronic 2 H411 GHS09 H411 Wng

610-010-00-2 2-bromo-1-(2-furyl)-2-nitroethylene 406-110-9 35950-52-8 Acute Tox. 4 * H302 GHS08 H302

STOT RE 2 * H373 ** GHS05 H373 ** Skin Corr. 1B H314 GHS07 H314 Skin Sens. 1 H317 GHS09 H317 Aquatic Acute 1 H400 Dgr H410 Aquatic Chronic 1 H410

382

D050725/02

Classification Labelling Specific Conc. Limits, M-factors Notes

Index No International Chemical Identification EC No CAS No

Hazard Class and Category Hazard Hazard Suppl. Hazard

Code(s) Statement

Pictogram, Signal statement statement

Code(s) Word Code(s) Code(s) Code(s)

611-001-00-6 azobenzene 203-102-5 103-33-3 Carc. 1B Muta. 2 H350 GHS08 H350

Acute Tox. 4 * H341 GHS07 H341 Acute Tox. 4 * H332 GHS09 H332 STOT RE 2 * H302 Dgr H302 Aquatic Acute 1 H373 ** H373 ** Aquatic Chronic 1 H400 H410 H410

611-002-00-1 azoxybenzene 207-802-1 495-48-7 Acute Tox. 4 * H332 GHS07 H332

Acute Tox. 4 * H302 Wng H302

611-003-00-7 fenaminosulf (ISO); 205-419-4 140-56-7 Acute Tox. 3 * H301 GHS06 H301 sodium 4- Acute Tox. 4 * H312 Dgr H312 dimethylaminobenzenediazosulphon Aquatic Chronic 3 H412 H412 ate

611-004-00-2 methyl-ONN-azoxymethyl acetate; 209-765-7 592-62-1 Carc. 1B Repr. 1B H350 GHS08 H350 methyl azoxy methyl acetate H360D *** Dgr H360D ***

611-005-00-8 disodium {5-[(4'-((2,6-hydroxy3-((2- 240-221-1 16071-86-6 Carc. 1B H350 GHS08 H350 hydroxy-5- Dgr

sulphophenyl)azo)phenyl)azo)(1,1'- biphenyl)-4-yl)azo]salicylato (4- )}cuprate(2-); CI Direct Brown 95

611-006-00-3 4-o-tolylazo-o-toluidine; 202-591-2 97-56-3 Carc. 1B H350 GHS08 H350

4-amino-2',3-dimethylazobenzene; Skin Sens. 1 H317 Dgr H317 fast garnet GBC base; AAT; o-aminoazotoluene

611-007-00-9 tricyclazole (ISO); 255-559-5 41814-78-2 Acute Tox. 4 * H302 GHS07 H302

5-methyl-1,2,4-triazolo(3,4-b)benzo Wng 1,3-thiazole;

611-008-00-4 4-aminoazobenzene; 200-453-6 60-09-3 Carc. 1B H350 GHS08 H350

4-phenylazoaniline Aquatic Acute 1 H400 GHS09 H410 Aquatic Chronic 1 H410 Dgr

383

D050725/02

Classification Labelling Specific Conc. Limits, M-factors Notes

Index No International Chemical Identification EC No CAS No

Hazard Class and Category Hazard Suppl. Hazard

Code(s) Statement

Pictogram, Signal Hazard statement

Code(s) Word Code(s)

statement Code(s) Code(s)

611-009-00-X sodium (1-(5-(4-(4-anilino-3- 401-220-3 — Acute Tox. 4 * H332 GHS07 H332 sulphophenylazo)-2-methyl-5- Aquatic Chronic 3 H412 Wng H412 methylsulphonamidophenylazo)4-

hydroxy-2-oxido-3- (phenylazo)phenylazo)-5-nitro-4- sulphonato-2-naphtholato)iron(II)

611-010-00-5 2'-(2-cyano-4,6-dinitrophenylazo)-5'- 403-010-7 106359-94-8 Skin Sens. 1 H317 GHS07 H317

(N,N-dipropylamino)propionanilide Aquatic Chronic 3 H412 Wng H412

611-011-00-0 N,N,N',N'-tetramethyl-3,3'- 403-340-1 — Eye Dam. 1 H318 GHS05 H318

(propylenebis(iminocarbonyl-4,1- Aquatic Chronic 2 H411 GHS09 H411 phenylenazo(1,6-dihydro-2-hydroxy Dg 4-methyl-6-oxopyridine-3,1- diyl)))di(propylammonium) dilactate

611-012-00-6 reaction mass of 2,2-iminodiethanol 403-410-1 114565-65-0 Skin Sens. 1 H317 GHS07 H317

6-methyl-2-(4-(2,4,6- Wng triaminopyrimidin-5- ylazo)phenyl)benzothiazole-7- sulfonate and 2-methylaminoethanol 6-methyl-2-(4-(2,4,6- triaminopyrimidin-5- ylazo)phenyl)benzothiazole-7- sulfonate and N,N-diethylpropane 1,3-diamine 6-methyl-2-(4-(2,4,6- triaminopyrimidin-5- ylazo)phenyl)benzothiazole-7- sulfonate

611-013-00-1 trilithium-1-hydroxy-7-(3- 403-650-7 117409-78-6 Expl. 1.3 **** H203 GHS01 H203 sulfonatoanilino)-2-(3-methyl-4-(2- Aquatic Chronic 2 H411 GHS09 H411 methoxy-4-(3- Dgr

sulfonatophenylazo)phenylazo)phen ylazo)naphthalene-3-sulfonate

384

D050725/02

Classification Labelling Specific Conc. Limits, M-factors Notes

Index No International Chemical Identification EC No CAS No

Hazard Class and Category Hazard Pictogram, Signal Hazard Suppl. Hazard

Code(s) Statement statement statement Code(s) Word Code(s) Code(s) Code(s)

611-014-00-7 (tetrasodium 1-(4-(3-acetamido-4- 404-250-5 115099-55-3 Skin Sens. 1 H317 GHS07 H317

(4'-nitro-2,2'-disulfonatostilben-4- Wng ylazo)anilino)-6-(2,5- disulfonatoanilino)-1,3,5-triazin-2- yl)-3-carboxypyridinium) hydroxide

611-015-00-2 tetrasodium 4-amino-5-hydroxy-6- 404-320-5 116889-78-2 Skin Sens. 1 H317 GHS07 H317

(4-(2-(2- Wng (sulfonatooxy)ethylsulfonyl)ethylcar bamoyl)phenylazo)-3-(4-(2- (sulfonatooxy)ethylsulfonyl)phenyla zo)naphthalene-2,7-disulfonate

611-016-00-8 reaction mass of 1,1'- 404-540-1 — Skin Sens. 1 H317 GHS07 H317

((dihydroxyphenylene)bis(azo-3,1- Wng phenylenazo(1-(3- dimethylaminopropyl)-1,2-dihydro 6-hydroxy-4-methyl-2-oxopyridine 5,3-diyl)))dipyridinium dichloride dihydrochloride, mixed isomers and 1-(1-(3-dimethylaminopropyl)-5-(3- ((4-(1-(3-dimethylaminopropyl)-1,6- dihydro-2-hydroxy-4-methyl-6-oxo 5-pyridinio-3- pyridylazo)phenylazo)-2,4(or 2,6 or 3,5)- dihydroxyphenylazo)phenylazo)-1,2- dihydro-6-hydroxy-4-methyl-2-oxo 3-pyridyl)pyridinium dichloride

611-017-00-3 2-(4- 404-910-2 — Skin Sens. 1 H317 GHS07 H317

(diethylaminopropylcarbamoyl)phen Aquatic Chronic 2 H411 GHS09 H411 ylazo)-3-oxo-N-(2,3-dihydro-2- Wng oxobenzimidazol-5-yl)butyramide

611-018-00-9 tetraammonium 5-(4-(7-amino-1- 405-130-5 — Skin Sens. 1 H317 GHS07 H317 hydroxy-3-sulfonato-2-naphthylazo)- Wng

6-sulfonato-1- naphthylazo)isophthalate

385

D050725/02

Classification Labelling Specific Conc. Limits, M-factors Notes

Index No International Chemical Identification EC No CAS No

Hazard Class and Category Hazard Hazard Suppl. Hazard

Code(s) Statement

Pictogram, Signal

Code(s) Word Code(s)

statement statement Code(s) Code(s)

611-019-00-4 tetralithium 6-amino-4-hydroxy-3- 405-150-4 106028-58-4 Skin Sens. 1 H317 GHS07 H317

(7-sulfonato-4-(4- Wng sulfonatophenylazo)-1- naphthylazo)naphthalene-2,7- disulfonate

611-020-00-X tetrakis(tetramethylammonium) 405-170-3 116340-05-7 Acute Tox. 3 * H301 GHS06 H301

6-amino-4-hydroxy-3-(7-sulfonato Skin Sens. 1 H317 Dgr H317 4-(4-sulfonatophenylazo)-1- Aquatic Chronic 3 H412 H412 naphthylazo)naphthalene-2,7- disulfonate

611-021-00-5 2-(4-(4-cyano-3-methylisothiazol-5- 405-480-9 — Acute Tox. 4 * H302 GHS08 H302 ylazo)-N-ethyl-3-methylanilino)ethyl STOT RE 2 * H373 ** GHS07 H373 ** acetate Skin Irrit. 2 H315 Wng H315 Aquatic Chronic 4 H413 H413

611-022-00-0 4-dimethylaminobenzenediazonium 404-980-4 — Self-react. C H242 GHS02 H242 T

3-carboxy-4- Acute Tox. 3 * H331 GHS06 H331 hydroxybenzenesulfonate Acute Tox. 3 * H301 GHS08 H301 Acute Tox. 4 * H312 GHS05 H312 STOT RE 2 * H373 ** GHS09 H373 ** Eye Dam. 1 H318 Dgr H318 Skin Sens. 1 H317 H317 Aquatic Acute 1 H400 H410 Aquatic Chronic 1 H410

611-023-00-6 disodium 7-(4,6-dichloro-1,3,5- 404-600-7 — Skin Sens. 1 H317 GHS07 H317 triazin-2-ylamino)-4-hydroxy-3-(4- Wng

(2- (sulfonatooxy)ethylsulfonyl)phenyla zo) naphthalene-2-sulfonate

611-024-00-1 benzidine based azo dyes; — — Carc. 1B H350 GHS08 H350 A

4,4'-diarylazobiphenyl dyes, with the Dgr exception of those specified elsewhere in this Annex

386

D050725/02

Classification Labelling Specific Conc. Limits, M-factors Notes

Index No International Chemical Identification EC No CAS No

Hazard Class and Category Hazard Hazard Suppl. Hazard

Code(s) Statement

Pictogram, Signal statement

Code(s) Word Code(s)

statement Code(s) Code(s)

611-025-00-7 disodium 4-amino-3-[[4'-[(2,4- 217-710-3 1937-37-7 Carc. 1B Repr. 2 H350 GHS08 H350 diaminophenyl)azo][1,1'-biphenyl]- H361d *** Dgr H361d *** 4-yl]azo]-5-hydroxy-6-

(phenylazo)naphtalene-2,7- disulphonate; C.I. Direct Black 38

611-026-00-2 tetrasodium 3,3'-[[1,1'-biphenyl]- 220-012-1 2602-46-2 Carc. 1B Repr. 2 H350 GHS08 H350

4,4'diylbis(azo)]bis[5-amino-4- H361d *** Dgr H361d *** hydroxynaphthalene-2,7- disulphonate]; C.I. Direct Blue 6

611-027-00-8 disodium 3,3'-[[1,1'-biphenyl]-4,4'- 209-358-4 573-58-0 Carc. 1B Repr. 2 H350 GHS08 H350 diylbis(azo)]bis(4- H361d *** Dgr H361d *** aminonaphthalene-1-sulphonate);

C.I. Direct Red 28

611-028-00-3 C,C'-azodi(formamide) 204-650-8 123-77-3 Resp. Sens. 1 H334 GHS08 H334 G

Dgr

611-029-00-9 o-dianisidine based azo dyes; — — Carc. 1B H350 GHS08 H350 A

4,4'-diarylazo-3,3'- Dgr dimethoxybiphenyl dyes with the exception of those mentioned elsewhere in this Annex

611-030-00-4 o-tolidine based dyes; — — Carc. 1B H350 GHS08 H350 A

4,4'-diarylazo-3,3'-dimethylbiphenyl Dgr dyes, with the exception of those mentioned elsewhere in this Annex

611-031-00-X 4,4'-(4-iminocyclohexa-2,5- 209-321-2 569-61-9 Carc. 1B H350 GHS08 H350 dienylidenemethylene)dianiline Dgr

hydrochloride; C.I. Basic Red 9

387

D050725/02

Classification Labelling Specific Conc. Limits, M-factors Notes

Index No International Chemical Identification EC No CAS No

Hazard Class and Category Hazard Pictogram, Signal Hazard Suppl. Hazard

Code(s) Statement statement statement Code(s) Word Code(s) Code(s) Code(s)

611-032-00-5 1,4,5,8-tetraaminoanthra 219-603-7 2475-45-8 Carc. 1B H350 GHS08 H350 quinone; Skin Irrit. 2 H315 GHS05 H315 C.I. Disperse Blue 1 Eye Dam. 1 H318 GHS07 H318 Skin Sens. 1 H317 Dgr H317

611-033-00-0 hexasodium [4,4''-azoxybis(2,2'- 400-020-3 82027-60-9 Aquatic Chronic 2 H411 GHS09 H411 disulfonatostilbene-4,4'diylazo)]-

bis[5'-sulfonatobenzene-2,2'-diolato O(2), O(2), N(1)]-copper(II)

611-034-00-6 N-(5-(bis(2-methoxyethyl)amino)-2- 402-430-8 105076-77-5 Aquatic Chronic 4 H413 H413

((5-nitro-2,1-benzisothiazol-3- — yl)azo)phenylacetamide

611-035-00-1 tetralithium 6-amino-4-hydroxy-3- 403-660-1 107246-80-0 Aquatic Chronic 2 H411 GHS09 H411

[7-sulfonato-4-(5-sulfonato-2- naphthylazo)-1- naphthylazo]naphthalene-2,7- disulfonate

611-036-00-7 2-(4-(5,6(or 6,7)-dichloro-1,3- 405-440-0 Skin Sens. 1 H317 GHS07 H317 benzothiazol-2-ylazo)-N-methyl-m- — Wng

toluidino)ethyl acetate

611-037-00-2 3(or 5)-(4-(N-benzyl-N-ethylamino)- 406-055-0 124584-00-5 Acute Tox. 4 * H302 GHS05 H302

2-methylphenylazo)1,4-dimethyl Eye Dam. 1 H318 GHS07 H318 1,2,4-triazolium methylsulphate Skin Sens. 1 H317 GHS09 H317 Aquatic Chronic 2 H411 Dgr H411

611-038-00-8 trisodium 1-hydroxynaphthalene-2- 406-820-9 — Eye Irrit. 2 H319 GHS07 H319 azo-4'(5',5''-dimethylbiphenyl)-4''- Wng

azo(4''-phenylsulfonyloxybenzene)- 2',2'',4-trisulfonate

388

D050725/02

Classification Labelling Specific Conc. Limits, M-factors Notes

Index No International Chemical Identification EC No CAS No

Hazard Class and Category Hazard Pictogram, Signal Hazard Suppl. Hazard

Code(s) Statement statement statement Code(s) Word Code(s) Code(s) Code(s)

611-039-00-3 7-[((4,6-dichloro-1,3,5-triazin-2- 407-050-6 117715-57-8 Skin Sens. 1 H317 GHS07 H317 yl)amino)-4-hydroxy-3-(4-((2- Wng

sulfoxy)ethyl)sulfonyl)phenylazo]na phthalene-2-sulfonic acid

611-040-00-9 3-(5-acetylamino-4-(4-[4,6-bis(3- 407-670-7 115099-58-6 Aquatic Acute 1 H400 GHS09 H410 diethylaminopropylamino)-1,3,5- Aquatic Chronic 1 H410 Wng

triazin-2-ylamino]phenylazo)-2-(2- methoxyethoxy)phenylazo)-6-amino 4-hydroxy-2-naphthalenesulfonic acid

611-041-00-4 2-[[4[[4,6-bis[[3- 407-680-1 98809-11-1 Eye Dam. 1 H318 GHS05 H318

(diethylamino)propyl]amino]-1,3,5- Skin Sens. 1 H317 GHS07 H317 triazine-2-yl]amino]phenyl]azo]-N- Aquatic Chronic 2 H411 GHS09 H411 (2,3-dihydro-2-oxo-1H- Dgr benzimidazol-5-yl)-3-oxobutanamide

611-042-00-X trisodium 5-amino-3-[5-(2- 411-770-6 136213-71-3 Aquatic Chronic 3 H412 — H412 bromoacryloylamino)-2-

sulfonatophenylazo]-4-hydroxy-6-(4- vinylsulfonylphenylazo)naphthalene 2,7-disulfonate

389

D050725/02

Classification Labelling Specific Conc. Limits, M-factors Notes

Index No International Chemical Identification EC No CAS No

Hazard Class and Category Hazard Hazard Suppl. Hazard

Code(s) Statement

Pictogram, Signal statement

Code(s) Word Code(s)

statement Code(s) Code(s)

611-043-00-5 reaction mass of: trisodium N(1')- 402-850-1 — Eye Dam. 1 H318 GHS05 H318

N(2):N(1''')-N(2'')-η-6-[2-amino-4- Aquatic Chronic 3 H412 Dgr H412 (or 6)-hydroxy-(or 4-amino-2- hydroxy)phenylazo]-6''-(1- carbaniloyl-2-hydroxyprop-1- enylazo)-5',5'''-disulfamoyl-3,3''- disulfonatobis(naphthalene-2,1'- azobenzene-1,2'-diolato-O(1), O(2'))- chromate; trisodium N(1')-N(2):N(1''')N(2'')-η- 6,6''-bis(1-carbaniloyl-2- hydroxyprop-1-enylazo)- 5',5'''disulfamoyl-3,3''-disulfonato bis(naphthalene-2,1'azobenzene-1,2'- diolato-O(1),O(2'))-chromate; trisodium N(1')-N(2):N(1''')N(2'')-η- 6,6''-bis[2-amino-4-(or 6)-hydroxy(or 4-amino-2- hydroxy)phenylazo]5',5'''disulfamoyl -3,3''-disulfonatobis(naphthalene 2,1'azobenzene-1,2'-diolato O(1),O(2'))-chromate (2:1:1)

390

D050725/02

Classification Labelling Specific Conc. Limits, M-factors Notes

Index No International Chemical Identification EC No CAS No

Hazard Class and Category Hazard Hazard Suppl. Hazard

Code(s) Statement

Pictogram, Signal statement

Code(s) Word Code(s)

statement Code(s) Code(s)

611-044-00-0 reaction mass of: tert-alkyl(C 12 - 403-720-7 117527-94-3 Aquatic Chronic 2 H411 GHS09 H411

C 14 )ammonium bis[1-[(2-hydroxy-5-

nitrophenyl)azo]-2- naphthalenolato(2-)]-chromate(1-);

tert-alkyl(C 12 -C )ammonium bis[1- 14

[(2-hydroxy-4-nitrophenyl)azo]-2- naphthalenolato(2)]-chromate(1-);

tert-alkyl(C 12 -C )ammonium bis[1- 14

[[5-(1,1-dimethylpropyl)-2-hydroxy 3-nitrophenyl]azo]-2- naphthalenolato(2-)]-chromate(1-);

tert-alkyl(C 12 -C )ammonium [[1- 14

[(2-hydroxy-5-nitrophenyl)azo]-2- naphthalenolato(2)]-[1-[(2-hydroxy 5-nitrophenyl)azo]-2- naphthalenolato(2-)]]-chromate(1-);

tert-alkyl(C 12 -C )ammonium [[1- 14

[[5-(1,1-dimethylpropyl)-2-hydroxy 3-nitrophenyl]azo]-2- naphthalenolato(2-)]-[1-[(2-hydroxy 5-nitrophenyl)azo]-2- naphthalenolato(2-)]]-chromate(1-); tert-alkyl(C 12 -C 14 )ammonium ((1-(4(or 5)-nitro-2- oxidophenylazo)-2-naphtholato)(1- (3-nitro-2-oxido-5-pentylphenylazo)- 2-naphtholato))chromate(1-)

611-045-00-6 2-[4-[N-(4-acetoxybutyl)-N- 404-830-8 — Aquatic Chronic 4 H413 — H413 ethyl]amino-2-methylphenylazo]-3-

acetyl-5-nitrothiophene

611-046-00-1 4,4'-diamino-2-methylazobenzene 407-590-2 43151-99-1 Acute Tox. 3 * H301 GHS06 H301

STOT RE 2 * H373 ** GHS08 H373 ** Skin Sens. 1 H317 GHS09 H317 Aquatic Acute 1 H400 Dgr H410 Aquatic Chronic 1 H410

391

D050725/02

Classification Labelling Specific Conc. Limits, M-factors Notes

Index No International Chemical Identification EC No CAS No

Hazard Class and Category Hazard Hazard Suppl. Hazard

Code(s) Statement

Pictogram, Signal

Code(s) Word Code(s)

statement statement Code(s) Code(s)

611-047-00-7 reaction mass of: 2-[[4-[N-ethyl-N- 407-890-3 111381-11-4 Aquatic Chronic 4 H413 — H413

(2-acetoxyethyl)amino]phenyl]azo]- 5,6-dichlorobenzothiazole; 2-[[4-[N- ethyl-N-(2- acetoxyethyl)amino]phenyl]azo]-6,7- dichlorobenzothiazole (1:1)

611-048-00-2 reaction mass of: 2-[[4-[bis(2- 407-900-6 111381-12-5 Aquatic Chronic 4 H413 — H413 acetoxyethyl)amino]phenyl]azo]-5,6-

dichlorobenzothiazole; 2-[[4-[bis(2- acetoxyethyl)amino]phenyl]azo]-6,7- dichlorobenzothiazole (1:1)

611-049-00-8 reaction mass of 7-[4-(3- 408-000-6 118658-98-3 STOT RE 2 * H373 ** GHS08 H373 ** diethylaminopropylamino)-6-(3- Skin Sens. 1 H317 Wng H317

diethylammoniopropylamino)-1,3,5- Aquatic Chronic 3 H412 H412 triazin-2-ylamino]-4-hydroxy-3-(4- phenylazophenylazo)-naphthalene-2- sulfonate, acetic acid, lactic acid (2:1:1)

392

D050725/02

Classification Labelling Specific Conc. Limits, M-factors Notes

Index No International Chemical Identification EC No CAS No

Hazard Class and Category Hazard Hazard Suppl. Hazard

Code(s) Statement

Pictogram, Signal

Code(s) Word Code(s)

statement statement Code(s) Code(s)

611-050-00-3 reaction mass of: pentasodium 415-350-3 Eye Dam. 1 H318 GHS05 H318

7-amino-3-[[4-[[4-[[4-[[4-[(6-amino 1-hydroxy-3-sulfonato-2- Aquatic Chronic 3 H412 Dgr H412 naphthyl]azo]-7-sulfonato 1naphthyl]azo]phenyl]amino]-3- sulfonatophenyl]azo]-6-sulfonato-1-

naphthyl]azo]-4-hydroxynaphthalen—

2-sulfonate;

pentasodium 7-amino-8-[4-[4-[4-[4- (2-amino-5-hydroxy-7-sulfonatonaphthalen-1-ylazo)-7- sulfonatonaphthalen-1-ylazo]- phenylamino]-3-sulfonatophenylazo]-6-sulfonato-naphthalen- 1-ylazo]-4-hydroxy-naphthalene-2- sulfonate;

pentasodium 7-amino-8-[4-[4-[4-[4- (6-amino-1-hydroxy-3-sulfonatonaphthalen-1-ylazo)-7- sulfonatonaphthalen-1-ylazo]- phenylamino]-3-sulfonatophenylazo]-6-sulfonato-naphthalen- 1-ylazo]-4-hydroxy-naphthalene-2- sulfonate;

tetrasodium 7-amino-4-hydroxy-3- [4-[4-[4-(4-hydroxy-7-sulfonatonaphthalen-1-ylazo)-2-sulfonato- phenylamino]phenylazo]-6- sulfonato-naphthalen-1- ylazo]naphthalene-2-sulfonate;

tetrasodium 7-amino-4-hydroxy-3- [4-[4-[4-(4-amino-7-sulfonatonaphthalen-1-ylazo)-2- sulfonatophenylamino]phenylazo]-6- sulfonato-naphthalen-1- ylazo]naphthalene-2-sulfonate

393

D050725/02

Classification Labelling Specific Conc. Limits, M-factors Notes

Index No International Chemical Identification EC No CAS No

Hazard Class and Category Hazard Pictogram, Signal Hazard Suppl. Hazard

Code(s) Statement Code(s) Word Code(s) statement statement Code(s) Code(s)

611-051-00-9 2-(4-(N-ethyl-N-(2- 411-110-7 136213-74-6 Aquatic Acute 1 H400 GHS09 H410 hydroxy)ethyl)amino-2- Aquatic Chronic 1 H410 Wng

methylphenyl)azo-6-methoxy-3- methyl-benzothiazolium chloride

611-052-00-4 monosodium aqua-[5-[[2,4- 400-720-9 — Aquatic Chronic 3 H412 — H412 dihydroxy-5-[(2-hydroxy-3,5-

dinitrophenyl)azo]phenyl]azo]-2- naphthalensulfonate], iron complex

611-053-00-X 2,2'-azobis[2-methylpropionamidine] 221-070-0 2997-92-4 Acute Tox. 4 * H302 GHS07 H302 dihydrochloride Skin Sens. 1 H317 Wng H317

611-055-00-0 C.I. Disperse Yellow 3; 220-600-8 2832-40-8 Carc. 2 H351 GHS08 H351

N-[4-[(2-hydroxy-5- Skin Sens. 1 H317 GHS07 H317 methylphenyl)azo]phenyl]acetamide Wng

611-056-00-6 C.I. Solvent Yellow 14; 212-668-2 842-07-9 Carc. 2 H351 GHS08 H351

1-phenylazo-2-naphthol Muta. 2 H341 GHS07 H341 Skin Sens. 1 H317 Wng H317 Aquatic Chronic 4 H413 H413

611-057-00-1 6-hydroxy-1-(3-isopropoxypropyl)- 400-340-3 85136-74-9 Carc. 1B H350 GHS08 H350

4-methyl-2-oxo-5-[4- Aquatic Chronic 4 H413 Wng H413 (phenylazo)phenylazo]-1,2-dihydro 3-pyridinecarbonitrile

611-058-00-7 (6-(4-hydroxy-3-(2- 402-060-7 108225-03-2 Carc. 1B H350 GHS08 H350 methoxyphenylazo)-2-sulfonato-7- Eye Dam. 1 H318 GHS05 H318 naphthylamino)-1,3,5-triazin-2,4- Aquatic Chronic 2 H411 GHS09 H411 diyl)bis[(amino-1- Dgr

methylethyl)ammonium] formate

394

D050725/02

Classification Labelling Specific Conc. Limits, M-factors Notes

Index No International Chemical Identification EC No CAS No

Hazard Class and Category Hazard Pictogram, Signal Hazard Suppl. Hazard

Code(s) Statement statement Code(s) Word Code(s) statement Code(s) Code(s)

611-059-00-2 octasodium 2-(6-(4-chloro-6-(3-(N- 412-960-1 148878-21-1 Eye Dam. 1 H318 GHS05 H318 methyl-N-(4-chloro-6-(3,5- Skin Sens. 1 H317 GHS07 H317 disulfonato-2-naphthylazo)-1- Aquatic Chronic 3 H412 Dgr H412

hydroxy-6-naphthylamino)-1,3,5- triazin-2- yl)aminomethyl)phenylamino)-1,3,5- triazin-2-ylamino)-3,5-disulfonato-1- hydroxy-2-naphthylazo)naphthalene 1,5-disulfonate

611-060-00-8 reaction mass of: sodium 5-[8-[4-[4- 413-180-4 187285-15-0 Eye Dam. 1 H318 GHS05 H318

[4-[7-(3,5-dicarboxylatophenylazo)- Dgr 8-hydroxy-3,6- disulfonatonaphthalen-1-ylamino]-6- hydroxy-1,3,5-triazin-2-yl]-2,5- dimethylpiperazin-1-yl]-6-hydroxy 1,3,5-triazin-2-ylamino]-1-hydroxy 3,6-disulfonatonaphthalen-2-ylazo]- isophthalate; ammonium 5-[8-[4-[4-[4-[7-(3,5- dicarboxylatophenylazo)-8-hydroxy 3,6-disulfonatonaphthalen-1- ylamino]-6-hydroxy-1,3,5-triazin-2- yl]-2,5-dimethylpiperazin-1-yl]-6- hydroxy-1,3,5-triazin-2-ylamino]-1- hydroxy 3,6-disulfonatonaphthalen 2-ylazo]-isophthalate;

5-[8-[4-[4-[4-[7-(3,5- dicarboxylatophenylazo)-8-hydroxy 3,6-disulfonatonaphthalen-1- ylamino]-6-hydroxy-1,3,5-triazin-2- yl]-2,5-dimethylpiperazin-1-yl]-6- hydroxy-1,3,5-triazin-2-ylamino]-1- hydroxy-3,6-disulfonaphthalen-2- ylazo]-isophthalic acid

395

D050725/02

Classification Labelling Specific Conc. Limits, M-factors Notes

Index No International Chemical Identification EC No CAS No

Hazard Class and Category Hazard Pictogram, Signal Hazard Suppl. Hazard

Code(s) Statement statement statement Code(s) Word Code(s) Code(s) Code(s)

611-061-00-3 disodium 5-[5-[4-(5-chloro-2,6- 412-530-3 — Eye Dam. 1 H318 GHS05 H318 difluoropyrimidin-4- Skin Sens. 1 H317 GHS07 H317 ylamino)benzamido]-2- Dgr

sulfonatophenylazo]-1-ethyl-6- hydroxy-4-methyl-2-oxo-3- pyridylmethylsulfonate

611-062-00-9 octasodium 2-(8-(4-chloro-6-(3-((4- 413-550-5 — Skin Irrit. 2 H315 GHS05 H315 chloro-6-(3,6-disulfonato-2-(1,5- Eye Dam. 1 H318 Dgr H318 disulfonatonaphthalen-2-ylazo)-1-

hydroxynaphthalen-8-ylamino)- 1,3,5-triazin-2- yl)aminomethyl)phenylamino)-1,3,5- triazin-2-ylamino)-3,6-disulfonato-1- hydroxynaphthalen-2- ylazo)naphthalene-1,5-disulfonate

611-063-00-4 trisodium [4'-(8-acetylamino-3,6- 413-590-3 164058-22-4 Carc. 1B H350 GHS08 H350 disulfonato-2-naphthylazo)-4''-(6- Dgr

benzoylamino-3-sulfonato2- naphthylazo)-biphenyl 1,3',3'',1'''- tetraolato-O,O',O'',O''']copper(II)

611-064-00-X 4-(3,4-dichlorophenylazo)-2,6-di 410-600-8 124719-26-2 STOT RE 2 * H373 ** GHS08 H373 ** sec-butyl-phenol Skin Irrit. 2 H315 GHS07 H315

Aquatic Acute 1 H400 GHS09 H410 Aquatic Chronic 1 H410 Wng

611-065-00-5 4-(4-nitrophenylazo)-2,6-di-sec- 410-610-2 111850-24-9 STOT RE 2 * H373 ** GHS08 H373 ** butyl-phenol Eye Irrit. 2 H319 GHS07 H319

Skin Irrit. 2 H315 GHS09 H315 Skin Sens. 1 H317 Wng H317 Aquatic Acute 1 H400 H410 Aquatic Chronic 1 H410

396

D050725/02

Classification Labelling Specific Conc. Limits, M-factors Notes

Index No International Chemical Identification EC No CAS No

Hazard Class and Category Hazard Hazard Suppl. Hazard

Code(s) Statement

Pictogram, Signal statement

Code(s) Word Code(s)

statement Code(s) Code(s)

611-066-00-0 tetrasodium 5-[4-chloro-6-(N-ethyl 411-540-5 130201-57-9 Eye Dam. 1 H318 GHS05 H318 anilino)-1,3,5-triazin-2-ylamino]-4- Skin Sens. 1 H317 GHS07 H317 hydroxy-3-(1,5- Aquatic Chronic 2 H411 GHS09 H411 disulfonatonaphthalen-2-ylazo)- Dgr

naphthalene-2,7-disulfonate

611-067-00-6 reaction mass of: bis(tris(2-(2- 406-910-8 — Acute Tox. 4 * H302 GHS07 H302 hydroxy(1- Aquatic Chronic 3 H412 Wng H412 methyl)ethoxy)ethyl)ammonium) 7-

anilino-4-hydroxy-3-(2-methoxy-5- methyl-4-(4- sulfonatophenylazo)phenylazo)napht halene-2-sulfonate; bis(tris(2-(2- hydroxy(2- methyl)ethoxy)ethyl)ammonium) 7- anilino-4-hydroxy-3-(2-methoxy-5- methyl-4-(4- sulfonatophenylazo)phenylazo)napht halene-2-sulfonate

611-068-00-1 tetrasodium 4-amino-3,6-bis(5-[4- 400-690-7 85665-98-1 Aquatic Chronic 2 H411 GHS09 H411 chloro-6-(2-hydroxyethylamino)-

1,3,5-triazin-2-ylamino]-2- sulfonatophenylazo)-5- hydroxynaphthalene-2,7-disulfonate

611-069-00-7 N,N-di-[poly(oxyethylene)-co 413-380-1 — Aquatic Chronic 2 H411 GHS09 H411 poly(oxypropylene)]-4-[(3,5-

dicyano-4-methyl-2-thienyl)azo)]-3- methylaniline

611-070-00-2 reaction mass of: disodium (6-(4- 405-665-4 Skin Sens. 1 H317 GHS07 H317 anisidino)-3-sulfonato-2-(3,5-dinitro— Aquatic Acute 1 H400 GHS09 H410 2-oxidophenylazo)-1-naphtholato)(1- Aquatic Chronic 1 H410 Wng

(5-chloro-2-oxidophenylazo)-2- naphtholato)chromate(1-); trisodium bis(5-(4-anisidino)-3- sulfonato-2-(3,5-dinitro-2- oxidophenylazo)-1- naphtholato)chromate(1-)

397

D050725/02

Classification Labelling Specific Conc. Limits, M-factors Notes

Index No International Chemical Identification EC No CAS No

Hazard Class and Category Hazard Pictogram, Signal Hazard Suppl. Hazard

Code(s) Statement statement Code(s) Word Code(s) statement Code(s) Code(s)

611-071-00-8 tris(tetramethylammonium) 5- 406-073-9 131013-81-5 Acute Tox. 3 * H301 GHS06 H301 hydroxy-1-(4-sulphonatophenyl)-4- Aquatic Chronic 3 H412 Dgr H412 (4-sulphonatophenylazo)pyrazole-3-

carboxylate

611-072-00-3 2,4-bis[2,2'-[2-(N,N- 407-010-8 118208-02-9 Acute Tox. 4 * H302 GHS05 H302 dimethylamino)ethyloxycarbonyl]ph Eye Dam. 1 H318 GHS07 H318 enylazo]-1,3-dihydroxybenzene, Aquatic Chronic 2 H411 GHS09 H411 dihydrochloride Dgr

611-073-00-9 dimethyl 3,3'-(N-(4-(4-bromo-2,6- 407-310-9 122630-55-1 Aquatic Chronic 4 H413 H413 dicyanophenylazo)-3- —

hydroxyphenyl)imino)dipropionate

611-074-00-4 reaction mass of: sodium/potassium 407-100-7 Skin Sens. 1 H317 GHS07 H317

(3-(4-(5-(5-chloro-2,6- — Wng

difluoropyrimidin-4-ylamino)-2- methoxy-3-sulfonatophenylazo)-2- oxidophenylazo)-2,5,7-trisulfonato 4-naphtholato)copper(II); sodium/potassium (3-(4-(5-(5- chloro-4,6-difluoropyrimidin-2- ylamino)-2-methoxy-3- sulfonatophenylazo)-2- oxidophenylazo)-2,5,7-trisulfonato 4-naphtholato)copper(II)

398

D050725/02

Classification Labelling Specific Conc. Limits, M-factors Notes

Index No International Chemical Identification EC No CAS No

Hazard Class and Category Hazard Suppl. Hazard

Code(s) Statement

Pictogram, Signal Hazard statement

Code(s) Word Code(s)

statement Code(s) Code(s)

611-075-00-X reaction mass of: tris(3,5,5- 406-000-0 Eye Dam. 1 H318 GHS05 H318 trimethylhexylammonium) 4-amino— Aquatic Chronic 2 H411 GHS09 H411 3-(4-(4-(2-amino-4- Dgr

hydroxyphenylazo)anilino)-3- sulfonatophenylazo)-5,6-dihydro-5- oxo-6-phenylhydrazononaphthalene 2,7-disulfonate; tris(3,5,5-trimethylhexylammonium) 4-amino-3-(4-(4-(4-amino-2- hydroxyphenylazo)anilino)-3- sulfonatophenylazo)-5,6-dihydro-5- oxo-6-phenylhydrazononaphthalene 2,7-disulfonate (2:1)

611-076-00-5 3-(2,6-dichloro-4-nitrophenylazo)-1- 406-280-4 117584-16-4 Aquatic Acute 1 H400 GHS09 H410 methyl-2-phenylindole Aquatic Chronic 1 H410 Wng

611-077-00-0 dilithium disodium (5,5'-diamino-(μ- 407-230-4 126637-70-5 Acute Tox. 4 * H302 GHS07 H302

4,4'-dihydroxy-1:2κ-2,O4,O4',-3,3'- Skin Sens. 1 H317 Wng H317 [3,3'-dihydroxy-1:2-κ-2-O3,O3'- biphenyl-4,4'-ylenebisazo-1:2-(N3, N4-η:N3', N4'-η)]-dinaphthalene-2,7- disulfonato(8)))dicuprate(2-)

611-078-00-6 (2,2'-(3,3'-dioxidobiphenyl-4,4'- 407-240-9 159604-94-1 Skin Sens. 1 H317 GHS07 H317 diyldiazo)bis(6-(4-(3- Aquatic Chronic 2 H411 GHS09 H411 (diethylamino)propylamino)-6-(-3- Wng

(diethylammonio)propylamino)1,3,5- triazin-2-ylamino)-3-sulfonato-1- naphtholato))dicopper(II) acetate lactate

611-079-00-1 disodium 7-[4-chloro-6-(N-ethyl-o- 410-390-8 147703-64-8 Eye Dam. 1 H318 GHS05 H318 toluidino)-1,3,5-triazin2-ylamino]-4- Dgr

hydroxy-3-(4-methoxy-2- sulfonatophenylazo)2- naphthalenesulfonate

399

D050725/02

Classification Labelling Specific Conc. Limits, M-factors Notes

Index No International Chemical Identification EC No CAS No

Hazard Class and Category Hazard Hazard Suppl. Hazard

Code(s) Statement

Pictogram, Signal

Code(s) Word Code(s)

statement statement Code(s) Code(s)

611-080-00-7 sodium 3-(2-acetamido-4-(4-(2- 410-150-2 147703-65-9 Skin Sens. 1 H317 GHS07 H317 hydroxybutoxy)phenylazo)phenylazo Wng

)benzenesulfonate

611-081-00-2 tetrasodium [7-(2,5-dihydroxy-KO2- 411-470-5 141048-13-7 Skin Sens. 1 H317 GHS07 H317

7-sulfonato-6-[4-(2,5,6-trichloro Aquatic Chronic 3 H412 Wng H412 pyrimidin-4-ylamino)phenylazo]- (N1,N7-N)1-naphthylazo)-8- hydroxy-KO8-naphthalene-1,3,5- trisulfonato(6)]cuprate(II)

611-082-00-8 reaction mass of: pentasodium bis(1- 407-570-3 Aquatic Chronic 2 H411 GHS09 H411

(3(or 5)-(4-anilino-3-

sulfonatophenylazo)-4-hydroxy-2- —

oxidophenylazo)-6-nitro-4-sulfonato 2-naphtholato)ferrate(1-); pentasodium [(1-(3-(4-anilino-3- sulfonatophenylazo)-4-hydroxy-2- oxidophenylazo)-6-nitro-4-sulfonato 2-naphtholato)-(5-(4anilino-3- sulfonatophenylazo)-4-hydroxy-2- oxidophenylazo)-6-nitro-4-sulfonato 2-naphtholato]ferrate(1-)

611-083-00-3 reaction mass of: 2-[N-ethyl-4-[(5,6- 411-560-4 STOT RE 1 H372 ** GHS08 H372 ** dichlorobenzothiazol-2-yl)azo]-m- Skin Sens. 1 H317 GHS07 H317

toludino]ethyl acetate; — Aquatic Chronic 2 H411 GHS09 H411

2-[N-ethyl-4-[(6,7- Dgr dichlorobenzothiazol-2-yl)azo]-m- toludino]ethyl acetate (1:1)

400

D050725/02

Classification Labelling Specific Conc. Limits, M-factors Notes

Index No International Chemical Identification EC No CAS No

Hazard Class and Category Hazard Pictogram, Signal Hazard Suppl. Hazard

Code(s) Statement statement Code(s) Word Code(s) statement Code(s) Code(s)

611-085-00-4 reaction mass of: 3-cyano-5-(2- 411-880-4 — Skin Sens. 1 H317 GHS07 H317 cyano-4-nitro-phenylazo)-2-(2- Aquatic Chronic 2 H411 GHS09 H411 hydroxy-ethylamino)-4-methyl-6-[3- Wng

(2- phenoxyethoxy)propylamino]pyridin e; 3-cyano-5-(2-cyano-4-nitrophenylazo)-6-(2-hydroxy- ethylamino)-4-methyl-2-[3-(2- phenoxyethoxy)propylamino]pyridin e; 3-cyano-5-(2-cyano-4-nitrophenylazo)-2-amino-4-methyl-6-[3- (3- hydroxypropoxy)propylamino]pyridi ne; 3-cyano-5-(2-cyano-4-nitrophenylazo)-6-amino-4-methyl-2-[3- (3- methoxypropoxy)propylamino]pyridi ne

611-086-00-X monolithium 5-[[2,4-dihydroxy-5- 411-360-7 — Aquatic Chronic 3 H412 — H412

[(2-hydroxy-3,5- dinitrophenyl)azo]phenyl]azo]-2- naphthalenesulfonate], iron complex, monohydrate

611-087-00-5 reaction mass of: 3-((5-cyano-1,6- 411-710-9 — Aquatic Chronic 4 H413 — H413 dihydro-1,4-dimethyl-2-hydroxyl-6-

oxo-3-pyridinyl)azo)-benzoyloxy-2- phenoxyethane; 3-((5-cyano-1,6-dihydro-1,4- dimethyl-2-hydroxy-6-oxo-3- pyridinyl)azo)-benzoyloxy-2- ethyloxy-2-(ethylphenol)

401

D050725/02

Classification Labelling Specific Conc. Limits, M-factors Notes

Index No International Chemical Identification EC No CAS No

Hazard Class and Category Hazard Pictogram, Signal Hazard Suppl. Hazard

Code(s) Statement statement statement Code(s) Word Code(s) Code(s) Code(s)

611-088-00-0 reaction mass of: trilithium 4-amino 411-890-9 Acute Tox. 4 * H302 GHS05 H302

3-((4-((4-((2-amino-4- — Eye Dam. 1 H318 GHS07 H318 hydroxyphenyl)azo)phenyl)amino)- Aquatic Chronic 3 H412 Dgr H412 3-sulfophenyl)azo)5-hydroxy-6- (phenylazo)naphthalene-2,7- disulfonate; trilithium 4-amino-3-((4-((4-((4- amino-2- hydroxyphenyl)azo)phenyl)amino)- 3-sulfophenyl)azo)-5-hydroxy-6- (phenylazo)naphthalene-2,7- disulfonate

611-089-00-6 2-((4-(ethyl-(2-hydroxyethyl)amino)- 411-100-2 136213-73-5 STOT RE 2 * H373 ** GHS08

2-methylphenyl)azo)-6-methoxy-3- Skin Sens. 1 H317 GHS07 H373 ** methyl-benzothiazolium Aquatic Acute 1 H400 GHS09 H317 methylsulfate Aquatic Chronic 1 H410 Wng H410

611-090-00-1 2,5-dibutoxy-4-(morpholin-4- 413-290-2 93672-52-7 Self-react. C H242 GHS02 H242 T yl)benzenediazonium 4- Acute Tox. 4 * H302 GHS05 H302

methylbenzenesulfonate Eye Dam. 1 H318 GHS07 H318 Skin Sens. 1 H317 Dgr H317 Aquatic Chronic 3 H412 H412

611-091-00-7 sodium (1,0-1,95)/lithium (0,051) 5- 413-470-0 134595-59-8 Skin Sens. 1 H317 GHS07 H317

((5-((5-chloro-6-fluoro-pyrimidin-4- Wng yl)amino)-2-sulfonatophenyl)azo)- 1,2-dihydro-6-hydroxy-1,4-dimethyl 2-oxo-3-pyridinemethylsulfonate

611-092-00-2 tert-(dodecyl/tetradecyl)-ammonium 413-210-6 — Aquatic Chronic 2 H411 GHS09 H411 bis(3-(4-((5-(1,1-dimethyl-propyl)-2-

hydroxy-3-nitrophenyl)azo)-3- methyl-5-hydroxy-(1H)-pyrazol-1- yl)benzenesulfonamidato)chromate

402

D050725/02

Classification Labelling Specific Conc. Limits, M-factors Notes

Index No International Chemical Identification EC No CAS No

Hazard Class and Category Hazard Pictogram, Signal Hazard Suppl. Hazard

Code(s) Statement statement statement Code(s) Word Code(s) Code(s) Code(s)

611-093-00-8 sodium 2-(4-(4-fluoro-6-(2-sulfo 410-770-3 146177-84-6 Skin Sens. 1 H317 GHS07 H317 ethylamino)-[1,3,5]triazin-2- Wng

ylamino)-2-ureido-phenylazo)-5-(4- sulfophenylazo)benzene-1-sulfonate

611-094-00-3 reaction mass of: 2-[2-acetylamino 411-600-0 143145-93-1 Aquatic Chronic 4 H413 H413

4-[N,N-bis[2-ethoxy—

carbonyloxy)ethyl]amino]phenylazo] -5,6-dichloro-1,3-benzothiazole; 2-[2-acetylamino-4-[N,N-bis[2- ethoxycarbonyloxy)ethyl]amino]phenylazo] -6,7-dichloro-1,3-benzotriazole (1:1)

611-095-00-9 hexasodium 1,1'-[(1-amino-8- 412-240-7 89797-03-5 Aquatic Chronic 2 H411 GHS09 H411

hydroxy-3,6-disulfonate-2,7- naphthalenediyl)bis(azo(4-sulfonate 1,3-phenyl)imino[6[(4-chloro-3- sulfonatophenyl)amino]-1,3,5- triazin-2,4-diyl]]]bis[3- carboxypyridinium] dihydroxide

611-096-00-4 methyl N-[3-acetylamino)-4-(2- 413-040-2 149850-30-6 Skin Sens. 1 H317 GHS07 H317 cyano-4-nitrophenylazo)phenyl]-N- Wng

[(1-methoxy)acetyl]glycinate

611-097-00-X reaction mass of iron complexes of: 414-150-3 Skin Sens. 1 H317 GHS07 H317

1,3-dihydroxy-4-[(5- — Aquatic Chronic 2 H411 GHS09 H411 phenylaminosulfonyl)-2- Wng

hydroxyphenylazo]-n-(5-aminosulfonyl-2- hydroxyphenylazo)benzene and: 1,3-dihydroxy-4-[(5- phenylaminosulfonyl)-2- hydroxyphenylazo]-n-[4-(4-nitro-2- sulfophenylamino)phenylazo]benzen e (n=2,5,6)

403

D050725/02

Classification Labelling Specific Conc. Limits, M-factors Notes

Index No International Chemical Identification EC No CAS No

Hazard Class and Category Hazard Pictogram, Signal Hazard Suppl. Hazard

Code(s) Statement statement statement Code(s) Word Code(s) Code(s) Code(s)

611-098-00-5 tetrakis(tetramethylammonium)3,3'- 405-950-3 131013-83-7 Acute Tox. 3 * Aquatic H301 GHS06 H301

(6-(2-hydroxyethylamino)1,3,5- Chronic 3 H412 Dgr H412 triazine-2,4-diylbisimino(2-methyl 4,1-phenyleneazo))bisnaphthalene 1,5-disulfonate

611-099-00-0 (methylenebis(4,1-phenylenazo(1-(3- 401-500-5 118658-99-4 Carc. 1B H350 GHS08 H350

(dimethylamino)propyl)-1,2- Aquatic Chronic 2 H411 GHS09 H411 dihydro-6-hydroxy-4-methyl-2- Dgr oxopyridine-5,3-diyl)))- 1,1'dipyridinium dichloride dihydrochloride

611-100-00-4 potassium sodium 3,3'-(3(or 4)- 403-810-6 140876-13-7 Eye Dam. 1 H318 GHS05 H318 methyl-1,2-phenylenebis(imino(6- Dgr

chloro)-1,3,5-triazine-4,2- diylimino(2-acetamido-5-methoxy)- 4,1-phenylenazo)dinaphthalene-1,5- disulfonate

611-101-00-X 2'-(4-chloro-3-cyano-5-formyl-2- 405-200-5 104366-25-8 Skin Sens. 1 H317 GHS07 H317 thienyl)azo-5'- Wng

diethylaminoacetanilide

611-102-00-5 reaction product of: C.I. Leuco 424-500-7 Aquatic Chronic 3 H412 — H412

Sulfur Black 1 and reaction mass of: — disodium-4-{4-[8-amino-1-hydroxy 7-(4-sulfamoylphenylazo)-3,6- disulfonato-2- naphthylazo]phenylsulfonylamino}b enzendiazoniumchlorid;disodium-4- {4-[2,6-dihydroxy-3-(8-hydroxy-3,6- disulfonato-1- naphthylazo)phenylazo]phenylsulfon ylamino}benzen-diazoniumchlorid

611-103-00-0 trisodium (1-(3-carboxylato-2-oxido 407-110-1 — Eye Dam. 1 H318 GHS05 H318

5-sulfonatophenylazo)-5-hydroxy-7- Skin Sens. 1 H317 GHS07 H317 sulfonatonaphthalen-2- Aquatic Chronic 2 H411 GHS09 H411 amido)nickel(II) Dgr

404

D050725/02

Classification Labelling Specific Conc. Limits, M-factors Notes

Index No International Chemical Identification EC No CAS No

Hazard Class and Category Hazard Hazard Suppl. Hazard

Code(s) Statement

Pictogram, Signal

Code(s) Word Code(s)

statement statement Code(s) Code(s)

611-104-00-6 reaction mass of: trisodium (2,4(or 406-870-1 Skin Sens. 1 H317 GHS07 H317

2,6 or 4,6)-bis(3,5-dinitro-2- — Aquatic Chronic 2 H411 GHS09 H411 oxidophenylazo)-5- Wng hydroxyphenolato)(2(or 4 or 6)-(3,5- dinitro-2-oxidophenylazo)5- hydroxy-4(or 2 or 6)-(4-(4-nitro-2- sulfonatoanilino)phenylazo)phenolat o)ferrate(1-); trisodium bis(2,4(or 2,6 or 4,6)-bis(3,5-dinitro-2- oxidophenylazo)-5- hydroxyphenolato)ferrate(1-); trisodium (2,4(or 2,6 or 4,6)-bis(3,5- dinitro-2-oxidophenylazo)-5- hydroxyphenolato)(2(or 4 or 6)-(3,5- dinitro-2-oxidophenylazo)-5- hydroxy-4(or 2 or 6)-(4-nitro-2- sulfonatophenylazo)phenolato)ferrat e(1-); trisodium (2,4(or 2,6 or 4,6)- bis(3,5-dinitro-2-oxidophenylazo)-5- hydroxyphenolato)(2(or 4 or 6)-(3,5- dinitro-2-oxidophenylazo)-5- hydroxy-4(or 2 or 6)-(3- sulfonatophenylazo)phenolato)ferrat e(1-); disodium 3,3'-(2,4-dihydroxy1,3(or 1,5 or 3,5)- phenylenediazo)dibenzenesulfonate

611-105-00-1 sodium 4-(4-chloro-6-(N- 407-800-2 136213-75-7 Skin Sens. 1 H317 GHS07 H317 ethylanilino)-1,3,5-triazin-2- Aquatic Chronic 2 H411 GHS09 H411 ylamino)-2-(1-(2-chlorophenyl)-5- Wng

hydroxy-3-methyl-1H-pyrazol-4- ylazo)benzenesulfonate

611-106-00-7 hexasodium 4,4'-dihydroxy-3,3'- 410-180-6 157627-99-1 Eye Dam. 1 H318 GHS05 H318 bis[2-sulfonato-4-(4- Dgr

sulfonatophenylazo)phenylazo]- 7,7'[p-phenylenebis[imino(6-chloro 1,3,5-triazine-4,2- diyl)imino]]dinaphthalene-2- sulfonate

405

D050725/02

Classification Labelling Specific Conc. Limits, M-factors Notes

Index No International Chemical Identification EC No CAS No

Hazard Class and Category Hazard Suppl. Hazard

Code(s) Statement

Pictogram, Signal Hazard statement statement

Code(s) Word Code(s) Code(s) Code(s)

611-107-00-2 potassium sodium 4-(4-chloro-6-(3,6- 412-490-7 — Skin Sens. 1 H317 GHS07 H317 disulfonato-7-(5,8-disulfonato Wng

naphthalen-2-ylazo)-8-hydroxynaphthalen-1-ylamino)-1,3,5-triazin-2- ylamino)-5-hydroxy-6-(4-(2- sulfatoethanesulfonyl)-phenylazo)- naphthalene-1,7-disulfonate

611-108-00-8 disodium 5-((4-((4-chloro-3- 413-600-6 6527-62-4 Aquatic Chronic 3 H412 — H412 sulfonatophenyl)azo)-1-naphthyl)azo)-

8-(phenylamino)-1- naphthalenesulfonate

611-109-00-3 reaction products of: copper(II) 407-710-3 — Aquatic Chronic 2 H411 GHS09 H411 sulfate and tetrasodium 2,4-bis[6-(2-

methoxy-5-sulfonatophenylazo)-5- hydroxy-7-sulfonato-2- naphthylamino]-6-(2- hydroxyethylamino)-1,3,5-triazine (2:1)

    tetra-sodium/lithium 4,4'-bis-(8-

611-110-00-9 amino-3,6-disulfonato-1-naphthol-2- 408-210-8 124605-82-9 Skin Sens. 1 H317

GHS07

ylazo)-3-methylazobenzene Aquatic Chronic 2 H411

GHS09 H317

Wng H411

    disodium 2-[[4-(2- chloroethylsulfonyl)phenyl]-[(2-

611-111-00-4 hydroxy-5-sulfo-3-[3-[2-(2- 414-230-8 — Skin Sens. 1 H317 GHS07 H317

(sulfooxy)ethylsulfonyl)ethylazo]-4- Wng

sulfobenzoato(3-)cuprate(1-)

611-112-00-X tetrasodium 4-hydroxy-5-[4-[3-(2- 413-070-6 — Skin Sens. 1 H317 GHS07 H317 sulfatoethanesulfonyl)phenylamino]-6- Wng

morpholin-4-yl-1,3,5-triazin-2- ylamino]-3-(1-sulfonatonaphthalen-2- ylazo)naphthalene-2,7-disulfonate

406

D050725/02

Classification Labelling Specific Conc. Limits, M-factors Notes

Index No International Chemical Identification EC No CAS No

Hazard Class and Category Hazard Hazard Suppl. Hazard

Code(s) Statement

Pictogram, Signal statement statement

Code(s) Word Code(s) Code(s) Code(s)

611-113-00-5 lithium sodium (2-(((5-((2,5- 414-280-0 149626-00-6 Aquatic Chronic 2 H411 GHS09 H411 dichlorophenyl)azo)-2-

hydroxyphenyl)methylene)amino)benz oato(2-))(2-((4,5-dihydro-3-methyl-5- oxo-1-phenyl-1H-pyrazol-4-yl)azo)-5- sulfobenzoato(3-)) chromate(2-)

611-114-00-0 lithium sodium (4-((5-chloro-2- 414-250-7 149564-66-9 Acute Tox. 4 * H302 GHS05 H302 hydroxyphenyl)azo)-2,4-dihydro-5- Eye Dam. 1 H318 GHS07 H318 methyl-3H-pyrazol-3-onato(2-))(3- Aquatic Chronic 3 H412 Dgr H412 ((4,5-dihydro-3-methyl-1-(4-

methylphenyl)-5-oxo-1H-pyrazol-4- yl)azo)-4-hydroxy-5- nitrobenzenesulfonato(3-)) chromate(2-)

611-115-00-6 trilithium bis(4-((4-(diethylamino)-2- 414-290-5 149564-65-8 Acute Tox. 4 * H302 GHS07 H302 hydroxyphenyl)azo)-3-hydroxy-1- Aquatic Chronic 3 H412 Wng H412 naphthalenesulfonato(3-))chromate(3-)

407

D050725/02

Classification Labelling Specific Conc. Limits, M-factors Notes

Index No International Chemical Identification EC No CAS No

Hazard Class and Category Hazard Hazard Suppl. Hazard

Code(s) Statement

Pictogram, Signal statement statement

Code(s) Word Code(s) Code(s) Code(s)

611-116-00-1 reaction mass of: trisodium 5{4- 414-620-8 — Eye Dam. 1 H318 GHS05 H318 chloro-6-[2-(2,6-dichloro-5- Skin Sens. 1 H317 GHS07 H317 cyanopyrimidin-4-ylamino)- Dgr

propylamino]-1,3,5-triazin-2- ylamino}-4-hydroxy-3-(1- sulfonatonaphthalene-2-ylazo)- naphthalene-2,7-disulfonate;

trisodium 5-{4-chloro-6-[2-(2,6- dichloro-5-cyanopyrimidin-4- ylamino)-1-methyl-ethylamino]- 1,3,5-triazin-2-ylamino}-4-hydroxy 3-(1-sulfonatonaphthalene-2-ylazo)- naphthalene-2,7-disulfonate;

trisodium 5-{4-chloro-6-[2-(4,6- dichloro-5-cyanopyrimidin-2- ylamino)-propylamino]-1,3,5-triazin 2-ylamino}-4-hydroxy-3-(1- sulfonatonaphthalen-2-ylazo)- naphthalene-2,7-disulfonate;

trisodium 5-{4-chloro-6-[2-(4,6- dichloro-5-cyanopyrimidin-2- ylamino)-1-methyl-ethylamino]- 1,3,5-triazin-2-ylamino}-4-hydroxy 3-(1-sulfonatonaphthalen-2-ylazo)- naphthalene-2,7-disulfonate

611-117-00-7 1,3-bis{6-fluoro-4-[1,5-disulfo-4-(3- 415-100-3 149850-29-3 Skin Sens. 1 H317 GHS07 H317 aminocarbonyl-1-ethyl-6-hydroxy-4- Wng

methyl-pyrid-2-on-5-ylazo)-phenyl 2-ylamino]-1,3,5-triazin-2- ylamino}propane lithium-, sodium salt

408

D050725/02

Classification Labelling Specific Conc. Limits, M-factors Notes

Index No International Chemical Identification EC No CAS No

Hazard Class and Category Hazard Pictogram, Signal Hazard Suppl. Hazard

Code(s) Statement statement statement Code(s) Word Code(s) Code(s) Code(s)

611-118-00-2 sodium 1,2-bis[4-[4-{4-(4- 413-990-8 Skin Sens. 1 H317 GHS07 H317 sulfophenylazo)-2-sulfophenylazo}- Wng

2-ureido-phenyl-amino]-6-fluoro 1,3,5-triazin-2-ylamino]-propane, sodium salt

611-119-00-8 tetrasodium 4-[4-chloro-6-(4-methyl 415-400-4 148878-22-2 Eye Dam. 1 H318 GHS05 H318

2-sulfophenylamino)-1,3,5-triazin-2- Skin Sens. 1 H317 GHS07 H317 ylamino]-6-(4,5-dimethyl-2- Dgr sulfophenylazo)-5- hydroxynaphthalene-2,7-disulfonate

611-120-00-3 5-{4-[5-amino-2-[4-(2- 418-340-7 157707-94-3 Eye Dam. 1 H318 GHS05 H318 sulfoxyethylsulfonyl)phenylazo]-4- Aquatic Chronic 3 H412 Dgr H412 sulfo-phenylamino]-6-chloro-1,3,5-

triazin-2-ylamino}-4-hydroxy-3-(1- sulfo-naphthalen-2-ylazo)- naphthalene-2,7-disulfonicacid sodium salt

611-121-00-9 main component 6 (isomer): asym. 417-280-9 30785-74-1 Eye Dam. 1 H318 GHS05 H318

1:2 Cr(III)-complex of: A: 3- Aquatic Acute 1 H400 GHS09 H410 hydroxy-4-(2-hydroxy-naphthalene Aquatic Chronic 1 H410 Dgr 1-ylazo)naphthalene-1-sulfonic acid, Na-salt and B: 1-[2-hydroxy-5-(4- methoxyphenylazo)phenylazo]naphthalene-2- ol; main component 8 (isomer): asym. 1:2 Cr-complex of: A: 3-hydroxy-4-(2-hydroxynaphthalene-1-ylazo)-naphthalene-1- sulfonic acid, Na-salt and B: 1-[2- hydroxy-5-(4-methoxy-phenylazo)- phenylazo]-naphthalene-2-ol

409

D050725/02

Classification Labelling Specific Conc. Limits, M-factors Notes

Index No International Chemical Identification EC No CAS No

Hazard Class and Category Hazard Pictogram, Signal Hazard Suppl. Hazard

Code(s) Statement statement Code(s) Word Code(s) statement Code(s) Code(s)

611-122-00-4 hexasodium (di[N-(3-(4-[5-(5- 417-250-5 151436-99-6 Eye Dam. 1 H318 GHS05 H318 amino-3-methyl-1-phenylpyrazol-4- Skin Sens. 1 H317 GHS07 H317 yl-azo)-2,4-disulfo-anilino]-6- Dgr

chloro-1,3,5-triazin-2- ylamino)phenyl)-sulfamoyl](disulfo)-phthalocyaninato)nickel

611-123-00-X 3-(2,4-bis(4-((5-(4,6-bis(2- 424-310-4 178452-66-9 Eye Dam. 1 H318 GHS05 H318 aminopropylamino)-1,3,5-triazin-2- Dgr

ylamino)-4-hydroxy-2,7- disulfonaphthalen-3- yl)azo)phenylamino)-1,3,5-triazin-6- ylamino)propyldiethylammonium lactate

611-124-00-5 reaction mass of: pentasodium 424-320-9 Eye Dam. 1 H318 GHS05 H318

5-amino-3-(5-{4-chloro-6-[4-(2- Aquatic Chronic 2 H411 GHS09 H411 sulfoxyethoxysulfonato)phenylamino Dgr ]-1,3,5-triazin-2-ylamino}-2- sulfonatophenylazo)-6-[5-(2,3- dibromopropionylamino)-2- sulfonatophenylazo]-4- hydroxynaphthalene-2,7-disulfonate; pentasodium 5-amino-6-[5-(2- bromoacryloylamino)-2- sulfonatophenylazo]-3-(5-{4-chloro 6-[4-(2- sulfoxyethoxysulfonato)phenylamino ]-1,3,5-triazin-2-ylamino}-2- sulfonatophenylazo)-4- hydroxynaphthalene-2,7-disulfonate; tetrasodium 5-amino-3-[5-{4-chloro 6-[4-(vinylsulfonyl)phenylamino]- 1,3,5-triazin-2-ylamino}-2- sulfonatophenylazo]-6-[5-(2,3- dibromopropionylamino)-2- sulfonatophenylazo]-4- hydroxynaphthalene-2,7-disulfonate

410

D050725/02

Classification Labelling Specific Conc. Limits, M-factors Notes

Index No International Chemical Identification EC No CAS No

Hazard Class and Category Hazard Suppl. Hazard

Code(s) Statement

Pictogram, Signal Hazard statement

Code(s) Word Code(s)

statement Code(s) Code(s)

611-125-00-0 reaction mass of: disodium 6-[3- 423-940-7 — Eye Dam. 1 H318 GHS05 H318 carboxy-4,5-dihydro-5-oxo-4- Aquatic Chronic 2 H411 GHS09 H411 sulfonatophenyl)pyrazolin-4-yl-azo]- Dgr

3-[2-oxido-4-(ethensulfonyl)-5- methoxyphenylazo]-4- oxidonaphthalene-2-sulfonate copper (II) complex; disodium 6-[3-carboxy-4,5-dihydro 5-oxo-4-sulfonatophenyl)pyrazolin 4-yl-azo]-3-[2-oxido-4-(2- hydroxyethylsulfonyl)-5- methoxyphenylazo]-4- oxidonaphthalene-2-sulfonate copper (II) complex

611-126-00-6 2,6-bis-(2-(4-(4-amino 424-120-1 174514-06-8 Eye Dam. 1 H318 GHS05 H318 phenylamino)-phenylazo)-1,3- Aquatic Acute 1 H400 GHS09 H410 dimethyl-3H-imidazolium)-4- Aquatic Chronic 1 H410 Dgr

dimethylamino-1,3,5-triazine, dichloride

611-127-00-1 pentasodium 4-amino-6-(5-(4-(2- 423-790-2 Eye Dam. 1 H318 GHS05 H318 G ethyl-phenylamino)-6-(2- Skin Sens. 1 H317 GHS07 H317

sulfatoethanesulfonyl)-1,3,5-triazin Aquatic Chronic 3 H412 Dgr H412

2-ylamino)-2-sulfonatophenylazo)-5- —

hydroxy-3-(4-(2- sulfatoethanesulfonyl)phenylazo)nap hthalene-2,7-disulfonate

611-128-00-7 N,N'-bis{6-chloro-4-[6-(4- 419-500-9 171599-85-2 Eye Dam. 1 H318 GHS05 H318 vinylsulfonylphenylazo)-2,7- Skin Sens. 1 H317 GHS07 H317 disulfonicacid-5-hydroxynapht-4- Dgr

ylamino]-1,3,5-triazin-2-yl}-N-(2- hydroxyethyl)ethane-1,2-diamine, sodium salt

411

D050725/02

Classification Labelling Specific Conc. Limits, M-factors Notes

Index No International Chemical Identification EC No CAS No

Hazard Class and Category Hazard Suppl. Hazard

Code(s) Statement

Pictogram, Signal Hazard statement statement

Code(s) Word Code(s) Code(s) Code(s)

611-129-00-2 reaction mass of: 5-[(4-[(7-amino-1- 418-230-9 163879-69-4 Expl. 1.3 **** H203 GHS01 H203 hydroxy-3-sulfo-2-naphthyl)azo]- Repr. 2 H361f *** GHS08 H361f *** 2,5-diethoxyphenyl)azo]-2-[(3- STOT RE 2 * H373 ** GHS07 H373 ** phosphonophenyl)azo]benzoic acid; Skin Sens. 1 H317 GHS09 H317 5-[(4-[(7-amino-1-hydroxy-3-sulfo Aquatic Chronic 2 H411 Dgr H411

2-naphthyl)azo]-2,5- diethoxyphenyl)azo]-3-[(3- phosphonophenyl)azo]benzoic acid

611-130-00-8 tetra-ammonium 2-[6-[7-(2- 418-520-5 183130-96-3 Eye Irrit. 2 H319 GHS07 H319 carboxylato-phenylazo)-8-hydroxy Aquatic Chronic 3 H412 Wng H412

3,6-disulfonato-1-naphthylamino]-4- hydroxy-1,3,5-triazin-2- ylamino]benzoate

611-131-00-3 2-[2-hydroxy-3-(2- 420-580-2 151798-26-4 Repr. 1B H360D *** GHS08 H360D *** chlorophenyl)carbamoyl-1- Aquatic Chronic 4 H413 Dgr H413

naphthylazo]-7-[2-hydroxy-3-(3- methylphenyl)carbamoyl-1- naphthylazo]fluoren-9-one

611-132-00-9 pentasodium bis{7-[4-(1-butyl-5- 419-210-2 178452-71-6 Eye Dam. 1 H318 GHS05 H318 cyano-1,2-dihydro-2-hydroxy-4- Aquatic Chronic 3 H412 Dgr H412

methyl-6-oxo-3- pyridylazo)phenylsulfonylamino]-5'- nitro-3,3'-disulfonatonaphthalene-2- azobenzene-1,2'-diolato} chromate (III)

412

D050725/02

Classification Labelling Specific Conc. Limits, M-factors Notes

Index No International Chemical Identification EC No CAS No

Hazard Class and Category Hazard Suppl. Hazard

Code(s) Statement

Pictogram, Signal Hazard statement

Code(s) Word Code(s)

statement Code(s) Code(s)

611-133-00-4 product by process iron complex of 419-260-5 Eye Dam. 1 H318 GHS05 H318 azo dyestuffs obtained by coupling — Aquatic Chronic 2 H411 GHS09 H411 a mixture of diazotized 2-amino-1- Dgr

hydroxybenzene-4-sulfanilide and 2- amino-1-hydroxybenzene-4- sulfonamide with resorcin, the obtained mixture being subsequently submitted to a second coupling reaction with a mixture of diazotized 3-aminobenzene-1- sulfonic acid (metanilic acid) and 4'- amino-4-nitro-1,1'-diphenylamine-2- sulfonic acid and metallization with ferric chloride, sodium salt

611-134-00-X trisodium 2-{α[2-hydroxy-3-[4- 423-770-3 Eye Dam. 1 H318 GHS05 H318

chloro-6-[4-(2,3- — Aquatic Chronic 2 H411 GHS09 H411 dibromopropionylamino)-2- Dgr sulfonatophenylamino]-1,3,5-triazin 2-ylamino]-5-sulfonatophenylazo]- benzylidenehydrazino}-4- sulfonatobenzoate, copper complex

611-135-00-5 reaction product of : 2-[[4-amino-2- 424-250-9 Eye Dam. 1 H318 GHS05 H318 ureidophenylazo]-5-[(2- — Aquatic Chronic 3 H412 Dgr H412 (sulfooxy)ethyl)sulfonyl]]benzenesul

fonic acid with 2,4,6- trifluoropyrimidine and partial hydrolysis to the corresponding vinylsulfonyl derivative, mixed potassium/sodium salt

611-136-00-0 2-{4-(2-ammoniopropylamino)-6-[4- 424-260-3 — Repr. 2 H361f *** GHS05 H361f *** hydroxy-3-(5-methyl-2-methoxy-4- Eye Dam. 1 H318 GHS08 H318

sulfamoylphenylazo)-2- Aquatic Chronic 2 H411 GHS09 H411 sulfonatonaphth-7-ylamino]-1,3,5- Dgr triazin-2-ylamino}-2-aminopropyl formate

413

D050725/02

Classification Labelling Specific Conc. Limits, M-factors Notes

Index No International Chemical Identification EC No CAS No

Hazard Class and Category Hazard Suppl. Hazard

Code(s) Statement

Pictogram, Signal Hazard statement statement

Code(s) Word Code(s) Code(s) Code(s)

611-137-00-6 6-tert-butyl-7-chloro-3-tridecyl-7,7a 419-870-1 159038-16-1 Aquatic Chronic 4 H413 — H413 dihydro-1H-pyrazolo[5,1-c]-1,2,4-

triazole

611-138-00-1 2-(4-aminophenyl)-6-tert-butyl-1H- 415-910-7 152828-25-6 Skin Sens. 1 H317 GHS07 H317 pyrazolo[1,5-b][1,2,4]triazole Aquatic Chronic 2 H411 GHS09 H411 Wng

611-139-00-7 reaction product of: C.I. Leuco 424-510-1 Eye Dam. 1 H318 GHS05 H318

Sulfur Black 1 with (3-chloro-2- — Aquatic Chronic 2 H411 GHS09 H411 hydroxypropyl)trimethylammonium Dgr chloride

611-140-00-2 azafenidin (ISO); 68049-83-2 Repr. 1B H360Df GHS08 H360Df M = 1 000

2-(2,4-dichloro-5-prop-2- — STOT RE 2 * H373 ** GHS09 H373 ** ynyloxyphenyl)-5,6,7,8-tetrahydro Aquatic Acute 1 H400 Dgr H410 1,2,4-triazolo[4,3-a]pyridine-3(2H)- Aquatic Chronic 1 H410

one

611-141-00-8 5-(4-[4-[4-(3,5-dicarboxy-phenyl 414-410-6 Eye Dam. 1 H318 GHS05 H318 azo)phenylamino]-6-morpholin-4-yl— Skin Sens. 1 H317 GHS07 H317 1,3,5-triazin-2- Dgr

ylamino]phenylazo)isophthalic acid, mixed monosodium and diammonium salt

414

D050725/02

Classification Labelling Specific Conc. Limits, M-factors Notes

Index No International Chemical Identification EC No CAS No

Hazard Class and Category Hazard Hazard Suppl. Hazard

Code(s) Statement

Pictogram, Signal

Code(s) Word Code(s)

statement statement Code(s) Code(s)

611-142-00-3 product-by-process definition 425-740-5 — Eye Dam. 1 H318 GHS05 H318 polyazodyestuff obtained by Aquatic Chronic 3 H412 Dgr H412 coupling 4-[4-(1-amino-8-hydroxy

3,6-disulfo-2- naphthylazo)phenylsulfonylamino] benzenediazonium with reaction mass of 4-carboxybenzenediazonium and diphenylamine-3-sulfo-4,4'- bisdiazonium, and further coupling of the obtained compounds with reaction mass of naphth-2-ol and 3- aminophenol, sodium salts; sodium chloride

611-143-00-9 reaction mass of: trisodium 2-(2-[α- 428-260-4 Eye Dam. 1 H318 GHS05 H318

(2-carboxylato-κ-O-4- Dgr

sulfonatophenylazo)benzylidene]hyd razino-κ-N')-6-(2,6- difluoropyrimidin-4-ylamino)-4-

sulfonatophenolatocuprate (II); —

trisodium 2-(2-[α-(2-carboxylato-κ- O-4- sulfonatophenylazo)benzylidene]hyd razino-κ-N')-6-(4,6- difluoropyrimidin-2-ylamino)-4- sulfonatophenolatocuprate (II)

415

D050725/02

Classification Labelling Specific Conc. Limits, M-factors Notes

Index No International Chemical Identification EC No CAS No

Hazard Class and Category Hazard Hazard Suppl. Hazard

Code(s) Statement

Pictogram, Signal

Code(s) Word Code(s)

statement statement Code(s) Code(s)

611-144-00-4 reaction mas of: 7-amino-3,8-bis-[4- 429-070-4 214362-06-8 Eye Dam. 1 H318 GHS05 H318

(2-sulfoxyethylsulfonyl)phenylazo]- Dgr 4-hydroxynaphthalene-2-sulfonic acid, Na/K salt; 7-amino-3-[4-(2- sulfoxyethylsulfonyl)phenylazo]-4- hydroxy-8-[4-(2- sulfoxyethylsulfonyl)-2- sulfophenylazo]naphthalene-2- sulfonic acid, Na/K salt; 7-amino-8- [4-(2-sulfoxyethylsulfonyl)- phenylazo]-4-hydroxy-3-[4-(2- sulfoxyethylsulfonyl)-2- sulfophenylazo]naphthalene-2- sulfonic acid, Na/K salt; 7-amino 3,8-bis-[4-(2-sulfoxyethylsulfonyl)- 2-sulfophenylazo]-4- hydroxynaphthalene-2-sulfonic acid, Na/K salt

611-145-00-X reaction mass of: tetrasodium 3-(1,5- 429-440-5 — Eye Dam. 1 H318 GHS05 H318 disulfonatonaphthalene-2-ylazo)-4- Dgr

hydroxy-7-{4-chloro-6-[4-(2- sulfoxyethylsulfonyl)phenylamino]- 1,3,5-triazine-2- ylamino}naphthalene-2-sulfonate; 3-(2,5-disulfophenylazo)-4-hydroxy 7-{4-chloro-6-[4-(2- sulfoxyethylsulfonyl)phenylamino{- 1,3,5-triazine-2- ylamino}naphthalene-2-sulfonic acid, sodium salt

416

D050725/02

Classification Labelling Specific Conc. Limits, M-factors Notes

Index No International Chemical Identification EC No CAS No

Hazard Class and Category Hazard Pictogram, Signal Hazard Suppl. Hazard

Code(s) Statement statement Code(s) Word Code(s) statement Code(s) Code(s)

— 611-146-00-5 reaction mass of: pentasodium 430-070-1 Aquatic Chronic 2 H411 GHS09 H411

3-(4-(4-(7-(2,4-diamino-5-sulfonato 3-(4-sulfonatophenylazo)phenylazo)- 1-hydroxy-3-sulfonatonaphthalen-2- ylazo)-2- sulfonatophenylamino)phenylazo)-4- hydroxy-6-(2-oxo-1- phenylcarbamoylpropylazo)naphthal ene-2-sulfonate; pentasodium 6- ((2,4-diamino-5- sulfonatophenyl)azo)-3-((4-((4-((7- ((2,4-diamino-5- sulfonatophenyl)azo)-1-hydroxy-3- sulfonatonaphthalen-2- yl)azo)phenyl)amino)-2- sulfonatophenyl)azo)-4- hydroxynaphthalene2-sulfonate; pentasodium 6-((2,4-diamino-5- sulfonato-3-((4- sulfonatophenyl)azo)phenyl)azo)-3- ((4-((4-((1,7-dihydroxy-3- sulfonatonaphthalen-2-yl)azo)-2- sulfonatophenyl)amino)phenyl)azo)- 4-hydroxynaphthalene-2-sulfonate; hexasodium 6-((2,4-diamino-5- sulfonatophenyl)azo)-3-((4-((4-((7- ((2,4-diamino-5-sulfonato-3-((4- sulfonatophenyl)azo)phenyl)azo)-1- hydroxy-3-sulfonatonaphthalen-2- yl)azo)-2- sulfonatophenyl)amino)phenyl)azo)- 4-hydroxynaphthalene-2-sulfonate

611-147-00-0 sodium, potassium, lithium 5- 430-090-0 205764-96-1 Eye Dam. 1 H318 GHS05 H318 amino-3,6-bis(5-(4-chloro-6- Skin Sens. 1 H317 GHS07 H317 (methyl-(2- Dgr

methylaminoacetyl)amino)-1,3,5- triazin-2-ylamino)-2- sulfonatophenylazo)-4- hydroxynaphthalene-2,7-disulfonate

417

D050725/02

Classification Labelling Specific Conc. Limits, M-factors Notes

Index No International Chemical Identification EC No CAS No

Hazard Class and Category Hazard Pictogram, Signal Hazard Suppl. Hazard

Code(s) Statement statement statement Code(s) Word Code(s) Code(s) Code(s)

611-148-00-6 reaction mass of: 2-(3-(2,6-dichloro 429-590-1 Skin Sens. 1 H317 GHS07 H317

4-nitrophenylazo)carbazol-9- — Aquatic Acute 1 H400 GHS09 H410 yl)ethanol; Aquatic Chronic 1 H410 Wng 2-(2-(3-(2,6-dichloro-4-nitrophenylazo)-carbazol-9- yl)ethoxy)ethanol; 3-(2,6-dichloro-4- nitrophenylazo)carbazol

611-149-00-1 2-(2-chloroacetoxy)ethyl 3-((4-(2,5- 427-570-7 193486-83-8 Aquatic Chronic 2 H411 GHS09 H411 dichloro-4-fluorosulfonylphenylazo)-

3- methylphenyl)ethylamino)propionate

611-150-00-7 tetralithium 2-[6-[7-[2- 440-460-3 Eye Irrit. 2 H319 GHS07 H319

(carboxylato)phenylazo]-8-hydroxy Aquatic Chronic 3 H412 Wng H412

3,6-disulfonato-1-naphthylamino]-4- —

hydroxy-1,3,5-triazine-2- ylamino]benzoate

611-151-00-2 chrysoidine; 207-803-7 495-54-5 Muta. 2 H341 GHS08 H341

4-(phenylazo)benzene-1,3-diamine Acute Tox. 4 * H302 GHS07 H302 Skin Irrit. 2 H315 GHS09 H315 Aquatic Acute 1 H400 Wng H410 Aquatic Chronic 1 H410

418

D050725/02

Classification Labelling Specific Conc. Limits, M-factors Notes

Index No International Chemical Identification EC No CAS No

Hazard Class and Category Hazard Pictogram, Signal Hazard Suppl. Hazard

Code(s) Statement statement statement Code(s) Word Code(s) Code(s) Code(s)

611-152-00-8 chrysoidine monohydrochloride; 208-545-8 [1] 532-82-1 [1] Muta. 2 H341 GHS05 H341

4-phenylazophenylene-1,3-diamine 278-290-5 [2] 75660-25-2 [2] Acute Tox. 4 * H302 GHS08 H302 monohydrochloride; [1] chrysoidine 279-116-0 [3] 79234-33-6 [3] Skin Irrit. 2 H315 GHS07 H315 monoacetate; 264-409-8 [4] 63681-54-9 [4] Eye Dam. 1 H318 GHS09 H318 4-(phenylazo)benzene-1,3-diamine 281-549-5 [5] 83968-67-6 [5] Aquatic Acute 1 H400 Dgr H410 monoacetate; [2] 282-432-1 [6] 84196-22-5 [6] Aquatic Chronic 1 H410 chrysoidine acetate; 4-(phenylazo)benzene-1,3-diamine acetate; [3] chrysoidine-p- dodecylbenzenesulfonate; dodecylbenzenesulfonic acid, compound with 4- (phenylazo)benzene-1,3-diamine (1:1); [4] chrysoidine dihydrochloride; 4-(phenylazo)benzene-1,3-diamine dihydrochloride; [5] chrysoidine sulfate; bis[4-(phenylazo)benzene-1,3- diamine] sulfate [6]

611-153-00-3 chrysoidine C 10-14 -alkyl derivatives; 286-946-7 [1] 85407-90-5 [1] Muta. 2 H341 GHS05 H341 benzenesulfonic acid, mono-C 10-14 - 304-236-8 [2] 94247-67-3 [2] Acute Tox. 4 * H302 GHS08 H302 alkyl derivatives, compounds Skin Irrit. 2 H315 GHS07 H315 with 4-(phenylazo)-1,3- Eye Dam. 1 H318 Dgr H318 benzenediamine; [1]

chrysoidine compound with dibutylnaphthalene sulfonic acid; dibutylnaphthalenesulfonic acid, compound with 4- (phenylazo)benzene-1,3-diamine

(1:1) [2]

611-154-00-9 trisodium 5-benzamido-4-hydroxy-3- 403-670-6 92408-46-3 Aquatic Chronic 3 H412 — H412

(4-methyl-2- sulfonatophenylazo)naphthalene-2,7- disulfonate

419

D050725/02

Classification Labelling Specific Conc. Limits, M-factors Notes

Index No International Chemical Identification EC No CAS No

Hazard Class and Category Hazard Hazard Suppl. Hazard

Code(s) Statement

Pictogram, Signal statement

Code(s) Word Code(s)

statement Code(s) Code(s)

611-155-00-4 4,4'-oxybis(benzenesulfonylazide) 431-850-4 7456-68-0 Expl. 1.1**** H201 GHS01 H201

STOT RE 2 * H373** GHS08 H373** Aquatic Acute 1 H400 GHS09 H410 Aquatic Chronic 1 H410 Dgr

611-156-00-X triammonium 4-[4-[7-(4- 432-270-4 221354-37-6 Repr. 2 H361f*** GHS08 H361f*** carboxylatoanilino)-1-hydroxy3- STOT RE 2 * H373** GHS09 H373** sulfonato-2-naphthylazo]-2,5- Aquatic Chronic 2 H411 Wng H411

dimethoxyphenylazo]benzoate

611-157-00-5 benzenesulfonic acid, 3,3'- 432-590-4 243869-48-9 Eye Irrit. 2 H319 GHS07 H319

(methylenebis((dihydroxyphenylene) Aquatic Chronic 3 H412 Wng H412 azo)) bis-, potassium sodium salt; potassium sodium 3-[(E)-(6{3,4- dihydroxy-2-}(Z)-(3- sulfonatophenyl)diazenyl]benzyl}- 2,3- dihydroxyphenyl)diazenyl]benzenes ulfonate

611-158-00-0 reaction product of: 2,3,4,2', 3', 421-520-8 — **** **** H413 **** **** H413

4'-hexahydroxy-5,5'-diacethyl Aquatic Chronic 4 diphenylmethane and 6-diazo-5,6- dihydro-5-oxo-1- naphthalenesulfonylchloride and 3- diazo-3,4-dihydro-6-methoxy-4-oxo 1-naphthalenesulfonylchloride

611-159-00-6 disodium 4-amino-6-((4-((4-(2,4- 421-880-6 Eye Dam. 1 H318 GHS05 H318 diaminophenyl)azo)phenylsulfamoyl — Aquatic Chronic 3 H412 Dgr H412 )phenyl)azo)-5-hydroxy-3-((4-

nitrophenyl)azo)naphthalene-2,7- disulfonate

420

D050725/02

Classification Labelling Specific Conc. Limits, M-factors Notes

Index No International Chemical Identification EC No CAS No

Hazard Class and Category Hazard Suppl. Hazard

Code(s) Statement

Pictogram, Signal Hazard statement statement

Code(s) Word Code(s) Code(s) Code(s)

611-160-00-1 reaction mass of: 1,1,1-tris(phenyl 422-760-6 — **** **** H413 **** **** H413

4'-(3''-diazo-3'', 4''-dihydro-4''-oxo Aquatic Chronic 4 naphthalene-1''-sulfonato)ethane; 1,1,1-tris(phenyl-4'-(6''-diazo-5'', 6''-dihydro-5''-oxo-naphthalene1''- sulfonato)ethane; reaction product of 1,1,1-tris(p- hydroxyphenyl)ethane with 6-diazo 5,6-dihydro-5-oxo-1- naphthylsulfonylchloride and 3- diazo-3,4-dihydro-4-oxo-1- naphthylsulfonylchloride (2:1); reaction product of 1,1,1-tris(p- hydroxyphenyl)ethane with 6-diazo 5,6-dihydro-5-oxo-1- naphthylsulfonylchloride and 3- diazo-3,4-dihydro-4-oxo-1- naphthylsulfonylchloride (1:2)

611-161-00-7 trisodium [1,2'-(2-(8-amino-3,5- 423-100-1 Eye Dam. 1 H318 GHS05 H318 disulfonatonaphthalene)azo)-(4'- Dgr

nitrobenzene)diolato-O,O,N][(Z)- 2,2-((phenylcarbamoylprop-1'-

enyl)azo)-5- —

sulfamoylbenzene)diolato O,O,N]chromate(III)

611-162-00-2 2,4-bis(((2- 429-600-4 Acute Tox. 4 * H302 GHS05 H302

(dimethylammonio)ethyloxy)carbon Eye Dam. 1 H318 GHS07 H318 yl)phen-2-ylazo)benzene-1,3- Aquatic Chronic 2 H411 GHS09 H411 diolbis(methanesulfonate) Dgr

—

611-163-00-8 2,4-bis(((2- 429-610-9 — Acute Tox. 4 * H302 GHS05 H302

(dimethylammonio)ethyloxy)carbon Eye Dam. 1 H318 GHS07 H318 yl)phen-2-ylazo)benzene-1,3-diol Aquatic Chronic 2 H411 GHS09 H411 sulfate Dgr

421

D050725/02

Classification Labelling Specific Conc. Limits, M-factors Notes

Index No International Chemical Identification EC No CAS No

Hazard Class and Category Hazard Pictogram, Signal Hazard Suppl. Hazard

Code(s) Statement statement statement Code(s) Word Code(s) Code(s) Code(s)

611-164-00-3 reaction mass of: 2,2’-dimethyl-2,2’- 429-710-2 — Self-react. D H242 GHS02 H242 azobutanenitrile; Acute Tox. 4 * H302 GHS07 H302 2-methylpentanenitrile-2-azo-2’-(2’- Aquatic Chronic 2 H411 GHS09 H411 methylpropanenitrile); Dgr

2,2’-dimethyl-2,2’-azoheptanenitrile; 2-methylheptanenitrile-2-azo-2’-(2’- methylpropanenitrile); 2-methylheptanenitrile-2-azo-2’-(2’- methylbutanenitrile)

611-165-00-9 reaction mass of: tetrasodium -4- 431-830-5 Aquatic Chronic 3 H412 — H412 amino-6-(5-(2,6-difluoropyrimidin

4-ylamino)-2-sulfonatophenylazo)-5-

hydroxy-3-(4- —

(sulfatoethylsulfonyl)phenylazo)nap hthalene-2,7-disulfonate; tetrasodium 4-amino-6-(5-(4,6- difluoropyrimidin-2-ylamino)-2- sulfonatophenylazo)-5-hydroxy-3-(4- (2- sulfatoethylsulfonyl)phenylazo)napht halene-2,7-disulfonate

611-166-00-4 reaction mass of: pentasodium 432-100-9 Eye Dam. 1 H318 GHS05 H318

4-amino-5-hydroxy-3-{(E)-4-[2- Aquatic Chronic 3 H412 Dgr H412 (sulfonatooxy)ethylsulfonyl]phenyla

zo}-6-{(E)-2-sulfonato-4-[2- —

(sulfonatooxy)ethylsulfonyl]phenyla zo}naphthalene-2,7-disulfonate; tetrasodium 4-amino-5-hydroxy-3- {(E)-4-[2- (sulfonatooxy)ethylsulfonyl]phenyla zo}-6-[(E)-2-sulfonato-4- (vinylsulfonyl)phenylazo]naphthalen e-2,7-disulfonate; tetrasodium -4- amino-5-hydroxy-6-(E)-2-sulfonato 4-}2- (sulfonatooxy)ethylsulfonyl{phenyla zo}-3-[(E)-4- (vinylsulfonyl)phenylazo]naphthalen e-2,7-disulfonate

422

D050725/02

Classification Labelling Specific Conc. Limits, M-factors Notes

Index No International Chemical Identification EC No CAS No

Hazard Class and Category Hazard Hazard Suppl. Hazard

Code(s) Statement

Pictogram, Signal

Code(s) Word Code(s)

statement statement Code(s) Code(s)

611-167-00-X sodium bis[tris(2- 435-240-9 Aquatic Chronic 3 H412 — H412 hydroxyethyl)ammonium][6-anilino—

4'-(4,8-disulfonato-2-naphthylazo)- 5'-methyl-3-sulfonatonaphthalene-2- azobenzene-1,2'-diolato]cuprate(II)

611-168-00-5 reaction mass of: 3-[[4-chloro-6-[[7- 435-440-6 Eye Dam. 1 H318 GHS05 H318

[(1,5-disulfo-2-naphthalenyl)azo]-8- — Dgr hydroxy-3,6-disulfo1- naphthalenyl]amino]-1,3,5-triazin-2- yl]amino]-5-[[4-chloro-6-[[8- hydroxy-3,6-disulfo-7-[(2- sulfophenyl)azo]-1- naphthalenyl]amino]-1,3,5-triazin 2yl]amino]benzoic acid; 3,5-bis[[4-chloro-6-[[7-[(1,5-disulfo 2-naphthalenyl)azo]-8-hydroxy-3,6- disulfo-1-naphthalenyl]amino]-1,3,5- triazin-2-yl]amino]benzoic acid

611-169-00-0 sodium 5-(2-carboxyphenylazo)-6- 435-800-2 Aquatic Chronic 3 H412 — H412 hydroxynaphthalene-2-sulfonate —

611-170-00-6 reaction mas of: trisodium 2-((1-(2- 435-880-9 Aquatic Chronic 3 H412 H412 hydroxy-κ-O-5-(2-

sulfonatoethansulfonyl)phenylazo-κ- — — N 2 )-1-phenylmethyl)azo-κ-N 1 )4- sulfonatobenzoate(5-)-κ- O)cuprate(II); disodium 2-((1-(5-ethenesulfonyl-2-

2

hydroxy-κ-O-phenylazo-κ-N )-1- phenylmethyl)azo-κ-N 1 )-4- sulfonatobenzoate-κ-O- (5))cuprate(II)

423

D050725/02

Classification Labelling Specific Conc. Limits, M-factors Notes

Index No International Chemical Identification EC No CAS No

Hazard Class and Category Hazard Pictogram, Signal Hazard Suppl. Hazard

Code(s) Statement statement statement Code(s) Word Code(s) Code(s) Code(s)

611-171-00-1 reaction mass of trisodium 3-(5-(2,6- 436-890-6 — Eye Dam. 1 H318 GHS05 H318 difluoropyrimidin-4-ylamino)-2- Aquatic Chronic 3 H412 Dgr H412 sulfonatophenylazo)5-(4-fluoro-6-

morpholin-4-yl-1,3,5-triazin-2- ylamino)-4-hydroxy-2,7- naphthalenedisulfonate; trisodium 3-(5-(4,6- difluoropyrimidin-2-ylamino)-2- sulfonatophenylazo)-5-(4-fluoro-6- morpholin-4-yl-1,3,5-triazin-2- ylamino)-4-hydroxy-2,7- naphthalenedisulfonate

611-172-00-7 reaction mass of: triammonium 438-310-7 — Self-react. C**** H242 GHS02 H242

6-amino-3-((2,5-diethoxy-4-(3- Repr. 2 H361f*** GHS08 H361f*** phosphonophenyl)azo)phenyl)azo-4- Acute Tox. 4 * H302 GHS07 H302 hydroxy-2-naphthalenesulfonate; STOT RE 2 * H373** Dgr H373** diammonium 3-((4-((7-amino-1- Aquatic Chronic 3 H412 H412 hydroxy-3-sulfo-naphthalen-2- yl)azo)-2,5- diethoxyphenyl)azo)benzoate

611-173-00-2 reaction mass of: 3-[3-carbamoyl-5- 440-510-4 Eye Dam. 1 H318 GHS05 H318

(5-{4-chloro-6[4-(2- — Skin Sens. 1 H317 GHS07 H317 sulfonatooxyethylsulfonyl)anilino]- Dgr 1,3,5-triazin-2-ylamino}-2- sulfonatophenylazo)-1,2-dihydro-6- hydroxy-4-methyl-2-oxo-1- pyridyl]propanoic acid, trisodium salt; 3-[3-carbamoyl-5-(5-{4-chloro 6-[4-(vinylsulfonyl)anilino]-1,3,5- triazin-2-ylamino}-2- sulfonatophenylazo)-1,2-dihydro-6- hydroxy-4-methyl-2oxo-1- pyridyl]propanoicacid, disodium salt

424

D050725/02

Classification Labelling Specific Conc. Limits, M-factors Notes

Index No International Chemical Identification EC No CAS No

Hazard Class and Category Hazard Pictogram, Signal Hazard Suppl. Hazard

Code(s) Statement statement Code(s) Word Code(s) statement Code(s) Code(s)

611-174-00-8 reaction mass of: 3-[5-(4- 442-290-5 457624-86-1 Eye Dam. 1 H318 GHS05 H318 ethenesulfonylbutyrylamino)-2- Dgr

sulfophenylazo]-5-4-chloro-[6-(4-(3- amino-5-hydroxy-2,7- disulfonaphthalene-4-ylazo)-3- sulfophenylamino]-1,3,5-triazin-2- ylamino[-4-hydroxynaphthalene-2,7- disulfonic acid, sodium salt; 3-[5-(4-(2- chloroethanesulfonyl)butyrylamino)- 2-sulfophenylazo]-5-4-chloro-[6-(4- (3-amino-5-hydroxy-2,7- disulfonaphthalene-4-ylazo)-3- sulfophenylamino]-1,3,5-triazin-2- ylamino}-4-hydroxynaphthalene 2,7-disulfonic acid, sodium salt

611-175-00-3 reaction mass of: trisodium 5-{4- 444-050-5 Eye Dam. 1 H318 GHS05 H318 chloro-6-[N-ethyl-(3-(2- — Aquatic Chronic 3 H412 Dgr H412 sulfonatooxy)ethylsulfonyl)aniline]-

1,3,5-triazin-2-ylamino}-4-hydroxy 3-[4- (vinylsulfonyl)phenylazo{naphthalen e-2,7-disulfonate; trisodium 5-4- chloro-6-[N-ethyl-3- (vinylsulfonyl)anilino]-1,3,5-triazin 2-ylamino}-4-hydroxy-3-[4-(2- (sulfonatooxy)ethylsulfonyl)phenyla zo]naphthalene-2,7-disulfonate; disodium 5-4-chloro-6-[N-ethyl-3- (vinylsulfonyl)anilino]-1,3,5-triazin 2-ylamino}-4-hydroxy-3-[(4- vinylsulfonyl)phenylazo]naphthalene -2,7-disulfonate; tetrasodium 5-4-chloro-6-[N-ethyl-3- (2- (sulfonatooxy)ethylsulfonyl)anilino]- 1,3,5-triazin-2-ylamino}-3-[4(2- (sulfonatooxy)ethylsulfonyl)phenyla zo]-4-hydroxynaphthalene-2,7- disulfonate

425

D050725/02

Classification Labelling Specific Conc. Limits, M-factors Notes

Index No International Chemical Identification EC No CAS No

Hazard Class and Category Hazard Hazard Suppl. Hazard

Code(s) Statement

Pictogram, Signal

Code(s) Word Code(s)

statement statement Code(s) Code(s)

611-176-00-9 2,6-bis(2,3,4-trihydroxybenzyl)-p- 444-250-2 Self-react. C**** Aquatic H242 GHS02 H242 cresol ester with 6-diazo-5,6- Chronic 2 H411 GHS09 H411 dihydro-5-oxo-1- Dgr

naphthalenesulfonate —

611-177-00-4 reaction mass of: pentasodium 444-290-0 508202-43-5 Eye Dam. 1 H318 GHS05 H318 bis[6-anilino-3,5'- Skin Sens. 1 H317 GHS07 H317 disulfonatonaphthalene-2- Aquatic Chronic 3 H412 Dgr H412 azobenzene-1,2'-

diolato]cobaltate(III); tetrasodium [6-anilino-3,5'- disulfonatonaphthalene-2- azobenzene-1,2'-diolato][6-anilino 5'-sulfamoyl-3- sulfonatonaphthalene-2-azobenzene 1,2'-diolato]cobaltate(III); trisodium bis[6-anilino-5'-sulfamoyl-3- sulfonatonaphthalene-2-azobenzene 1,2'-diolato]cobaltate(III)

426

D050725/02

Classification Labelling Specific Conc. Limits, M-factors Notes

Index No International Chemical Identification EC No CAS No

Hazard Class and Category Hazard Hazard Suppl. Hazard

Code(s) Statement

Pictogram, Signal statement statement

Code(s) Word Code(s) Code(s) Code(s)

611-178-00-X reaction mass of: pentasodium 445-280-9 Eye Dam. 1 H318 GHS05 H318

4-amino-5-hydroxy-3-{(E)-4-[2- Skin Sens. 1 H317 GHS07 H317 (sulfonatooxy)ethylsulfonyl]phenyla Aquatic Chronic 3 H412 Dgr H412 zo}-6-{(E)-2-sulfonato-4-[2- (sulfonatooxy)ethylsulfonyl]phenyla zo}naphthalene-2,7-disulfonate;

tetrasodium 4-amino-5-hydroxy-3- —

{(E)-4-[2- (sulfonatooxy)ethylsulfonyl]phenyla zo}-6-[(E)-2-sulfonato-4- (vinylsulfonyl)phenylazo]naphthalen e-2,7-disulfonate; tetrasodium 4- amino-5-hydroxy-6-{(E)-2- sulfonato-4-[2- (sulfonatooxy)ethylsulfonyl]phenyla zo}-3-[(E)-4- (vinylsulfonyl)phenylazo]naphthalen e-2,7-disulfonate; trisodium 4- amino-5-hydroxy-3-[(E)-4- (vinylsulfonyl)phenylazo]-6-[(E)-2- sulfonato-4- (vinylsulfonyl)phenylazo]naphthalen e-2,7-disulfonate; trisodium 4-amino-5-hydroxy-3-[(2- hydroxyethylsulfonyl)-phenylazo]-6- [(E)-2-sulfonato-4- (vinylsulfonyl)phenylazo]naphthalen e-2,7-disulfonate; trisodium 4-amino-5-hydroxy-3- [(E)-4-(vinylsulfonyl)phenylazo]-6- [-2-sulfonato-4-(2- hydroxyethylsulfonyl)phenylazo]nap hthalene-2,7-disulfonate

427

D050725/02

Classification Labelling Specific Conc. Limits, M-factors Notes

Index No International Chemical Identification EC No CAS No

Hazard Class and Category Hazard Hazard Suppl. Hazard

Code(s) Statement

Pictogram, Signal

Code(s) Word Code(s)

statement statement Code(s) Code(s)

611-179-00-5 reaction mass of: pentasodium 450-010-8 Eye Dam. 1 H318 GHS05 H318

2-[[8-[[4-chloro-6-[[4-(2- Skin Sens. 1 H317 GHS07 H317 sulfonatethylsulfonyl)]phenyl]amino Dgr ]-1,3,5-triazin-2-yl]amino-1-

hydroxy-3,6-disulfonato-2- —

naphthalenyl]azo]naphthalene-1,5- disulfonate; 2-[[8-[[4-chloro-6-[[4-[[2- ethenyl]sulfonyl]phenyl]amino]1,3,5 -triazin-2-yl]amino]-1-hydroxy-3,6- disulfonato-2- naphthalenyl]azo]naphthalene-1,5- disulfonate

611-180-00-0 iron, complexes with diazotised 417-850-7 — Aquatic Chronic 2 H411 GHS09 H411

4-aminobenzenesulfonamide, diazotized 3-aminobenzenesulfonic acid, diazotised 3-amino-4- hydroxybenzenesulfonamide, diazotised 3-amino-4-hydroxy-N- phenylbenzenesulfonamide, diazotised 5-amino-2- (phenylamino)benzenesulfonic acid and resorcinol, sodium salts

• * 

  612-001-00-9 mono-methylamine; [1] 200-820-0 [1] 74-89-5 [1] Flam. Gas 1 H220 GHS02 H220 Skin Irrit. 2; U5

di-methylamine; [2] 204-697-4 [2] 124-40-3 [2] Press. Gas H332 GHS04 H332 H315: C ≥ 5% tri-methylamine [3] 200-875-0 [3] 75-50-3 [3] Acute Tox. 4 * H335 GHS05 H335 Eye Dam. 1; H318: STOT SE 3 H315 GHS07 H315 C ≥ 5 % Eye Irrit. Skin Irrit. 2 H318 Dgr H318 2; Eye Dam. 1 H319: 0,5% ≤ C < 5% STOT SE 3; H335: C ≥ 5%

612-001-01-6 mono-methylamine ... %; [1] 200-820-0 [1] 74-89-5 [1] Flam. Liq. 1 H224 GHS02 H224 * di-methylamine ... %; [2] 204-697-4 [2] 124-40-3 [2] Acute Tox. 4 * H332 GHS05 H332 STOT SE 3; H335: B tri-methylamine ... % [3] 200-875-0 [3] 75-50-3 [3] Acute Tox. 4 * H302 GHS07 H302 C ≥ 5 % Skin Corr. 1B H314 Dgr H314

428

D050725/02

Classification Labelling Specific Conc. Limits, M-factors Notes

Index No International Chemical Identification EC No CAS No

Hazard Class and Category Hazard Pictogram, Signal Hazard Suppl. Hazard

Code(s) Statement statement Code(s) Word Code(s) statement Code(s) Code(s)

612-002-00-4 ethylamine 200-834-7 75-04-7 Flam. Gas 1 H220 GHS02 H220 U

Press. Gas H319 GHS04 H319 Eye Irrit. 2 H335 GHS07 H335 STOT SE 3 Dgr

612-003-00-X diethylamine 203-716-3 109-89-7 Flam. Liq. 2 H225 GHS02 H225 STOT SE 3; H335:

Acute Tox. 4 * H332 GHS05 H332 C ≥ 1% Acute Tox. 4 * H312 GHS07 H312 Acute Tox. 4 * H302 Dgr H302 Skin Corr. 1A H314 H314

612-004-00-5 triethylamine 204-469-4 121-44-8 Flam. Liq. 2 H225 GHS02 H225 STOT SE 3; H335:

Acute Tox. 4 * H332 GHS05 H332 C ≥ 1% Acute Tox. 4 * H312 GHS07 H312 Acute Tox. 4 * H302 Dgr H302 Skin Corr. 1A H314 H314

612-005-00-0 butylamine 203-699-2 109-73-9 Flam. Liq. 2 H225 GHS02 H225 STOT SE 3; H335:

Acute Tox. 4 * H332 GHS05 H332 C ≥ 1 % Acute Tox. 4 * H312 GHS07 H312 Acute Tox. 4 * H302 Dgr H302 Skin Corr. 1A H314 H314

612-006-00-6 ethylenediamine; 203-468-6 107-15-3 Flam. Liq. 3 H226 GHS02 H226

1,2-diaminoethane Acute Tox. 4 * H312 GHS08 H312 Acute Tox. 4 * H302 GHS05 H302 Skin Corr. 1B H314 GHS07 H314 Resp. Sens. 1 H334 Dgr H334 Skin Sens. 1 H317 H317

612-007-00-1 2-aminopropane; 200-860-9 75-31-0 Flam. Liq. 1 H224 GHS02 H224 isopropylamine Eye Irrit. 2 H319 GHS07 H319 STOT SE 3 H335 Dgr H335 Skin Irrit. 2 H315 H315

429

D050725/02

Classification Labelling Specific Conc. Limits, M-factors Notes

Index No International Chemical Identification EC No CAS No

Hazard Class and Category Hazard Pictogram, Signal Hazard Suppl. Hazard

Code(s) Statement statement Code(s) Word Code(s) statement Code(s) Code(s)

• * 

  612-008-00-7 niline 200-539-3 62-53-3 Carc. 2 H351 GHS06 H351 STOT RE 1; H372:

Muta. 2 H341 GHS08 H341 C ≥ 1 % Acute Tox. 3 * H331 GHS05 H331 STOT RE 2; H373: Acute Tox. 3 * H311 GHS09 H311 0,2 % ≤ C < 1 % Acute Tox. 3 * H301 Dgr H301 STOT RE 1 H372 ** H372 ** Eye Dam. 1 H318 H318 Skin Sens. 1 H317 H317 Aquatic Acute 1 H400 H400

612-009-00-2 salts of aniline Carc. 2 H351 GHS06 H351 * A

— — Muta. 2 H341 GHS08 H341 STOT RE 1; H372: Acute Tox. 3 * H331 GHS05 H331 C ≥ 1% STOT RE Acute Tox. 3 * H311 GHS09 H311 2;

Acute Tox. 3 * H301 Dgr H301 H373: 0,2% ≤ STOT RE 1 H372 ** H372 ** C < 1 % Eye Dam. 1 H318 H318 Skin Sens. 1 H317 H317 Aquatic Acute 1 H400 H400

612-010-00-8 chloroanilines (with exception of those Acute Tox. 3 * H331 GHS06 H331 C specified elsewhere in this Annex) — — Acute Tox. 3 * H311 GHS08 H311

Acute Tox. 3 * H301 GHS09 H301 STOT RE 2 * H373 ** Dgr H373 ** Aquatic Acute 1 H400 H410 Aquatic Chronic 1 H410

612-011-00-3 4-nitrosoaniline 211-535-6 659-49-4 Acute Tox. 4 * H332 GHS07 H332

Acute Tox. 4 * H312 Wng H312 Acute Tox. 4 * H302 H302

o-nitroaniline; [1] m-nitroaniline; [2]

612-012-00-9 p-nitroaniline [3] 201-855-4 [1] 88-74-4 [1] Acute Tox. 3 * H331 GHS06 H331 C

202-729-1 [2] 99-09-2 [2] Acute Tox. 3 * H311 GHS08 H311 202-810-1 [3] 100-01-6 [3] Acute Tox. 3 * H301 Dgr H301 STOT RE 2 * H373 ** H373 ** Aquatic Chronic 3 H412 H412

430

D050725/02

Classification Labelling Specific Conc. Limits, M-factors Notes

Index No International Chemical Identification EC No CAS No

Hazard Class and Category Hazard Suppl. Hazard

Code(s) Statement

Pictogram, Signal Hazard statement statement

Code(s) Word Code(s) Code(s) Code(s)

612-013-00-4 3-aminobenzene sulphonic acid; 204-473-6 121-47-1 Acute Tox. 4 * H332 GHS07 H332 metanilic acid Acute Tox. 4 * H312 Wng H312 Acute Tox. 4 * H302 H302

612-014-00-X sulphanilic acid; 204-482-5 121-57-3 Eye Irrit. 2 H319 GHS07 H319

4-aminobenzenesulphonic acid Skin Irrit. 2 H315 Wng H315 Skin Sens. 1 H317 H317

612-015-00-5 N-methylaniline 202-870-9 100-61-8 Acute Tox. 3 * H331 GHS06 H331

Acute Tox. 3 * H311 GHS08 H311 Acute Tox. 3 * H301 GHS09 H301 STOT RE 2 * H373 ** Dgr H373 ** Aquatic Acute 1 H400 H410 Aquatic Chronic 1 H410

612-016-00-0 N,N-dimethylaniline 204-493-5 121-69-7 Carc. 2 H351 GHS06 H351

Acute Tox. 3 * H331 GHS08 H331 Acute Tox. 3 * H311 GHS09 H311 Acute Tox. 3 * H301 Dgr H301 Aquatic Chronic 2 H411 H411

612-017-00-6 N-methyl-N-2,4,6-tetranitroaniline; 207-531-9 479-45-8 Expl. 1.1 H201 GHS01 H201 tetryl Acute Tox. 3 * H331 GHS06 H331

Acute Tox. 3 * H311 GHS08 H311 Acute Tox. 3 * H301 Dgr H301 STOT RE 2 H373** H373**

612-018-00-1 bis(2,4,6-trinitrophenyl)amine; 205-037-8 131-73-7 Expl. 1.1 H201 GHS01 H201 hexyl Acute Tox. 2 * H330 GHS06 H330 Acute Tox. 1 H310 GHS08 H310 Acute Tox. 2 * H300 GHS09 H300 STOT RE 2 H373** Dgr H373** Aquatic Chronic 2 H411 H411

431

D050725/02

Classification Labelling Specific Conc. Limits, M-factors Notes

Index No International Chemical Identification EC No CAS No

Hazard Class and Category Hazard Suppl. Hazard

Code(s) Statement

Pictogram, Signal Hazard statement statement

Code(s) Word Code(s) Code(s) Code(s)

612-019-00-7 dipicrylamine, ammonium salt 220-639-0 2844-92-0 Expl. 1.1 H201 GHS01 H201

Acute Tox. 2 * H330 GHS06 H330 Acute Tox. 1 H310 GHS08 H310 Acute Tox. 2 * H300 GHS09 H300 STOT RE 2 H373** Dgr H373** Aquatic Chronic 2 H411 H411

612-020-00-2 1-naphthylamine 205-138-7 134-32-7 Acute Tox. 4 * H302 GHS07 H302

Aquatic Chronic 2 H411 GHS09 H411 Wng

612-022-00-3 2-naphthylamine 202-080-4 91-59-8 Carc. 1A H350 GHS08 H350 Carc. 1A; H350: C

Acute Tox. 4 * H302 GHS07 H302 ≥ 0,01 % Aquatic Chronic 2 H411 GHS09 H411 Dgr

612-023-00-9 phenylhydrazine; [1] 202-873-5 [1] 100-63-0 [1] Carc. 1B H350 GHS06 H350 phenylhydrazinium chloride; [2] 200-444-7 [2] 59-88-1 [2] Muta. 2 H341 GHS08 H341 phenylhydrazine hydrochloride; [3] 248-259-0 [3] 27140-08-5 [3] Acute Tox. 3 * H331 GHS09 H331 phenylhydrazinium sulphate 257-622-2 [4] 52033-74-6 [4] Acute Tox. 3 * H311 Dgr H311 (2:1) [4] Acute Tox. 3 * H301 H301 STOT RE 1 H372 ** H372 ** Eye Irrit. 2 H319 H319 Skin Irrit. 2 H315 H315 Skin Sens. 1 H317 H317 Aquatic Acute 1 H400 H400

612-024-00-4 m-toluidine; 203-583-1 108-44-1 Acute Tox. 3 * H331 GHS06 H331

3-aminotoluene Acute Tox. 3 * H311 GHS08 H311 Acute Tox. 3 * H301 GHS09 H301 STOT RE 2 * H373 ** Dgr H373 ** Aquatic Acute 1 H400 H400

432

D050725/02

Classification Labelling Specific Conc. Limits, M-factors Notes

Index No International Chemical Identification EC No CAS No

Hazard Class and Category Hazard Suppl. Hazard

Code(s) Statement

Pictogram, Signal Hazard statement statement

Code(s) Word Code(s) Code(s) Code(s)

612-025-00-X nitrotoluidines, with the exception of — Acute Tox. 3 * H331 GHS06 H331 C those specified elsewhere in this — Acute Tox. 3 * H311 GHS08 H311

Annex Acute Tox. 3 * H301 GHS09 H301 STOT RE 2 * H373 ** Dgr H373 ** Aquatic Chronic 2 H411 H411

612-026-00-5 diphenylamine 204-539-4 122-39-4 Acute Tox. 3 * H331 GHS06 H331

Acute Tox. 3 * H311 GHS08 H311 Acute Tox. 3 * H301 GHS09 H301 STOT RE 2 * H373 ** Dgr H373 ** Aquatic Acute 1 H400 H410 Aquatic Chronic 1 H410

612-027-00-0 xylidines with the exception of those Acute Tox. 3 * H331 GHS06 H331 C specified elsewhere in this Annex; — — Acute Tox. 3 * H311 GHS08 H311

dimethyl anilines with the exception Acute Tox. 3 * H301 GHS09 H301 of those specified elsewhere in this STOT RE 2 * H373 ** Dgr H373 ** Annex Aquatic Chronic 2 H411 H411

612-028-00-6 p-phenylenediamine 203-404-7 106-50-3 Acute Tox. 3 * H331 GHS06 H331

Acute Tox. 3 * H311 GHS09 H311 Acute Tox. 3 * H301 Dgr H301 Eye Irrit. 2 H319 H319 Skin Sens. 1 H317 H317 Aquatic Acute 1 H400 H410 Aquatic Chronic 1 H410

612-029-00-1 benzene-1,4-diamine 210-834-9 624-18-0 Acute Tox. 3 * H331 GHS06 H331 dihydrochloride; Acute Tox. 3 * H311 GHS09 H311 p-phenylenediamine dihydrochloride Acute Tox. 3 * H301 Dgr H301 Eye Irrit. 2 H319 H319 Skin Sens. 1 H317 H317 Aquatic Acute 1 H400 H410 Aquatic Chronic 1 H410

433

D050725/02

Classification Labelling Specific Conc. Limits, M-factors Notes

Index No International Chemical Identification EC No CAS No

Hazard Class and Category Hazard Pictogram, Signal Hazard Suppl. Hazard

Code(s) Statement statement Code(s) Word Code(s) statement Code(s) Code(s)

612-030-00-7 2-methyl-p-phenylenediamine 210-431-8 [1] 615-50-9 [1] Acute Tox. 3 * H301 GHS06 H301 sulphate [1] 228-871-4 [2] 6369-59-1 [2] Acute Tox. 4 * H332 GHS09 H332 Acute Tox. 4 * H312 Dgr H312 Skin Sens. 1 H317 H317 Aquatic Chronic 2 H411 H411

612-031-00-2 N,N-dimethylbenzene-1,3-diamine; 220-623-3 [1] 2836-04-6 [1] Acute Tox. 3 * H331 GHS06 H331 C

[1] 202-807-5 [2] 99-98-9 [2] Acute Tox. 3 * H311 Dgr H311 4-amino-N,N-dimethylaniline; Acute Tox. 3 * H301 H301 3-amino-N,N'-dimethylaniline [2]

612-032-00-8 N,N,N',N'-tetramethyl-p- 202-831-6 100-22-1 Acute Tox. 4 * H332 GHS07 H332 phenylenediamine Acute Tox. 4 * H312 Wng H312 Acute Tox. 4 * H302 H302

612-033-00-3 2-aminophenol 202-431-1 95-55-6 Muta. 2 H341 GHS08 H341

Acute Tox. 4 * H332 GHS07 H332 Acute Tox. 4 * H302 Wng H302

612-034-00-9 2-amino-4,6-dinitrophenol; 202-544-6 96-91-3 Expl. 1.1 H201 GHS01 H201 picramic acid Acute Tox. 4 * H332 GHS07 H332 Acute Tox. 4 * H312 Dgr H312 Acute Tox. 4 * H302 H302 Aquatic Chronic 3 H412 H412

612-034-01-6 2-amino-4,6-dinitrophenol; 202-544-6 96-91-3 Acute Tox. 4 * H332 GHS07 H332 G picramic acid; [≥ 20% water] Acute Tox. 4 * H312 Wng H312

Acute Tox. 4 * H302 H302 Aquatic Chronic 3 H412 H412

612-035-00-4 2-methoxyaniline; 201-963-1 90-04-0 Carc. 1B Muta. 2 H350 GHS06 H350 o-anisidine Acute Tox. 3 * H341 GHS08 H341 Acute Tox. 3 * H331 Dgr H331 Acute Tox. 3 * H311 H311 H301 H301

434

D050725/02

Classification Labelling Specific Conc. Limits, M-factors Notes

Index No International Chemical Identification EC No CAS No

Hazard Class and Category Hazard Pictogram, Signal Hazard Suppl. Hazard

Code(s) Statement statement Code(s) Word Code(s) statement Code(s) Code(s)

612-036-00-X 3,3'-dimethoxybenzidine; 204-355-4 119-90-4 Carc. 1B H350 GHS08 H350 o-dianisidine Acute Tox. 4 * H302 GHS07 H302 Dgr

612-037-00-5 salts of 3,3'-dimethoxybenzidine; — — Carc. 1B H350 GHS08 H350 A salts of o-dianisidine Acute Tox. 4 * H302 GHS07 H302

Dgr

612-038-00-0 2-nitro-p-anisidine; 202-547-2 96-96-8 Acute Tox. 2 * H330 GHS06 H330

4-methoxy-2-nitroaniline Acute Tox. 1 H310 GHS08 H310 Acute Tox. 2 * H300 Dgr H300 STOT RE 2 * H373 ** H373 ** Aquatic Chronic 3 H412 H412

612-039-00-6 2-ethoxyaniline; 202-356-4 94-70-2 Acute Tox. 3 * H331 GHS06 H331 o-phenetidine Acute Tox. 3 * H311 GHS08 H311 Acute Tox. 3 * H301 Dgr H301 STOT RE 2 * H373 ** H373 **

612-040-00-1 2,4-dinitroaniline 202-553-5 97-02-9 Acute Tox. 2 * H330 GHS06 H330

Acute Tox. 1 H310 GHS08 H310 Acute Tox. 2 * H300 GHS09 H300 STOT RE 2 * H373 ** Dgr H373 ** Aquatic Chronic 2 H411 H411

612-041-00-7 4,4'-bi-o-toluidine 204-358-0 119-93-7 Carc. 1B H350 GHS08 H350

Acute Tox. 4 * H302 GHS07 H302 Aquatic Chronic 2 H411 GHS09 H411 Dgr

612-042-00-2 benzidine; 202-199-1 92-87-5 Carc. 1A H350 GHS08 H350 Carc. 1A; H350: C

1,1'-biphenyl-4,4'-diamine; Acute Tox. 4 * H302 GHS07 H302 ≥ 0,01 % 4,4'-diaminobiphenyl; Aquatic Acute 1 H400 GHS09 H410 biphenyl-4,4'-ylenediamine Aquatic Chronic 1 H410 Dgr

435

D050725/02

Classification Labelling Specific Conc. Limits, M-factors Notes

Index No International Chemical Identification EC No CAS No

Hazard Class and Category Hazard Pictogram, Signal Hazard Suppl. Hazard

Code(s) Statement statement statement Code(s) Word Code(s) Code(s) Code(s)

612-043-00-8 N,N'-dimethylbenzidine — 2810-74-4 Acute Tox. 4 * H332 GHS07 H332

Acute Tox. 4 * H312 Wng H312 Acute Tox. 4 * H302 H302

612-044-00-3 N,N'-diacetylbenzidine 210-338-2 613-35-4 Carc. 1B Muta. 2 H350 GHS08 H350

Acute Tox. 4 * H341 GHS07 H341 Acute Tox. 4 * H332 Dgr H332 Acute Tox. 4 * H312 H312 H302 H302

612-046-00-4 allylamine 203-463-9 107-11-9 Flam. Liq. 2 H225 GHS02 H225

Acute Tox. 3 * H331 GHS06 H331 Acute Tox. 3 * H311 GHS09 H311 Acute Tox. 3 * H301 Dgr H301 Aquatic Chronic 2 H411 H411

612-047-00-X benzylamine 202-854-1 100-46-9 Acute Tox. 4 * H312 GHS05 H312

Acute Tox. 4 * H302 GHS07 H302 Skin Corr. 1B H314 Dgr H314

612-048-00-5 dipropylamine 205-565-9 142-84-7 Flam. Liq. 2 H225 GHS02 H225 STOT SE 3; H335:

Acute Tox. 4 * H332 GHS05 H332 C ≥ 1% Acute Tox. 4 * H312 GHS07 H312 Acute Tox. 4 * H302 Dgr H302 Skin Corr. 1A H314 H314

612-049-00-0 di-n-butylamine; [1] 203-921-8 [1] 111-92-2 [1] Flam. Liq. 3 H226 GHS02 H226 di-sec-butylamine [2] 210-937-9 [2] 626-23-3 [2] Acute Tox. 4 * H332 GHS07 H332 Acute Tox. 4 * H312 Wng H312 Acute Tox. 4 * H302 H302

612-050-00-6 cyclohexylamine 203-629-0 108-91-8 Flam. Liq. 3 H226 GHS02 H226

Repr. 2 H361f*** GHS05 H361f*** Acute Tox. 4 * H312 GHS08 H312 Acute Tox. 4 * H302 GHS07 H302 Skin Corr. 1B H314 Dgr H314

436

D050725/02

Classification Labelling Specific Conc. Limits, M-factors Notes

Index No International Chemical Identification EC No CAS No

Hazard Class and Category Hazard Suppl. Hazard

Code(s) Statement

Pictogram, Signal Hazard statement statement

Code(s) Word Code(s) Code(s) Code(s)

612-051-00-1 4,4'-diaminodiphenylmethane; 202-974-4 101-77-9 Carc. 1B H350 GHS08 H350

4,4'-methylenedianiline Muta. 2 H341 GHS07 H341 STOT SE 1 H370 ** GHS09 H370 ** STOT RE 2 * H373 ** Dgr H373 ** Skin Sens. 1 H317 H317 Aquatic Chronic 2 H411 H411

612-052-00-7 (S)-sec-butylamine; 208-164-7 [1] 513-49-5 [1] Flam. Liq. 2 H225 GHS02 H225

(S)-2-aminobutane; [1] (R)-sec- 236-232-6 [2] 13250-12-9 [2] Acute Tox. 4 * H332 GHS05 H332 C butylamine; 237-732-7 [3] 13952-84-6 [3] Acute Tox. 4 * H302 GHS07 H302 (R)-2-aminobutane; [2] Skin Corr. 1A H314 GHS09 H314 sec-butylamine; Aquatic Acute 1 H400 Dgr H400 2-aminobutane [3]

612-053-00-2 N-ethylaniline 203-135-5 103-69-5 Acute Tox. 3 * H331 GHS06 H331

Acute Tox. 3 * H311 GHS08 H311 Acute Tox. 3 * H301 Dgr H301 STOT RE 2 * H373 ** H373 **

612-054-00-8 N,N-diethylaniline 202-088-8 91-66-7 Acute Tox. 3 * H331 GHS06 H331 *

Acute Tox. 3 * H311 GHS08 H311 Acute Tox. 3 * H301 GHS09 H301 STOT RE 2 * H373 ** Dgr H373 ** Aquatic Chronic 2 H411 H411

612-055-00-3 N-methyl-o-toluidine; [1] N-methyl 210-260-9 [1] 611-21-2 [1] Acute Tox. 3 * H331 GHS06 H331 C m-toluidine; [2] N-methyl-p- 211-795-0 [2] 696-44-6 [2] Acute Tox. 3 * H311 GHS08 H311

toluidine [3] 210-769-6 [3] 623-08-5 [3] Acute Tox. 3 * H301 Dgr H301 STOT RE 2 * H373 ** H373 ** Aquatic Chronic 3 H412 H412

437

D050725/02

Classification Labelling Specific Conc. Limits, M-factors Notes

Index No International Chemical Identification EC No CAS No

Hazard Class and Category Hazard Suppl. Hazard

Code(s) Statement

Pictogram, Signal Hazard statement statement

Code(s) Word Code(s) Code(s) Code(s)

612-056-00-9 N,N-dimethyl-p-toluidine; [1] N,N- 202-805-4 [1] 99-97-8 [1] Acute Tox. 3 * H331 GHS06 H331 * C dimethyl-m-toluidine; [2] N,N- 204-495-6 [2] 121-72-2 [2] Acute Tox. 3 * H311 GHS08 H311

dimethyl-o-toluidine [3] 210-199-8 [3] 609-72-3 [3] Acute Tox. 3 * H301 Dgr H301 STOT RE 2 * H373 ** H373 ** Aquatic Chronic 3 H412 H412

612-057-00-4 piperazine; [solid] 203-808-3 110-85-0 Repr. 2 H361fd GHS05 H361fd

Skin Corr. 1B H314 GHS08 H314 Resp. Sens. 1 H334 Dgr H334 Skin Sens. 1 H317 H317

612-057-01-1 piperazine; [liquid] 203-808-3 110-85-0 Repr. 2 H361fd GHS05 H361fd

Skin Corr. 1B H314 GHS08 H314 Resp. Sens. 1 H334 Dgr H334 Skin Sens. 1 H317 H317

612-058-00-X 2,2'-iminodiethylamine; 203-865-4 111-40-0 Acute Tox. 4 * H312 GHS05 H312 diethylenetriamine Acute Tox. 4 * H302 GHS07 H302 Skin Corr. 1B H314 Dgr H314 Skin Sens. 1 H317 H317

612-059-00-5 3,6-diazaoctanethylenediamin; 203-950-6 112-24-3 Acute Tox. 4 * H312 GHS05 H312 triethylenetetramine Skin Corr. 1B H314 GHS07 H314 Skin Sens. 1 H317 Dgr H317 Aquatic Chronic 3 H412 H412

612-060-00-0 3,6,9- 203-986-2 112-57-2 Acute Tox. 4 * H312 GHS05 H312 triazaundecamethylenediamine; Acute Tox. 4 * H302 GHS07 H302 tetraethylenepentamine Skin Corr. 1B H314 GHS09 H314

Skin Sens. 1 H317 Dgr H317 Aquatic Chronic 2 H411 H411

438

D050725/02

Classification Labelling Specific Conc. Limits, M-factors Notes

Index No International Chemical Identification EC No CAS No

Hazard Class and Category Hazard Suppl. Hazard

Code(s) Statement

Pictogram, Signal Hazard statement statement

Code(s) Word Code(s) Code(s) Code(s)

612-061-00-6 3-aminopropyldimethylamine; N,N- 203-680-9 109-55-7 Flam. Liq. 3 H226 GHS02 H226 dimethyl-1,3-diaminopropane Acute Tox. 4 * H302 GHS05 H302 Skin Corr. 1B H314 GHS07 H314 Skin Sens. 1 H317 Dgr H317

612-062-00-1 3-aminopropyldiethylamine; 203-236-4 104-78-9 Flam. Liq. 3 H226 GHS02 H226

N,N-diethyl-1,3-diaminopropane Acute Tox. 4 * H312 GHS05 H312 Acute Tox. 4 * H302 GHS07 H302 Skin Corr. 1B H314 Dgr H314 Skin Sens. 1 H317 H317

612-063-00-7 3,3'-iminodi(propylamine); 200-261-2 56-18-8 Acute Tox. 2 * H330 GHS06 H330 dipropylenetriamine Acute Tox. 3 * H311 GHS05 H311 Acute Tox. 4 * H302 Dgr H302 Skin Corr. 1A H314 H314 Skin Sens. 1 H317 H317

612-064-00-2 3,6,9,12-tetra 223-775-9 4067-16-7 Skin Corr. 1B H314 GHS05 H314 azatetradecamethylenediamine; Skin Sens. 1 H317 GHS07 H317 pentacthylenehexamine Aquatic Acute 1 H400 GHS09 H410 Aquatic Chronic 1 H410 Dgr

612-065-00-8 polyethlyenepolyamines with the — — Acute Tox. 4 * H312 GHS05 H312 exception of those specified Acute Tox. 4 * H302 GHS07 H302 elsewhere in this Annex Skin Corr. 1B H314 GHS09 H314 Skin Sens. 1 H317 Dgr H317 Aquatic Acute 1 H400 H410 Aquatic Chronic 1 H410

612-066-00-3 dicyclohexylamine 202-980-7 101-83-7 Acute Tox. 4 * H302 GHS05 H302

Skin Corr. 1B H314 GHS07 H314 Aquatic Acute 1 H400 GHS09 H410 Aquatic Chronic 1 H410 Dgr

439

D050725/02

Classification Labelling Specific Conc. Limits, M-factors Notes

Index No International Chemical Identification EC No CAS No

Hazard Class and Category Hazard Pictogram, Signal Hazard Suppl. Hazard

Code(s) Statement statement statement Code(s) Word Code(s) Code(s) Code(s)

612-067-00-9 3-aminomethyl-3,5,5- 220-666-8 2855-13-2 Acute Tox. 4 * H312 GHS05 H312 trimethylcyclohexylamine Acute Tox. 4 * H302 GHS07 H302 Skin Corr. 1B H314 Dgr H314 Skin Sens. 1 H317 H317 Aquatic Chronic 3 H412 H412

612-068-00-4 3,3'-dichlorobenzidine; 202-109-0 91-94-1 Carc. 1B H350 GHS08 H350

3,3'-dichlorobiphenyl-4,4'- Acute Tox. 4 * H312 GHS07 H312 ylenediamine Skin Sens. 1 H317 GHS09 H317 Aquatic Acute 1 H400 Dgr H410 Aquatic Chronic 1 H410

612-069-00-X salts of 3,3'-dichlorobenzidine; — — Carc. 1B H350 GHS08 H350 A salts of 3,3'-dichlorobiphenyl-4,4'- Acute Tox. 4 * H312 GHS07 H312

ylenediamine Skin Sens. 1 H317 GHS09 H317 Aquatic Acute 1 H400 Dgr H410 Aquatic Chronic 1 H410

612-070-00-5 salts of benzidine 208-519-6 531-85-1 Carc. 1A H350 GHS08 H350 A

208-520-1 531-86-2 Acute Tox. 4 * H302 GHS07 H302 244-236-4 21136-70-9 Aquatic Acute 1 H400 GHS09 H410 252-984-8 36341-27-2 Aquatic Chronic 1 H410 Dgr

612-071-00-0 salts of 2-naphthylamine 209-030-0 553-00-4 Carc. 1A H350 GHS08 H350 A

210-313-6 612-52-2 Acute Tox. 4 * H302 GHS07 H302 Aquatic Chronic 2 H411 GHS09 H411 Dgr

612-072-00-6 biphenyl-4-ylamine; 202-177-1 92-67-1 Carc. 1A H350 GHS08 H350 xenylamine; Acute Tox. 4 * H302 GHS07 H302 4-aminobiphenyl Dgr

612-073-00-1 salts of biphenyl-4-ylamine; — — Carc. 1A H350 GHS08 H350 A salts of xenylamine; Acute Tox. 4 * H302 GHS07 H302

salts of 4-aminobiphenyl Dgr

440

D050725/02

Classification Labelling Specific Conc. Limits, M-factors Notes

Index No International Chemical Identification EC No CAS No

Hazard Class and Category Hazard Pictogram, Signal Hazard Suppl. Hazard

Code(s) Statement statement Code(s) Word Code(s) statement Code(s) Code(s)

612-074-00-7 benzyldimethylamine 203-149-1 103-83-3 Flam. Liq. 3 H226 GHS02 H226

Acute Tox. 4 * H332 GHS05 H332 Acute Tox. 4 * H312 GHS07 H312 Acute Tox. 4 * H302 Dgr H302 Skin Corr. 1B H314 H314 Aquatic Chronic 3 H412 H412

612-075-00-2 2-aminoethyldimethylamine; 203-541-2 108-00-9 Flam. Liq. 2 H225 GHS02 H225

2-dimethylaminoethylamine Acute Tox. 4 * H312 GHS05 H312 Acute Tox. 4 * H302 GHS07 H302 Skin Corr. 1A H314 Dgr H314

612-076-00-8 ethyldimethylamine 209-940-8 598-56-1 Flam. Liq. 2 H225 GHS02 H225

Acute Tox. 4 * H332 GHS05 H332 Acute Tox. 4 * H302 GHS07 H302 Skin Corr. 1B H314 Dgr H314

612-077-00-3 dimethylnitrosoamine; 200-549-8 62-75-9 Carc. 1B H350 GHS06 H350 Carc. 1B; H350: C

N-nitrosodimethylamine Acute Tox. 2 * H330 GHS08 H330 ≥ 0,001 % Acute Tox. 3 * H301 GHS09 H301

STOT RE 1 H372 ** Dgr H372 ** Aquatic Chronic 2 H411 H411

612-078-00-9 2,2'-dichloro-4,4'- 202-918-9 101-14-4 Carc. 1B H350 GHS08 H350 methylenedianiline; Acute Tox. 4 * H302 GHS07 H302 4,4'-methylene bis(2-chloroaniline) Aquatic Acute 1 H400 GHS09 H410 Aquatic Chronic 1 H410 Dgr

612-079-00-4 salts of 2,2'-dichloro-4,4'- — — Carc. 1B H350 GHS08 H350 A methylenedianiline; Acute Tox. 4 * H302 GHS07 H302

salts of 4,4'-methylenebis(2- Aquatic Acute 1 H400 GHS09 H410 chloroaniline) Aquatic Chronic 1 H410 Dgr

441

D050725/02

Classification Labelling Specific Conc. Limits, M-factors Notes

Index No International Chemical Identification EC No CAS No

Hazard Class and Category Hazard Hazard Suppl. Hazard

Code(s) Statement

Pictogram, Signal

Code(s) Word Code(s)

statement statement Code(s) Code(s)

612-080-00-X 4-amino-N,N-diethylaniline; 202-214-1 93-05-0 Acute Tox. 3 * H301 GHS06 H301

N,N-diethyl-p-phenylendiamine Skin Corr. 1B H314 GHS05 H314 Dgr

612-081-00-5 salts of 4,4'-bi-o-toluidine; 210-322-5 612-82-8 Carc. 1B H350 GHS08 H350 A salts of 3,3'-dimethylbenzidine; 265-294-7 64969-36-4 Acute Tox. 4 * H302 GHS07 H302

salts of o-tolidine 277-985-0 74753-18-7 Aquatic Chronic 2 H411 GHS09 H411 Dgr

612-082-00-0 thiourea; 200-543-5 62-56-6 Carc. 2 H351 GHS08 H351 thiocarbamide Repr. 2 H361d *** GHS07 H361d *** Acute Tox. 4 * H302 GHS09 H302 Aquatic Chronic 2 H411 Wng H411

612-083-00-6 1-methyl-3-nitro-1-nitrosoguanidine 200-730-1 70-25-7 Carc. 1B H350 GHS08 H350 Carc. 1B; H350: C

Acute Tox. 4 * H332 GHS07 H332 ≥ 0,01 % Eye Irrit. 2 H319 GHS09 H319 Skin Irrit. 2 H315 Dgr H315 Aquatic Chronic 2 H411 H411

612-084-00-1 dapsone; 201-248-4 80-08-0 Acute Tox. 4 * H302 GHS07 H302

4,4'-diamino diphenyl sulfone Wng

612-085-00-7 4,4'-methylenedi-o-toluidine 212-658-8 838-88-0 Carc. 1B H350 GHS08 H350

Acute Tox. 4 * H302 GHS07 H302 Skin Sens. 1 H317 GHS09 H317 Aquatic Acute 1 H400 Dgr H410 Aquatic Chronic 1 H410

442

D050725/02

Classification Labelling Specific Conc. Limits, M-factors Notes

Index No International Chemical Identification EC No CAS No

Hazard Class and Category Hazard Suppl. Hazard

Code(s) Statement

Pictogram, Signal Hazard statement statement

Code(s) Word Code(s) Code(s) Code(s)

612-086-00-2 amitraz (ISO); 251-375-4 33089-61-1 Acute Tox. 4 * H302 GHS08 H302 M = 10

N,N-bis(2,4-xylyliminomethyl) STOT RE 2 * H373 ** GHS07 H373 ** methylamine Skin Sens. 1 H317 GHS09 H317 Aquatic Acute 1 H400 Wng H410 Aquatic Chronic 1 H410

612-087-00-8 guazatine (ISO) 108173-90-6 Acute Tox. 2 * H330 GHS06 H330

Acute Tox. 4 * H312 GHS05 H312 Acute Tox. 4 * H302 GHS09 H302 STOT SE 3 H335 Dgr H335 Skin Irrit. 2 H315 H315 Eye Dam. 1 H318 H318 Aquatic Acute 1 H400 H410 Aquatic Chronic 1 H410

612-088-00-3 simazine (ISO); 204-535-2 122-34-9 Carc. 2 H351 GHS08 H351

6-chloro-N,N'-diethyl-1,3,5-triazine Aquatic Acute 1 H400 GHS09 H410 2,4-diamine Aquatic Chronic 1 H410 Wng

612-089-00-9 1,5-naphthylenediamine 218-817-8 2243-62-1 Carc. 2 H351 GHS08 H351

Aquatic Acute 1 H400 GHS09 H410 Aquatic Chronic 1 H410 Wng

612-090-00-4 2,2'-(nitrosoimino)bisethanol 214-237-4 1116-54-7 Carc. 1B H350 GHS08 H350

Dgr

612-091-00-X o-toluidine; 202-429-0 95-53-4 Carc. 1B H350 GHS06 H350

2-aminotoluene Acute Tox. 3 * H331 GHS08 H331 Acute Tox. 3 * H301 GHS09 H301 Eye Irrit. 2 H319 Dgr H319 Aquatic Acute 1 H400 H400

612-092-00-5 N,N'-(2,2- 401-660-6 1000-78-8 Skin Irrit. 2 H315 GHS07 H315 dimethylpropylidene)hexamethylene Skin Sens. 1 H317 Wng H317 diamine

443

D050725/02

Classification Labelling Specific Conc. Limits, M-factors Notes

Index No International Chemical Identification EC No CAS No

Hazard Class and Category Hazard Suppl. Hazard

Code(s) Statement

Pictogram, Signal Hazard statement statement

Code(s) Word Code(s) Code(s) Code(s)

612-093-00-0 3,5-dichloro-4-(1,1,2,2- 401-790-3 104147-32-2 Acute Tox. 4 * H302 GHS07 H302 tetrafluoroethoxy)aniline Aquatic Acute 1 H400 GHS09 H410 Aquatic Chronic 1 H410 Wng

612-094-00-6 4-(2-chloro-4- 402-190-4 113674-95-6 STOT RE 1 H372** GHS05 H372** trifluoromethyl)phenoxy-2- Acute Tox. 4 * H302 GHS08 H302

fluoroaniline hydrochloride STOT RE 2 * H373** GHS07 H373**

Eye Dam. 1 H318 GHS09 H318 Skin Sens. 1 H317 Dgr H317 Aquatic Acute 1 H400 H410 Aquatic Chronic 1 H410

612-095-00-1 benzyl-2-hydroxydodecyldi 402-610-6 113694-52-3 Skin Corr. 1B H314 GHS05 H314 methylammonium benzoate Acute Tox. 4 * H302 GHS07 H302 Aquatic Acute 1 H400 GHS09 H410 Aquatic Chronic 1 H410 Dgr

612-096-00-7 4,4'-carbonimidoylbis[N,N- 207-762-5 492-80-8 Carc. 2 H351 GHS08 H351 dimethylaniline] Acute Tox. 4 * H302 GHS07 H302 Eye Irrit. 2 H319 GHS09 H319 Aquatic Chronic 2 H411 Wng H411

612-097-00-2 salts of 4,4'-carbonimidoylbis[N,N- — — Carc. 2 H351 GHS08 H351 A dimethylaniline] Acute Tox. 4 * H302 GHS07 H302

Eye Irrit. 2 H319 GHS09 H319 Aquatic Chronic 2 H411 Wng H411

612-098-00-8 nitrosodipropylamine 210-698-0 621-64-7 Carc. 1B H350 GHS08 H350 Carc. 1B; H350: C

Acute Tox. 4 * H302 GHS07 H302 ≥ 0,001% Aquatic Chronic 2 H411 GHS09 H411 Dgr

444

D050725/02

Classification Labelling Specific Conc. Limits, M-factors Notes

Index No International Chemical Identification EC No CAS No

Hazard Class and Category Hazard Hazard Suppl. Hazard

Code(s) Statement

Pictogram, Signal statement statement

Code(s) Word Code(s) Code(s) Code(s)

612-099-00-3 4-methyl-m-phenylenediamine; 202-453-1 95-80-7 Carc. 1B H350 GHS06 H350

2,4-toluenediamine Muta. 2 H341 GHS08 H341 Repr. 2 H361f*** GHS09 H361f*** Acute Tox. 3 * H301 Dgr H301 Acute Tox. 4 * H312 H312 STOT RE 2 * H373** H373** Skin Sens. 1 H317 H317 Aquatic Chronic 2 H411 H411

612-100-00-7 propylenediamine 201-155-9 78-90-0 Flam. Liq. 3 H226 GHS02 H226

Acute Tox. 4 * H312 GHS05 H312 Acute Tox. 4 * H302 GHS07 H302 Skin Corr. 1A H314 Dgr H314

612-101-00-2 methenamine; 202-905-8 100-97-0 Flam. Sol. 2 H228 GHS02 H228 hexamethylenetetramine Skin Sens. 1 H317 GHS07 H317 Wng

612-102-00-8 N,N-bis(3-aminopropyl)methylamine 203-336-8 105-83-9 Acute Tox. 3 * H331 GHS06 H331

Acute Tox. 3 * H311 GHS05 H311 Acute Tox. 4 * H302 Dgr H302 Skin Corr. 1B H314 H314

612-103-00-3 N,N,N',N'- 203-744-6 110-18-9 Flam. Liq. 2 H225 GHS02 H225 tetramethylethylenediamine Acute Tox. 4 * H332 GHS05 H332 Acute Tox. 4 * H302 GHS07 H302 Skin Corr. 1B H314 Dgr H314

612-104-00-9 hexamethylenediamine 204-679-6 124-09-4 Acute Tox. 4 * H312 GHS05 H312

Acute Tox. 4 * H302 GHS07 H302 STOT SE 3 H335 Dgr H335 Skin Corr. 1B H314 H314

445

D050725/02

Classification Labelling Specific Conc. Limits, M-factors Notes

Index No International Chemical Identification EC No CAS No

Hazard Class and Category Hazard Hazard Suppl. Hazard

Code(s) Statement

Pictogram, Signal statement statement

Code(s) Word Code(s) Code(s) Code(s)

612-105-00-4 2-piperazin-1-ylethylamine 205-411-0 140-31-8 Acute Tox. 4 * H312 GHS05 H312

Acute Tox. 4 * H302 GHS07 H302 Skin Corr. 1B H314 Dgr H314 Skin Sens. 1 H317 H317 Aquatic Chronic 3 H412 H412

612-106-00-X 2,6-diethylaniline 209-445-7 579-66-8 Acute Tox. 4 * H302 — H302

612-107-00-5 1-phenylethylamine; [1] 202-706-6 [1] 98-84-0 [1] Acute Tox. 4 * H312 GHS05 H312

DL-α-methylbenzylamine [2] 210-545-8 [2] 618-36-0 [2] Acute Tox. 4 * H302 GHS07 H302 Skin Corr. 1B H314 Dgr H314

612-108-00-0 3-aminopropyltriethoxysilane 213-048-4 919-30-2 Acute Tox. 4 * H302 GHS05 H302

Skin Corr. 1B H314 GHS07 H314 Dgr

612-109-00-6 bis(2- 221-201-1 3030-47-5 Acute Tox. 3 * H311 GHS06 H311 dimethylaminoethyl)(methyl)amine Acute Tox. 4 * H302 GHS05 H302 Skin Corr. 1B H314 Dgr H314

612-110-00-1 2,2'-dimethyl-4,4'- 229-962-1 6864-37-5 Acute Tox. 3 * H331 GHS06 H331 methylenebis(cyclohexylamine) Acute Tox. 3 * H311 GHS05 H311 Acute Tox. 4 * H302 GHS09 H302 Skin Corr. 1A H314 Dgr H314 Aquatic Chronic 2 H411 H411

612-111-00-7 2-methyl-m-phenylenediamine; 212-513-9 823-40-5 Muta. 2 H341 GHS08 H341

2,6-toluenediamine Acute Tox. 4 * H312 GHS07 H312 Acute Tox. 4 * H302 GHS09 H302 Skin Sens. 1 H317 Wng H317 Aquatic Chronic 2 H411 H411

446

D050725/02

Classification Labelling Specific Conc. Limits, M-factors Notes

Index No International Chemical Identification EC No CAS No

Hazard Class and Category Hazard Hazard Suppl. Hazard

Code(s) Statement

Pictogram, Signal statement statement

Code(s) Word Code(s) Code(s) Code(s)

612-112-00-2 p-anisidine; 203-254-2 104-94-9 Acute Tox. 2 * H330 GHS06 H330

4-methoxyaniline Acute Tox. 1 H310 GHS08 H310 Acute Tox. 2 * H300 GHS09 H300 STOT RE 2 * H373 ** Dgr H373 ** Aquatic Acute 1 H400 H400

612-113-00-8 6-methyl-2,4- 403-240-8 106264-79-3 Acute Tox. 4 * H302 GHS07 H302 bis(methylthio)phenylene-1,3- Skin Sens. 1 H317 GHS09 H317 diamine Aquatic Acute 1 H400 Wng H410

Aquatic Chronic 1 H410

612-114-00-3 R,R-2-hydroxy-5-(1-hydroxy-2-(4- 404-390-7 — Flam. Sol. 1 H228 GHS02 H228 phenylbut-2- Skin Sens. 1 H317 GHS07 H317 ylamino)ethyl)benzamide hydrogen Aquatic Chronic 3 H412 Wng H412 2,3-bis(benzoyloxy)succinate

612-115-00-9 dimethyldioctadecylammonium 404-050-8 123312-54-9 Eye Irrit. 2 H319 GHS07 H319 hydrogen sulfate Aquatic Chronic 4 H413 Wng H413

612-116-00-4 C 8-18 alkylbis(2- 404-690-8 68132-19-4 Acute Tox. 3 * H331 GHS06 H331 hydroxyethyl)ammonium bis(2- Skin Corr. 1B H314 GHS05 H314 ethylhexyl)phosphate Skin Sens. 1 H317 GHS09 H317 Aquatic Acute 1 H400 Dgr H410 Aquatic Chronic 1 H410

612-117-00-X C 12-14 -tert-alkylamine, 404-750-3 119415-07-5 Acute Tox. 4 * H302 GHS05 H302 methylphosphonic acid salt Skin Corr. 1B H314 GHS07 H314 Aquatic Chronic 2 H411 GHS09 H411 Dgr

447

D050725/02

Classification Labelling Specific Conc. Limits, M-factors Notes

Index No International Chemical Identification EC No CAS No

Hazard Class and Category Hazard Suppl. Hazard

Code(s) Statement

Pictogram, Signal Hazard statement statement

Code(s) Word Code(s) Code(s) Code(s)

612-118-00-5 A reaction mass of: (1,3-dioxo-2H- 405-080-4 — Eye Dam. 1 H318 GHS05 H318 benz(de)isoquinolin-2- Aquatic Acute 1 H400 GHS09 H410 ylpropyl)hexadecyldimethylammoni Aquatic Chronic 1 H410 Dgr

um 4-toluenesulfonate; (1,3-dioxo 2H-benz(de)isoquinolin-2- ylpropyl)hexadecyldimethylammoni um bromide

612-119-00-0 benzyldimethyloctadecylammonium 405-330-2 — Skin Irrit. 2 H315 GHS05 H315

3-nitrobenzenesulfonate Eye Dam. 1 H318 GHS09 H318 Aquatic Acute 1 H400 Dgr H410 Aquatic Chronic 1 H410

612-120-00-6 aclonifen (ISO); 277-704-1 74070-46-5 Carc. 2 H351 GHS08 H351 M = 100

2-chloro-6-nitro-3-phenoxyaniline Skin Sens. 1A H317 GHS07 H317 M = 10

Aquatic Acute 1 H400 GH09 H410 Aquatic Chronic 1 H410 Wng

612-121-00-1 amines, polyethylenepoly-; HEPA 268-626-9 68131-73-7 Acute Tox. 4 * H312 GHS05 H312

Acute Tox. 4 * H302 GHS07 H302 Skin Corr. 1B H314 GHS09 H314 Skin Sens. 1 H317 Dgr H317 Aquatic Acute 1 H400 H410 Aquatic Chronic 1 H410

612-122-00-7 hydroxylamine … % 232-259-2 7803-49-8 Unst. Expl. Met. Corr. 1 H200 GHS01 H200

[> 55% in aqueous solution] Carc. 2 H290 GHS05 H290 B Acute Tox. 4 * H351 GHS08 H351

Acute Tox. 4 * H312 GHS07 H312 STOT RE 2 * H302 GHS09 H302 STOT SE 3 H373** Dgr H373** Skin Irrit. 2 H335 H335 Eye Dam. 1 H315 H315 Skin Sens. 1 H318 H318 Aquatic Acute 1 H317 H317 H400 H400

448

D050725/02

Classification Labelling Specific Conc. Limits, M-factors Notes

Index No International Chemical Identification EC No CAS No

Hazard Class and Category Hazard Pictogram, Signal Hazard Suppl. Hazard

Code(s) Statement statement statement Code(s) Word Code(s) Code(s) Code(s)

612-122-01-4 hydroxylamine …% [≤ 55% in 232-259-2 7803-49-8 Met. Corr. 1 H290 GHS05 H290 aqueous solution] Carc. 2 H351 GHS08 H351 B Acute Tox. 4 * H312 GHS07 H312 Acute Tox. 4 * H302 GHS09 H302 STOT RE 2 * H373** Dgr H373** STOT SE 3 H335 H335 Skin Irrit. 2 H315 H315 Eye Dam. 1 H318 H318 Skin Sens. 1 H317 H317 Aquatic Acute 1 H400 H400

612-123-00-2 hydroxylammonium chloride; 226-798-2 [1] 5470-11-1 [1] Met. Corr. 1 H290 GHS05 H290 hydroxylamine hydrochloride; [1] 233-118-8 [2] 10039-54-0 [2] Carc. 2 H351 GHS08 H351 bis(hydroxylammonium) sulfate; Acute Tox. 4 * H312 GHS07 H312 hydroxylamine sulfate (2:1) [2] Acute Tox. 4 * H302 GHS09 H302 STOT RE 2 * H373** Wng H373** Eye Irrit. 2 H319 H319 Skin Irrit. 2 H315 H315 Skin Sens. 1 H317 H317 Aquatic Acute 1 H400 H400

612-124-00-8 N,N,N-trimethylanilinium chloride 205-319-0 138-24-9 Acute Tox. 3 * H311 GHS06 H311

Acute Tox. 3 * H301 Dgr H301

612-125-00-3 2-methyl-p-phenylenediamine; 202-442-1 95-70-5 Acute Tox. 3 * H301 GHS06 H301

2,5-toluenediamine Acute Tox. 4 * H332 GHS09 H332 Acute Tox. 4 * H312 Dgr H312 Skin Sens. 1 H317 H317 Aquatic Chronic 2 H411 H411

612-126-00-9 toluene-2,4-diammonium sulphate; 265-697-8 65321-67-7 Carc. 1B H350 GHS06 H350

4-methyl-m-phenylenediamine Acute Tox. 3 * H301 GHS08 H301 sulfate Acute Tox. 4 * H312 GHS09 H312 Eye Irrit. 2 H319 Dgr H319 Skin Sens. 1 H317 H317 Aquatic Chronic 2 H411 H411

449

D050725/02

Classification Labelling Specific Conc. Limits, M-factors Notes

Index No International Chemical Identification EC No CAS No

Hazard Class and Category Hazard Pictogram, Signal Hazard Suppl. Hazard

Code(s) Statement statement statement Code(s) Word Code(s) Code(s) Code(s)

612-127-00-4 3-aminophenol 209-711-2 591-27-5 Acute Tox. 4 * H332 GHS07 H332

Acute Tox. 4 * H302 GHS09 H302 Aquatic Chronic 2 H411 Wng H411

612-128-00-X 4-aminophenol 204-616-2 123-30-8 Muta. 2 H341 GHS08 H341

Acute Tox. 4 * H332 GHS07 H332 Acute Tox. 4 * H302 GHS09 H302 Aquatic Acute 1 H400 Wng H410 Aquatic Chronic 1 H410

612-129-00-5 diisopropylamine 203-558-5 108-18-9 Flam. Liq. 2 H225 GHS02 H225 STOT SE 3; H335:

Acute Tox. 4 * H332 GHS05 H332 C ≥ 5 % Acute Tox. 4 * H302 GHS07 H302 Skin Corr. 1B H314 Dgr H314

612-130-00-0 2,6-diamino-3,5-diethyltoluene; 218-255-3 [1] 2095-01-4 [1] Acute Tox. 4 * H312 GHS08 H312

4,6-diethyl-2-methyl-1,3- 218-256-9 [2] 2095-02-5 [2] Acute Tox. 4 * H302 GHS07 H302 C benzenediamine; [1] 270-877-4 [3] 68479-98-1 [3] STOT RE 2 * H373 ** GHS09 H373 ** 2,4-diamino-3,5-diethyltoluene; Eye Irrit. 2 H319 Wng H319 2,4-diethyl-6-methyl-1,3- Aquatic Acute 1 H400 H410 benzenediamine; [2] Aquatic Chronic 1 H410 diethylmethylbenzenediamine [3]

612-131-00-6 didecyldimethylammonium chloride 230-525-2 7173-51-5 Acute Tox. 4 * H302 GHS05 H302

Skin Corr. 1B H314 GHS07 H314 Dgr

612-132-00-1 N,N'-diphenyl-p-phenylenediamine; 200-806-4 74-31-7 Skin Sens. 1 H317 GHS07 H317

N,N'-diphenyl-1,4-benzenediamine Aquatic Chronic 3 H412 Wng H412

612-133-00-7 (4-ammonio-m-tolyl)ethyl(2- 247-162-0 25646-77-9 Acute Tox. 3 * H301 GHS06 H301 hydroxyethyl)ammonium sulphate; STOT RE 2 * H373 ** GHS08 H373 ** 4-(N-ethyl-N-2-hydroxyethyl)-2- Skin Sens. 1 H317 GHS09 H317 methylphenylenediamine sulphate Aquatic Acute 1 H400 Dgr H410 Aquatic Chronic 1 H410

450

D050725/02

Classification Labelling Specific Conc. Limits, M-factors Notes

Index No International Chemical Identification EC No CAS No

Hazard Class and Category Hazard Hazard Suppl. Hazard

Code(s) Statement

Pictogram, Signal statement statement

Code(s) Word Code(s) Code(s) Code(s)

612-134-00-2 N-(2-(4-amino-N-ethyl-m- 247-161-5 25646-71-3 Acute Tox. 4 * H302 GHS07 H302 toluidino)ethyl)methanesulphonamid Skin Sens. 1 H317 GHS09 H317 e sesquisulphate; Aquatic Acute 1 H400 Wng H410 4-(N-ethyl-N-2- Aquatic Chronic 1 H410

methanesulphonylaminoethyl)-2- methylphenylenediamine sesquisulphate monohydrate

612-135-00-8 N-2-naphthylaniline; 205-223-9 135-88-6 Carc. 2 H351 GHS08 H351

N-phenyl-2-naphthylamine Eye Irrit. 2 H319 GHS07 H319

Skin Irrit. 2 H315 GHS09 H315 Skin Sens. 1 H317 Wng H317 Aquatic Chronic 2 H411 H411

612-136-00-3 N-isopropyl-N'-phenyl-p- 202-969-7 101-72-4 Acute Tox. 4 * H302 GHS07 H302 Skin Sens. 1; H317 phenylenediamine Skin Sens. 1 H317 GHS09 H317 :C ≥0,1%

Aquatic Acute 1 H400 Wng H410 Aquatic Chronic 1 H410

612-137-00-9 4-chloroaniline 203-401-0 106-47-8 Carc. 1B H350 GHS06 H350

Acute Tox. 3 * H331 GHS08 H331 Acute Tox. 3 * H311 GHS09 H311 Acute Tox. 3 * H301 Dgr H301 Skin Sens. 1 H317 H317 Aquatic Acute 1 H400 H410 Aquatic Chronic 1 H410

612-138-00-4 furalaxyl (ISO); 260-875-1 57646-30-7 Acute Tox. 4 * H302 GHS07 H302 methyl N-(2,6-dimethylphenyl)-N- Aquatic Chronic 3 H412 Wng H412 (2-furylcarbonyl)-DL-alaninate

612-139-00-X mefenacet (ISO); 277-328-8 73250-68-7 Aquatic Chronic 2 H411 GHS09 H411

2-(benzothiazol-2-yloxy)-N-methyl N-phenylacetamide

451

D050725/02

Classification Labelling Specific Conc. Limits, M-factors Notes

Index No International Chemical Identification EC No CAS No

Hazard Class and Category Hazard Hazard Suppl. Hazard

Code(s) Statement

Pictogram, Signal

Code(s) Word Code(s)

statement statement Code(s) Code(s)

612-140-00-5 quaternary ammonium compounds, 264-151-6 63449-41-2 Acute Tox. 4 * H312 GHS05 H312 benzyl-C 8-18 -alkyldimethyl, chlorides Acute Tox. 4 * H302 GHS07 H302 Skin Corr. 1B H314 GHS09 H314 Aquatic Acute 1 H400 Dgr H400

612-141-00-0 4,4'-methylenebis(2-ethylaniline); 243-420-1 19900-65-3 Carc. 2 H351 GHS08 H351

4,4'-methylenebis(2- Acute Tox. 4 * H302 GHS07 H302 ethylbenzeneamine) Aquatic Acute 1 H400 GHS09 H410

Aquatic Chronic 1 H410 Wng

612-142-00-6 biphenyl-2-ylamine 201-990-9 90-41-5 Carc. 2 H351 GHS08 H351

Acute Tox. 4 * Aquatic H302 GHS07 H302 Chronic 3 H412 Wng H412

612-143-00-1 5 5 N ,N -diethyltoluene-2,5-diamine 218-130-3 2051-79-8 Acute Tox. 3 * H301 GHS06 H301 monohydrochloride; Eye Irrit. 2 H319 GHS09 H319

4-diethylamino-2-methylaniline Skin Sens. 1 H317 Dgr H317

monohydrochloride Aquatic Acute 1 H400 H410 Aquatic Chronic 1 H410

612-144-00-7 flumetralin (ISO); 62924-70-3 Eye Irrit. 2 H319 GHS07 H319

N-(2-chloro-6-fluorobenzyl)-N-ethyl— Skin Irrit. 2 H315 GHS09 H315 α,α,α-trifluoro-2,6-dinitro-p- Skin Sens. 1 H317 Wng H317 toluidine Aquatic Acute 1 H400 H410 Aquatic Chronic 1 H410

452

D050725/02

Classification Labelling Specific Conc. Limits, M-factors Notes

Index No International Chemical Identification EC No CAS No

Hazard Class and Category Hazard Suppl. Hazard

Code(s) Statement

Pictogram, Signal Hazard statement statement

Code(s) Word Code(s) Code(s) Code(s)

612-145-00-2 o-phenylenediamine 202-430-6 95-54-5 Carc. 2 H351 GHS06 H351

Muta. 2 H341 GHS08 H341 Acute Tox. 3 * H301 GHS09 H301 Acute Tox. 4 * H332 Dgr H332 Acute Tox. 4 * H312 H312 Eye Irrit. 2 H319 H319 Skin Sens. 1 H317 H317 Aquatic Acute 1 H400 H410 Aquatic Chronic 1 H410

612-146-00-8 o-phenylenediamine dihydrochloride 210-418-7 615-28-1 Carc. 2 H351 GHS06 H351

Muta. 2 H341 GHS08 H341 Acute Tox. 3 * H301 GHS09 H301 Acute Tox. 4 * H332 Dgr H332 Acute Tox. 4 * H312 H312 Eye Irrit. 2 H319 H319 Skin Sens. 1 H317 H317 Aquatic Acute 1 H400 H410 Aquatic Chronic 1 H410

612-147-00-3 m-phenylenediamine 203-584-7 108-45-2 Muta. 2 H341 GHS06 H341

Acute Tox. 3 * H331 GHS08 H331 Acute Tox. 3 * H311 GHS09 H311 Acute Tox. 3 * H301 Dgr H301 Eye Irrit. 2 H319 H319 Skin Sens. 1 H317 H317 Aquatic Acute 1 H400 H410 Aquatic Chronic 1 H410

612-148-00-9 m-phenylenediamine 208-790-0 541-69-5 Muta. 2 H341 GHS06 H341 dihydrochloride Acute Tox. 3 * H331 GHS08 H331 Acute Tox. 3 * H311 GHS09 H311 Acute Tox. 3 * H301 Dgr H301 Eye Irrit. 2 H319 H319 Skin Sens. 1 H317 H317 Aquatic Acute 1 H400 H410 Aquatic Chronic 1 H410

453

D050725/02

Classification Labelling Specific Conc. Limits, M-factors Notes

Index No International Chemical Identification EC No CAS No

Hazard Class and Category Hazard Suppl. Hazard

Code(s) Statement

Pictogram, Signal Hazard statement statement

Code(s) Word Code(s) Code(s) Code(s)

612-149-00-4 1,3-diphenylguanidine 203-002-1 102-06-7 Repr. 2 H361f *** GHS08 H361f ***

Acute Tox. 4 * H302 GHS07 H302 Eye Irrit. 2 H319 GHS09 H319 STOT SE 3 H335 Wng H335 Skin Irrit. 2 H315 H315 Aquatic Chronic 2 H411 H411

612-151-00-5 methyl-phenylene diamine; — — Carc. 1B Muta. 2 H350 GHS06 H350 diaminotoluene; Repr. 2 H341 GHS08 H341 [technical product – reaction mass of Acute Tox. 3 * H361f*** GHS09 H361f*** 4-methyl-m-phenylene diamine (EC Acute Tox. 4 * H301 Dgr H301 No 202-453-1) and 2-methyl-m- STOT RE 2 * H312 H312 phenylene diamine (EC No 212- Eye Irrit. 2 H373** H373** 513-9)] Skin Sens. 1 H319 H319 Aquatic Chronic 2 H317 H317 H411 H411

612-152-00-0 N,N-diethyl-N',N'-dimethylpropan 406-610-7 62478-82-4 Flam. Liq. 3 H226 GHS02 H226

1,3-diyl-diamine Acute Tox. 4 * H332 GHS08 H332 Acute Tox. 4 * H302 GHS05 H302 STOT RE 2 * H373 ** GHS07 H373 ** Skin Corr. 1A H314 Dgr H314 Aquatic Chronic 3 H412 H412

612-153-00-6 4-[N-ethyl-N-(2- 407-020-2 132885-85-9 Acute Tox. 4 * H302 GHS07 H302 hydroxyethyl)amino]-1-(2- Skin Sens. 1 H317 Wng H317 hydroxyethyl)amino-2-nitrobenzene, Aquatic Chronic 3 H412 H412 monohydrochloride

612-154-00-1 6'-(isobutylethylamino)-3'-methyl-2'- 410-890-6 95235-29-3 Aquatic Chronic 4 H413 H413 phenylamino-spiro[isobenzo-2- —

oxofuran-7,9'-[9H]-xanthene]

612-155-00-7 2'-anilino-6'-((3- 411-730-8 93071-94-4 Aquatic Chronic 4 H413 H413 ethoxypropyl)ethylamino)-3'- —

methylspiro(isobenzo-3-oxofuran)-1- (1H)-9'-xanthene

454

D050725/02

Classification Labelling Specific Conc. Limits, M-factors Notes

Index No International Chemical Identification EC No CAS No

Hazard Class and Category Hazard Hazard Suppl. Hazard

Code(s) Statement

Pictogram, Signal statement statement

Code(s) Word Code(s) Code(s) Code(s)

612-156-00-2 reaction mass of: 405-620-9 — Eye Dam. 1 H318 GHS05 H318 trihexadecylmethylammonium Aquatic Acute 1 H400 GHS09 H410 chloride; Aquatic Chronic 1 H410 Dgr

dihexadecyldimethylammonium chloride

612-157-00-8 (Z)-1-benzo[b]thien-2-ylethanone 410-780-8 — Acute Tox. 4 * H302 GHS08 H302 oxime hydrochloride STOT RE 2 * H373 ** GHS05 H373 ** Eye Dam. 1 H318 GHS07 H318 Skin Sens. 1 H317 GHS09 H317 Aquatic Chronic 2 H411 Dgr H411

612-158-00-3 reaction mass of: bis(5-dodecyl-2- 410-820-4 — Aquatic Chronic 4 H413 — H413 hydroxybenzald-oximate) copper (II)

C 12 -alkyl group is branched;

4-dodecylsalicylaldoxime

612-159-00-9 reaction products of: 410-880-1 — Acute Tox. 4 * H302 GHS05 H302 trimethylhexamethylene diamine (a Skin Corr. 1B H314 GHS07 H314 mixture of 2,2,4-trimethyl-1,6- Aquatic Acute 1 H400 GHS09 H410 hexanediamine and 2,4,4-trimethyl Aquatic Chronic 1 H410 Dgr

1,6-hexanediamine, EINECS listed), Epoxide 8 (mono[(C 10 -C 16 - alkyloxy)methyl]oxirane derivatives) and p-toluene-sulfonic acid

612-160-00-4 p-toluidine; 203-403-1 [1] 106-49-0 [1] Carc. 2 H351 GHS06 H351

4-aminotoluene; [1] 208-740-8 [2] 540-23-8 [2] Acute Tox. 3 * H331 GHS08 H331 toluidinium chloride; [2] 208-741-3 [3] 540-25-0 [3] Acute Tox. 3 * H311 GHS09 H311 toluidine sulphate (1:1) [3] Acute Tox. 3 * H301 Dgr H301 Eye Irrit. 2 H319 H319 Skin Sens. 1 H317 H317 Aquatic Acute 1 H400 H400

455

D050725/02

Classification Labelling Specific Conc. Limits, M-factors Notes

Index No International Chemical Identification EC No CAS No

Hazard Class and Category Hazard Hazard Suppl. Hazard

Code(s) Statement

Pictogram, Signal statement statement

Code(s) Word Code(s) Code(s) Code(s)

612-161-00-X 2,6-xylidine; 201-758-7 87-62-7 Carc. 2 H351 GHS08 H351

2,6-dimethylaniline Acute Tox. 4 * H332 GHS07 H332 Acute Tox. 4 * H312 GHS09 H312 Acute Tox. 4 * H302 Wng H302 STOT SE 3 H335 H335 Skin Irrit. 2 H315 H315 Aquatic Chronic 2 H411 H411

612-162-00-5 dimethyldioctadecylammonium 203-508-2 107-64-2 Eye Dam. 1 H318 GHS05 H318 chloride; Aquatic Acute 1 H400 GHS09 H410 DODMAC Aquatic Chronic 1 H410 Dgr

612-163-00-0 metalaxyl-M (ISO); — 70630-17-0 Acute Tox. 4 * H302 GHS05 H302 mefenoxam; Eye Dam. 1 H318 GHS07 H318 (R)-2-[(2,6-dimethylphenyl)- Dgr

methoxyacetylamino]propionic acid methyl ester

612-164-00-6 2-butyl-2-ethyl-1,5-diaminopentane 412-700-7 137605-95-9 Acute Tox. 4 * H312 GHS08 H312

Acute Tox. 4 * H302 GHS05 H302 STOT RE 2 * H373 ** GHS07 H373 ** Skin Corr. 1B H314 Dgr H314 Skin Sens. 1 H317 H317 Aquatic Chronic 3 H412 H412

612-165-00-1 N,N'-diphenyl-N,N'-bis(3- 413-810-8 65181-78-4 Aquatic Chronic 2 H411 GHS09 H411 methylphenyl)-(1,1'-diphenyl)-4,4'-

diamine

612-166-00-7 reaction mass of: cis-(5-ammonium 411-830-1 114765-88-7 Eye Dam. 1 H318 GHS05 H318

1,3,3-trimethyl)- Skin Sens. 1 H317 GHS07 H317 cyclohexanemethylammonium Aquatic Chronic 3 H412 Dgr H412 phosphate (1:1); trans-(5-ammonium-1,3,3-trimethyl)- cyclohexanemethylammonium phosphate (1:1)

456

D050725/02

Classification Labelling Specific Conc. Limits, M-factors Notes

Index No International Chemical Identification EC No CAS No

Hazard Class and Category Hazard Pictogram, Signal Hazard Suppl. Hazard

Code(s) Statement statement statement Code(s) Word Code(s) Code(s) Code(s)

612-167-00-2 5-acetyl-3-amino-10,11-dihydro-5H- 410-490-1 — Acute Tox. 4 * H302 GHS08 H302 dibenz[b,f]azepine-hydrochloride STOT RE 2 * H373 ** GHS05 H373 ** Eye Dam. 1 H318 GHS07 H318 Skin Sens. 1 H317 GHS09 H317 Aquatic Chronic 2 H411 Dgr H411

612-168-00-8 3,5-dichloro-2,6-difluoropyrdine-4- 220-630-1 2840-00-8 Acute Tox. 4 * H312 GHS07 H312 amine Acute Tox. 4 * Aquatic H302 GHS09 H302 Chronic 2 H411 Wng H411

612-169-00-3 bis(N-methyl-N- 423-170-1 618-26-8 Flam. Liq. 2 H225 GHS02 H225 phenylhydrazine)sulfate STOT RE 1 H372** GHS05 H372** Acute Tox. 4 * H302 GHS08 H302 Eye Dam. 1 H318 GHS07 H318 Skin Sens. 1 H317 GHS09 H317 Aquatic Acute 1 H400 Dgr H410 Aquatic Chronic 1 H410

612-170-00-9 4-chlorophenyl cyclopropyl ketone 405-260-2 Acute Tox. 4 * H302 GHS07 H302

O-(4-aminobenzyl)oxime Skin Sens. 1 H317 GHS09 H317

— Aquatic Acute 1 H400 Wng H410

Aquatic Chronic 1 H410

612-171-00-4 N,N,N',N'-tetraglycidyl-4,4'-diamino 410-060-3 130728-76-6 Muta. 2 H341 GHS08 H341

3,3'-diethyldiphenylmethane Skin Sens. 1 H317 GHS09 H317 Aquatic Chronic 2 H411 Wng H411

612-172-00-X 4,4'-methylenebis(N,N'- 412-840-9 13474-64-1 Acute Tox. 4 * H302 GHS08 H302 dimethylcyclohexanamine STOT RE 2 * H373 ** GHS05 H373 ** Skin Corr. 1A H314 GHS07 H314 Aquatic Chronic 3 H412 Dgr H412

612-173-00-5 lithium 1-amino-4-(4-tert 411-140-0 125328-86-1 Eye Dam. 1 H318 GHS05 H318 butylanilino)anthraquinone-2- Skin Sens. 1 H317 GHS07 H317 sulfonate Aquatic Chronic 2 H411 GHS09 H411 Dgr

457

D050725/02

Classification Labelling Specific Conc. Limits, M-factors Notes

Index No International Chemical Identification EC No CAS No

Hazard Class and Category Hazard Suppl. Hazard

Code(s) Statement

Pictogram, Signal Hazard statement statement

Code(s) Word Code(s) Code(s) Code(s)

612-174-00-0 4,4-dimethoxybutylamine 407-690-6 19060-15-2 Acute Tox. 4 * H302 GHS05 H302

Skin Corr. 1B H314 GHS07 H314 Skin Sens. 1 H317 Dgr H317 Aquatic Chronic 3 H412 H412

612-175-00-6 2-(O-aminooxy)ethylamine 412-310-7 37866-45-8 Skin Sens. 1 H317 GHS07 H317 dihydrochloride Aquatic Chronic 3 H412 Wng H412

612-176-00-1 polymer of 1,3-dibromopropane and 410-570-6 143747-73-3 Aquatic Acute 1 H400 GHS09 H410

N,N-diethyl-N',N'-dimethyl-1,3- Aquatic Chronic 1 H410 Wng propanediamine

612-177-00-7 2-naphthylamino-6- 412-120-4 104295-55-8 STOT RE 2 * H373 ** GHS08 H373 ** sulfomethylamide Skin Sens. 1 H317 GHS09 H317

Aquatic Chronic 2 H411 Wng H411

612-178-00-2 1,4,7,10-tetraazacyclododecane 412-080-8 112193-77-8 Acute Tox. 4 * H302 GHS05 H302 disulfate STOT SE 3 H335 GHS07 H335 Eye Dam. 1 H318 Dgr H318 Aquatic Chronic 3 H412 H412

612-179-00-8 1-(2-propenyl)pyridinium chloride 412-740-5 25965-81-5 Acute Tox. 4 * H302 GHS07 H302

Skin Sens. 1 H317 Wng H317

612-180-00-3 3-aminobenzylamine 412-230-2 4403-70-7 Acute Tox. 4 * H302 GHS05 H302

Skin Corr. 1B H314 GHS07 H314 Aquatic Chronic 2 H411 GHS09 H411 Dgr

612-181-00-9 2-phenylthioaniline 413-030-8 1134-94-7 Skin Sens. 1 H317 GHS07 H317

Aquatic Chronic 2 H411 GHS09 H411 Wng

612-182-00-4 1-ethyl-1-methylmorpholinium 418-210-1 65756-41-4 Muta. 2 H341 GHS08 H341 bromide Wng

458

D050725/02

Classification Labelling Specific Conc. Limits, M-factors Notes

Index No International Chemical Identification EC No CAS No

Hazard Class and Category Hazard Pictogram, Signal Hazard Suppl. Hazard

Code(s) Statement statement statement Code(s) Word Code(s) Code(s) Code(s)

612-183-00-X 1-ethyl-1-methylpyrrolidinium 418-200-5 69227-51-6 Muta. 2 H341 GHS08 H341 bromide Wng

612-184-00-5 6'-(dibutylamino)-3'-methyl-2'- 403-830-5 89331-94-2 Aquatic Chronic 3 H412 — H412

(phenylamino)spiro[isobenzofuran 1(3H),9-(9H)-xanthen]-3-one

612-185-00-0 1-[3-[4- 407-400-8 59493-72-0 Eye Dam. 1 H318 GHS05 H318

((heptadecafluorononyl)oxy)- Aquatic Acute 1 H400 GHS09 H410 benzamido]propyl]-N,N,N- Aquatic Chronic 1 H410 Dgr trimethylammonium iodide

612-186-00-6 bis(N-(7-hydroxy-8-methyl-5- 406-770-8 149057-64-7 STOT RE 2 * H373 ** GHS08 H373 ** phenylphenazin-3- Eye Dam. 1 H318 GHS05 H318

ylidene)dimethylammonium) sulfate Skin Sens. 1 H317 GHS07 H317 Aquatic Acute 1 H400 GHS09 H410 Aquatic Chronic 1 H410 Dgr

612-187-00-1 2,3,4-trifluoroaniline 407-170-9 3862-73-5 Acute Tox. 4 * H312 GHS08 H312

Acute Tox. 4 * H302 GHS05 H302 STOT RE 2 * H373 ** GHS07 H373 ** Skin Irrit. 2 H315 GHS09 H315 Eye Dam. 1 H318 Dgr H318 Aquatic Chronic 2 H411 H411

612-188-00-7 4,4'-(9H-fluoren-9-ylidene)bis(2- 407-560-9 107934-68-9 Aquatic Chronic 2 H411 GHS09 H411 chloroaniline)

612-189-00-2 4-amino-2-(aminomethyl)phenol 412-510-4 135043-64-0 Acute Tox. 4 * H302 GHS07 H302 dihydrochloride Skin Sens. 1 H317 GHS09 H317 Aquatic Acute 1 H400 Wng H410 Aquatic Chronic 1 H410

612-190-00-8 4,4'-methylenebis(2-isopropyl-6- 415-150-6 16298-38-7 STOT RE 2 * H373 ** GHS08 H373 ** methylaniline) Aquatic Chronic 2 H411 GHS09 H411

Wng

612-191-00-3 polymer of allylamine hydrochloride 415-050-2 71550-12-4 Acute Tox. 4 * H302 GHS07 H302

Skin Sens. 1 H317 Wng H317

459

D050725/02

Classification Labelling Specific Conc. Limits, M-factors Notes

Index No International Chemical Identification EC No CAS No

Hazard Class and Category Hazard Pictogram, Signal Hazard Suppl. Hazard

Code(s) Statement statement Code(s) Word Code(s) statement Code(s) Code(s)

612-192-00-9 2-isopropyl-4-(N- 414-800-6 154212-60-9 Acute Tox. 4 * H312 GHS05 H312 methyl)aminomethylthiazole Acute Tox. 4 * H302 GHS07 H302 Skin Irrit. 2 H315 GHS09 H315 Eye Dam. 1 H318 Dgr H318 Aquatic Chronic 2 H411 H411

612-193-00-4 3-methylaminomethylphenylamine 414-570-7 18759-96-1 Acute Tox. 4 * H312 GHS05 H312

Acute Tox. 4 * H302 GHS07 H302 Skin Corr. 1B H314 GHS09 H314 Skin Sens. 1 H317 Dgr H317 Aquatic Acute 1 H400 H410 Aquatic Chronic 1 H410

612-194-00-X 2-hydroxy-3-[(2-hydroxyethyl)-[2- 414-670-0 141890-30-4 Acute Tox. 4 * H302 GHS05 H302

(1- Eye Dam. 1 H318 GHS07 H318 oxotetradecyl)amino]ethyl]amino]- Aquatic Acute 1 H400 GHS09 H410 N,N,N-trimethyl-1- Aquatic Chronic 1 H410 Dgr propanammonium chloride

612-195-00-5 bis[tributyl 4- 415-210-1 160236-81-7 Acute Tox. 4 * H332 GHS05 H332

(methylbenzyl)ammonium] 1,5- Acute Tox. 4 * H302 GHS07 H302 naphthalenedisulfonate Eye Dam. 1 H318 GHS09 H318 Aquatic Acute 1 H400 Dgr H410 Aquatic Chronic 1 H410

612-196-00-0 4-chloro-o-toluidine; [1] 202-441-6[1] 95-69-2[1] Carc. 1B H350 GHS06 H350

4-chloro-o-toluidine hydrochloride 221-627-8[2] 3165-93-3[2] Muta. 2 H341 GHS08 H341 [2] Acute Tox. 3 * H331 GHS09 H331 Acute Tox. 3 * H311 Dgr H311 Acute Tox. 3 * H301 H301 Aquatic Acute 1 H400 H410 Aquatic Chronic 1 H410

612-197-00-6 2,4,5-trimethylaniline; [1] 205-282-0[1]-[2] 137-17-7 [1] Carc. 1B H350 GHS06 H350

2,4,5-trimethylaniline hydrochloride 21436-97-5[2] Acute Tox. 3 * H331 GHS08 H331 [2] Acute Tox. 3 * H311 GHS09 H311 Acute Tox. 3 * H301 Dgr H301 Aquatic Chronic 2 H411 H411

460

D050725/02

Classification Labelling Specific Conc. Limits, M-factors Notes

Index No International Chemical Identification EC No CAS No

Hazard Class and Category Hazard Pictogram, Signal Hazard Suppl. Hazard

Code(s) Statement statement Code(s) Word Code(s) statement Code(s) Code(s)

612-198-00-1 4,4'-thiodianiline and its salts 205-370-9 139-65-1 Carc. 1B H350 GHS08 H350

Acute Tox. 4 * H302 GHS07 H302 Aquatic Chronic 2 H411 GHS09 H411 Dgr

612-199-00-7 4,4'-oxydianiline and its salts; 202-977-0 101-80-4 Carc. 1B Muta. H350 GHS06 H350 p-aminophenyl ether 1B Repr. 2 H340 GHS08 H340 Acute Tox. 3 * H361f *** GHS09 H361f *** Acute Tox. 3 * H331 Dgr H331 Acute Tox. 3 * H311 H311 Aquatic Chronic 2 H301 H301 H411 H411

612-200-00-0 2,4-diaminoanisole; 210-406-1 [1] 615-05-4 [1] Carc. 1B Muta. 2 H350 GHS08 H350

4-methoxy-m-phenylenediamine; [1] 254-323-9 [2] 39156-41-7 [2] Acute Tox. 4 * H341 GHS07 H341 2,4-diaminoanisole sulphate [2] Aquatic Chronic 2 H302 GHS09 H302 H411 Dgr H411

612-201-00-6 N,N,N',N'-tetramethyl-4,4'- 202-959-2 101-61-1 Carc. 1B H350 GHS08 H350 methylendianiline Aquatic Acute 1 H400 GHS09 H410 Aquatic Chronic 1 H410 Dgr

612-202-00-1 3,4-dichloroaniline 202-448-4 95-76-1 Acute Tox. 3 * H331 GHS06 H331

Acute Tox. 3 * H311 GHS05 H311 Acute Tox. 3 * H301 GHS09 H301 Eye Dam. 1 H318 Dgr H318 Skin Sens. 1 H317 H317 Aquatic Acute 1 H400 H410 Aquatic Chronic 1 H410

612-203-00-7 C 8-10 alkyl dimethyl hydroxyethyl 417-360-3 Acute Tox. 4 * H312 GHS07 H312

ammoniumchloride (chain < C 8 : Acute Tox. 4 * H302 Wng H302

<3%, chain = C — Skin Irrit. 2 H315 H315 8 : 15%-70%, chain

• = 

  C : 30%- 85%, chain > C : 10 10

<3%)

461

D050725/02

Classification Labelling Specific Conc. Limits, M-factors Notes

Index No International Chemical Identification EC No CAS No

Hazard Class and Category Hazard Hazard Suppl. Hazard

Code(s) Statement

Pictogram, Signal statement statement

Code(s) Word Code(s) Code(s) Code(s)

612-204-00-2 C.I. Basic Violet 3; 208-953-6 548-62-9 Carc. 2 H351 GHS08 H351

4-[4,4'-bis(dimethylamino) Acute Tox. 4 * H302 GHS05 H302 benzhydrylidene]cyclohexa-2,5- Eye Dam. 1 H318 GHS07 H318 dien-1-ylidene]dimethylammonium Aquatic Acute 1 H400 GHS09 H410 chloride Aquatic Chronic 1 H410 Dgr

612-205-00-8 C.I. Basic Violet 3 with ≥ 0,1% of 208-953-6 548-62-9 Carc. 1B H350 GHS08 H350

Michler's ketone (EC no.202-027-5) Acute Tox. 4 * H302 GHS05 H302 Eye Dam. 1 H318 GHS07 H318 Aquatic Acute 1 H400 GHS09 H410 Aquatic Chronic 1 H410 Dgr

612-206-00-3 famoxadone (ISO); — 131807-57-3 STOT RE 2 * H373 ** GHS08 H373 **

3-anilino-5-methyl-5-(4- Aquatic Acute 1 H400 GHS09 H410 phenoxyphenyl)-1,3-oxazolidine-2,4- Aquatic Chronic 1 H410 Wng dione

612-207-00-9 4-ethoxyaniline; 205-855-5 156-43-4 Muta. 2 H341 GHS08 H341 p-phenetidine Acute Tox. 4 * H332 GHS07 H332 Acute Tox. 4 * H312 Wng H312 Acute Tox. 4 * H302 H302 Eye Irrit. 2 H319 H319 Skin Sens. 1 H317 H317

612-208-00-4 N-methylbenzene-1,2-diammonium 424-460-0 Acute Tox. 4 * H302 GHS07 H302 hydrogen phosphate Skin Sens. 1 H317 GHS09 H317 — Aquatic Chronic 2 H411 Wng H411

612-209-00-X 6-methoxy-m-toluidine; 204-419-1 120-71-8 Carc. 1B H350 GHS08 H350 p-cresidine Acute Tox. 4 * H302 GHS07 H302

Dgr

462

D050725/02

Classification Labelling Specific Conc. Limits, M-factors Notes

Index No International Chemical Identification EC No CAS No

Hazard Class and Category Hazard Suppl. Hazard

Code(s) Statement

Pictogram, Signal Hazard statement statement

Code(s) Word Code(s) Code(s) Code(s)

612-210-00-5 5-nitro-o-toluidine; [1] 202-765-8 [1] 99-55-8 [1] Carc. 2 H351 GHS06 H351

5-nitro-o-toluidine hydrochloride [2] 256-960-8 [2] 51085-52-0 [2] Acute Tox. 3 * H331 GHS08 H331 Acute Tox. 3 * H311 Dgr H311 Acute Tox. 3 * H301 H301 Aquatic Chronic 3 H412 H412

612-211-00-0 N-[(benzotriazole-1-yl)methyl)]4- 416-470-9 170292-97-4 Eye Irrit. 2 H319 GHS07 H319 carboxy-benzenesulfonamide Aquatic Chronic 2 H411 GHS09 H411 Wng

612-212-00-6 2,6-dichloro-4-trifluoromethylaniline 416-430-0 24279-39-8 Acute Tox. 4 * H332 GHS07 H332

Acute Tox. 4 * H302 GHS09 H302 Skin Irrit. 2 H315 Wng H315 Skin Sens. 1 H317 H317 Aquatic Acute 1 H400 H410 Aquatic Chronic 1 H410

612-213-00-1 isobutylidene-(2-(2-isopropyl-4,4- 419-850-2 148348-13-4 Skin Corr. 1B H314 GHS05 H314 dimethyloxazolidine-3-yl)-1,1- Aquatic Chronic 3 H412 Dgr H412 dimethylethyl)amine

612-214-00-7 4-(2,2-diphenylethenyl)-N,N-di 421-390-2 89114-90-9 Aquatic Chronic 4 H413 — H413 phenylbenzenamine

612-215-00-2 3-chloro-2-(isopropylthio)aniline 421-700-6 179104-32-6 Skin Irrit. 2 H315 GHS07 H315

Aquatic Chronic 2 H411 GHS09 H411 Wng

612-216-00-8 1-amino-1-cyanamino-2,2- 425-870-2 19450-38-5 Skin Sens. 1 H317 GHS07 H317 dicyanoethylene, sodium salt Aquatic Chronic 3 H412 Wng H412

612-217-00-3 1-methoxy-2-propylamine 422-550-4 37143-54-7 Flam. Liq. 2 H225 GHS02 H225

Skin Corr. 1B H314 GHS05 H314 Acute Tox. 4 * H302 GHS07 H302 Aquatic Chronic 3 H412 Dgr H412

463

D050725/02

Classification Labelling Specific Conc. Limits, M-factors Notes

Index No International Chemical Identification EC No CAS No

Hazard Class and Category Hazard Pictogram, Signal Hazard Suppl. Hazard

Code(s) Statement statement Code(s) Word Code(s) statement Code(s) Code(s)

612-219-00-4 (2-hydroxy-3-(3,4-dimethyl-9-oxo 402-200-7 Aquatic Chronic 3 H412 — H412

10-thiaanthracen-2- — yloxy)propyl)trimethylammonium chloride

612-220-00-X N-nitro-N-(3-methyl-3,6-dihydro 431-060-1 153719-38-1 Acute Tox. 4 * H302 GHS07 H302

2H-1,3,5-oxadiazin-4-yl)amine Skin Sens. 1 H317 Wng H317 Aquatic Chronic 3 H412 H412

612-221-00-5 2-amino-4- 429-560-8 4274-38-8 Skin Corr. 1B H314 GHS05 H314

(trifluoromethyl)benzenethiol Acute Tox. 4 * H332 GHS08 H332 hydrochloride Acute Tox. 4 * H312 GHS07 H312 Acute Tox. 4 * H302 GHS09 H302 STOT RE 2 * H373** Dgr H373** Skin Sens. 1 H317 H317 Aquatic Acute 1 H400 H400

612-222-00-0 cis-1-(3-(4-fluorophenoxy)propyl)-3- 425-080-8 104860-26-6 Acute Tox. 4 * H312 GHS05 H312 methoxy-4-piperidinamine Acute Tox. 4 * H302 GHS08 H302 STOT RE 2 * H373** GHS07 H373** Eye Dam. 1 H318 GHS09 H318 Aquatic Acute 1 H400 Dgr H410 Aquatic Chronic 1 H410

612-223-00-6 N-benzyl-N-ethyl-(4-(5-nitro 425-300-2 186450-73-7 Skin Sens. 1 H317 GHS07 H317 benzo[c]isothiazol-3- Aquatic Chronic 4 H413 Wng H413 ylazo)phenyl)amine

612-224-00-1 N2,N4,N6-tris{4-[(1,4- 426-150-0 121246-28-4 Skin Sens. 1 H317 GHS07 H317 dimethylpentyl)amino]phenyl}- Aquatic Acute 1 H400 GHS09 H410 1,3,5-triazine-2,4,6-triamine Aquatic Chronic 1 H410 Wng

612-225-00-7 1,4,7,10-tetraazacyclododecane 425-450-9 294-90-6 Skin Corr. 1B H314 GHS05 H314

Acute Tox. 4 * H312 GHS07 H312 Acute Tox. 4 * H302 GHS09 H302 Aquatic Acute 1 H400 Dgr H410 Aquatic Chronic 1 H410

464

D050725/02

Classification Labelling Specific Conc. Limits, M-factors Notes

Index No International Chemical Identification EC No CAS No

Hazard Class and Category Hazard Hazard Suppl. Hazard

Code(s) Statement

Pictogram, Signal statement statement

Code(s) Word Code(s) Code(s) Code(s)

612-226-00-2 3-(2'-phenoxyethoxy)propylamine 427-870-8 6903-18-0 Acute Tox. 4 * H302 GHS05 H302

Skin Irrit. 2 H315 GHS07 H315 Eye Dam. 1 H318 Dgr H318 Aquatic Chronic 3 H412 H412

612-227-00-8 benzyl-N-(2-(2- 428-290-8 120606-08-8 Acute Tox. 4 * H302 GHS05 H302 methoxyphenoxy)ethyl)amine Eye Dam. 1 H318 GHS07 H318 hydrochloride Aquatic Acute 1 H400 GHS09 H410 Aquatic Chronic 1 H410 Dgr

612-228-00-3 reaction mass of: N-(3- 414-340-6 Flam. Liq. 3 H226 GHS02 H226

(trimethoxysilyl)propyl)ethylenedia — Acute Tox. 4 * H332 GHS05 H332 mine; Acute Tox. 4 * H312 GHS08 H312 N-benzyl-N-(3- Acute Tox. 4 * H302 GHS07 H302 (trimethoxysilyl)propyl)ethylenedia STOT SE 2 H371 Dgr H371 mine; N-benzyl-N'-[3- Eye Dam. 1 H318 H318 (trimethoxysilyl)propyl]ethylenedia Skin Sens. 1 H317 H317 mine; Aquatic Chronic 3 H412 H412 N,N'-bis-benzyl-N'-[3- (trimethoxysilyl)propyl]ethylenedia mine; N,N,N'-tris-benzyl-N'-[3- (trimethoxysilyl)propyl]ethylenedia mine; N,N-bis-benzyl-N'-[3- (trimethoxysilyl)propyl]ethylenedia mine

612-229-00-9 mepanipyrim; 110235-47-7 Carc. 2 H351 GHS08 H351

4-methyl-N-phenyl-6-(1-propynyl)- — Aquatic Acute 1 H400 GHS09 H410 2-pyrimidinamine Aquatic Chronic 1 H410 Wng

612-230-00-4 N,N-bis(cocoyl-2-oxypropyl)-N,N- 431-530-4 — Skin Corr. 1A H314 GHS05 H314 dibutylammonium bromide Skin Sens. 1 H317 GHS07 H317 Aquatic Acute 1 H400 GHS09 H410 Aquatic Chronic 1 H410 Dgr

465

D050725/02

Classification Labelling Specific Conc. Limits, M-factors Notes

Index No International Chemical Identification EC No CAS No

Hazard Class and Category Hazard Hazard Suppl. Hazard

Code(s) Statement

Pictogram, Signal statement statement

Code(s) Word Code(s) Code(s) Code(s)

612-231-00-X 3-((C 12-18 )-acylamino)-N-(2-((2- 427-370-1 164288-56-6 Eye Dam. 1 H318 GHS05 H318 hydroxyethyl)amino)-2-oxoethyl)- Aquatic Acute 1 H400 GHS09 H410 N,N-dimethyl-1-propanaminium Aquatic Chronic 1 H410 Dgr

chloride

612-232-00-5 reaction mass of: 430-410-9 186148-38-9 Aquatic Chronic 3 H412 — H412 triisopropanolamine salt of 1-amino

4-(3- propionamidoanilino)anthraquinone 2-sulfonic acid; triisopropanolamine salt of 1-amino-4-[3,4-dimethyl-5- (2- hydroxyethylaminosulfonyl)anilino]a nthraquinone-2-sulfonic acid

612-237-00-2 hydroxylammonium 233-154-4 [1] 10046-00-1 [1] Expl. 1.1 H201 GHS01 H201 hydrogensulfate; 244-077-0 [2] 20845-01-6 [2] Carc. 2 H351 GHS08 H351

hydroxylamine sulfate(1:1); [1] 242-818-2 [3] 19098-16-9 [3] Acute Tox. 4 * H312 GHS07 H312 T

hydroxylamine phosphate; [2] 258-872-5 [4] 53933-48-5 [4] Acute Tox. 4 * H302 GHS09 H302 hydroxylamine dihydrogenphos STOT RE 2 * H373** Dgr H373** phate; [3] hydroxylamine 4- Eye Irrit. 2 H319 H319 methylben Skin Irrit. 2 H315 H315 zenesulfonate [4] Skin Sens. 1 H317 H317 Aquatic Acute 1 H400 H400

612-238-00-8 (3-chloro-2-hydroxypropyl) 222-048-3 3327-22-8 Carc. 2 H351 GHS08 H351 B trimethylammonium chloride …% Aquatic Chronic 3 H412 Wng H412

612-239-00-3 biphenyl-3,3', 4,4'-tetrayltetraamine; 202-110-6 91-95-2 Carc. 1B Muta. 2 H350 GHS08 H350 diaminobenzidine H341 Dgr H341

612-240-00-9 pyrimethanil (ISO); — 53112-28-0 Aquatic Chronic 2 H411 GHS09 H411

N-(4,6-dimethylpyrimidin-2- yl)aniline

466

D050725/02

Classification Labelling Specific Conc. Limits, M-factors Notes

Index No International Chemical Identification EC No CAS No

Hazard Class and Category Hazard Hazard Suppl. Hazard

Code(s) Statement

Pictogram, Signal

Code(s) Word Code(s)

statement statement Code(s) Code(s)

612-241-00-4 piperazine hydrochloride; [1] 228-042-7 [1] 6094-40-2 [1] Repr. 2 H361fd GHS08 H361fd piperazine dihydrochloride; [2] 205-551-2 [2] 142-64-3 [2] Eye Irrit. 2 H319 Dgr H319 piperazine phosphate [3] 217-775-8 [3] 1951-97-9 [3] Skin Irrit. 2 H315 H315 Resp. Sens. 1 H334 H334 Skin Sens. 1 H317 H317 Aquatic Chronic 3 H412 H412

612-242-00-X cyprodinil (ISO); — 121552-61-2 Skin Sens. 1 H317 GHS07 H317 M=10

4-cyclopropyl-6-methyl-N- Aquatic Acute 1 H400 GHS09 H410 phenylpyrimidin-2-amine Aquatic Chronic 1 H410 Wng

612-243-00-5 (1S-cis)-4-(3,4-dichlorophenyl)- 420-560-3 79617-97-3 Eye Dam. 1 H318 GHS05 H318 M=10

1,2,3,4-tetrahydro-N-methyl-1- Aquatic Acute 1 H400 GHS09 H410 naphthalenamine 2-hydroxy-2- Aquatic Chronic 1 H410 Dgr phenylacetate

612-244-00-0 3-(piperazin-1-yl)- 421-310-6 87691-88-1 Repr. 2 H361f*** GHS08 H361f*** benzo[d]isothiazole hydrochloride Acute Tox. 4 * H302 GHS07 H302

Eye Irrit. 2 H319 GHS09 H319 Skin Sens. 1 H317 Wng H317 Aquatic Acute 1 H400 H410 Aquatic Chronic 1 H410

612-245-00-6 2-ethylphenylhydrazine 421-460-2 19398-06-2 Carc. 2 H351 GHS05 H351 M=10 hydrochloride STOT RE 1 H372** GHS08 H372**

Acute Tox. 4 * H302 GHS07 H302 Eye Dam. 1 H318 GHS09 H318 Skin Sens. 1 H317 Dgr H317 Aquatic Acute 1 H400 H410 Aquatic Chronic 1 H410

612-246-00-1 (2-chloroethyl)(3- 429-740-6 40722-80-3 Carc. 1B H350 GHS08 H350 hydroxypropyl)ammonium chloride Muta. 1B H340 GHS07 H340 STOT RE 2 * H373** Dgr H373** Skin Sens. 1 H317 H317 Aquatic Chronic 3 H412 H412

612-247-00-7 N-[3-(1,1-dimethylethyl)-1H- 423-530-8 152828-23-4 STOT RE 1 H372** H302 GHS08 H372** pyrazol-5-yl]-N'-hydroxy-4- Acute Tox. 4 * H412 GHS07 H302

nitrobenzenecarboximidamide Aquatic Chronic 3 Dgr H412

467

D050725/02

Classification Labelling Specific Conc. Limits, M-factors Notes

Index No International Chemical Identification EC No CAS No

Hazard Class and Category Hazard Pictogram, Signal Hazard Suppl. Hazard

Code(s) Statement statement Code(s) Word Code(s) statement Code(s) Code(s)

612-248-00-2 reaction product of diphenylamine, 439-540-0 — Skin Irrit. 2 H315 GHS07 H315 phenothiazine, and alkenes, branched Skin Sens. 1 H317 Wng H317 (C 8-10 , C 9 -rich) Aquatic Chronic 4 H413 H413

612-249-00-8 4-[(3-chlorophenyl)(1H-imidazol-1- 425-030-5 159939-85-2 Repr. 2 H361f*** GHS05 H361f*** yl)methyl]-1,2-benzenediamine Acute Tox. 4 * H302 GHS08 H302

dihydrochloride Skin Corr. 1B H314 GHS07 H314 Skin Sens. 1 H317 GHS09 H317 Aquatic Chronic 2 H411 Dgr H411

612-250-00-3 chloro-N,N-dimethylformiminium 425-970-6 3724-43-4 Repr. 1B H360D*** GHS05 H360D*** EUH014 chloride Acute Tox. 4 * H302 GHS08 H302

Skin Corr. 1A H314 GHS07 H314 Dgr

612-251-00-9 cis-1-(3-chloroallyl)-3,5,7-triaza-1- 426-020-3 51229-78-8 Flam. Sol. 2 H228 GHS02 H228 azoniaadamantane chloride Repr. 2 H361d*** GHS08 H361d*** Acute Tox. 4 * H302 GHS07 H302 Skin Irrit. 2 H315 GHS09 H315 Skin Sens. 1 H317 Wng H317 Aquatic Chronic 2 H411 H411

612-252-00-4 imidacloprid (ISO); 428-040-8 138261-41-3 Acute Tox. 4 * H302 GHS07 H302

1-(6-chloropyridin-3-ylmethyl)-N- Aquatic Acute 1 H400 GHS09 H410 nitroimidazolidin-2-ylidenamine Aquatic Chronic 1 H410 Wng

612-253-00-X 7-methoxy-6-(3-morpholin-4-yl 429-400-7 199327-61-2 Aquatic Chronic 3 H412 — H412 propoxy)-3H-quinazolin-4-one;

[containing < 0,5% formamide (EC No 200-842-0)]

612-253-01-7 7-methoxy-6-(3-morpholin-4-yl 429-400-7 199327-61-2 Repr. 1B H360D*** GHS08 H360D*** propoxy)-3H-quinazolin-4-one; Aquatic Chronic 3 H412 Dgr H412

[containing ≥ 0,5% formamide (EC No 200-842-0)]

468

D050725/02

Classification Labelling Specific Conc. Limits, M-factors Notes

Index No International Chemical Identification EC No CAS No

Hazard Class and Category Hazard Pictogram, Signal Hazard Suppl. Hazard

Code(s) Statement Code(s) Word Code(s) statement statement Code(s) Code(s)

612-254-00-5 reaction products of 432-440-8 220444-73-5 Carc. 2 H351 GHS05 H351 diisopropanolamine with Acute Tox. 4 * H302 GHS08 H302 formaldehyde (1:4) Skin Corr. 1B H314 GHS07 H314 Skin Sens. 1 H317 GHS09 H317 Aquatic Chronic 2 H411 Dgr H411

612-255-00-0 1-(3-methoxypropyl)-4- 431-950-8 179474-79-4 Acute Tox. 4 * H312 GHS05 H312 piperidinamine Acute Tox. 4 * H302 GHS07 H302 Skin Corr. 1B H314 Dgr H314 Aquatic Chronic 3 H412 H412

612-256-00-6 benzyl(S)-2-[(2'-cyanobiphenyl-4- 427-470-3 137864-22-3 Acute Tox. 4 * H302 GHS07 H302 ylmethyl)pentanoylamino]-3- Skin Sens. 1 H317 Wng H317 methylbutyrate

612-257-00-1 tripropylammonium 433-700-3 35687-90-2 Acute Tox. 4 * H302 GHS07 H302 dihydrogenphosphate Wng

612-259-00-2 N-ethyl-3-trimethoxysilyl-2-methyl 437-720-3 227085-51-0 Eye Dam. 1 H318 GHS05 H318 propanamine Dgr

612-261-00-3 3,5-dichloro-2-fluoro-4-(1,1,2,3,3,3- 441-190-9 121451-05-6 Acute Tox. 4 * H302 GHS07 H302 M=10 hexafluoropropoxy)aniline Skin Sens. 1 H317 GHS09 H317

Aquatic Acute 1 H400 Wng H410 Aquatic Chronic 1 H410

612-265-00-5 bis(2-hydroxyethyl)-(2- 444-360-0 191617-13-7 Aquatic Chronic 3 H412 H412 hydroxypropyl)ammonium acetate —

469

D050725/02

Classification Labelling Specific Conc. Limits, M-factors Notes

Index No International Chemical Identification EC No CAS No

Hazard Class and Category Hazard Suppl. Hazard

Code(s) Statement

Pictogram, Signal Hazard statement

Code(s) Word Code(s)

statement Code(s) Code(s)

612-266-00-0 3-chloro-4-(3- 445-590-4 202197-26-0 Muta. 2 H341 GHS08 H341 fluorobenzyloxy)aniline Acute Tox. 4 * H302 GHS07 H302 STOT RE 2 * H373** GHS09 H373** Aquatic Acute 1 H400 Wng H410 Aquatic Chronic 1 H410

612-267-00-6 bis(hydrogenated tallow C 16-18 - 418-370-0 Skin Sens. 1 H317 GHS07 H317 alkyl)hydroxylamine — Aquatic Chronic 4 H413 Wng H413

612-269-00-7 reaction mass of: 1-[di(4- 420-720-2 Aquatic Chronic 4 H413 H413 octylphenyl)aminomethyl]-5-methyl— —

1H-benzotriazole; 1-[di(4-octylphenyl)aminomethyl]-4- methyl-1H-benzotriazole; reaction mass of: N-[(5-methyl-1H- benzotriazol-1-yl)methyl]-4-octyl-N- (4-octylphenyl)aniline; N-[(4-methyl-1H-benzotriazol 1yl)methyl]-4-octyl-N-(4- octylphenyl)aniline

612-270-00-2 (S)-azetidine-2-carboxylic acid 433-010-2 Acute Tox. 4 * H302 GHS07 H302

4-cyanobenzylamide hydrochloride Skin Sens. 1 H317 Wng H317

— Aquatic Chronic 3 H412 H412

612-271-00-8 reaction mass of: ethyl 2-((4-(5,6- 434-970-5 160987-57-5 Aquatic Chronic 4 H413 H413 dichlorobenzothiazol-2- —

ylazo)phenyl)ethylamino)benzoate; ethyl 2-((4-(6,7- dichlorobenzothiazol-2- ylazo)phenyl)ethylamino)benzoate

470

D050725/02

Classification Labelling Specific Conc. Limits, M-factors Notes

Index No International Chemical Identification EC No CAS No

Hazard Class and Category Hazard Pictogram, Signal Hazard Suppl. Hazard

Code(s) Statement statement statement Code(s) Word Code(s) Code(s) Code(s)

612-272-00-3 ammonium (η-6-2-(2-(1,2- 435-210-5 Aquatic Chronic 2 H411 GHS09 H411

dicarboxylatoethylamino)ethylamino —

)butane-1,4-dioato(4))iron(3+) monohydrate

612-273-00-9 alkyl(rapeseed oil), bis(2- 435-650-8 Acute Tox. 4 * H302 GHS05 H302 hydroxyethyl)ammonium fluoride — Skin Corr. 1A H314 GHS07 H314

Aquatic Acute 1 H400 GHS09 H410 Aquatic Chronic 1 H410 Dgr

612-274-00-4 (R,S)-1-[2-amino-1(4- 445-750-3 — Acute Tox. 4 * H302 GHS05 H302 methoxyphenyl)ethyl]cyclohexanol Eye Dam. 1 H318 GHS07 H318 acetate Skin Sens. 1 H317 Dgr H317 Aquatic Chronic 3 H412 H412

612-275-00-X fatty acids, C 18 -unsatd., dimers, 447-880-6 206565-89-1 Skin Irrit. 2 H315 GHS05 H315 M=10 reaction products with 1- Eye Dam. 1 H318 GHS07 H318

piperazineethanamine and tall oil Skin Sens. 1 H317 GHS09 H317 Aquatic Acute 1 H400 Dgr H410 Aquatic Chronic 1 H410

612-276-00-5 1-amino-4-[(4-amino-2- 451-430-4 500717-36-2 Eye Dam. 1 H318 GHS05 H318 sulfofenyl)amino]-9,10-dihydro Skin Sens. 1 H317 GHS07 H317 9,10-dioxo-2-anthracenesulfonic Aquatic Chronic 3 H412 Dgr H412 acid, disodium salt, reaction products

with 2-[[3-[(4,6-dichloro-1,3,5- triazin-2- yl)ethylamino]phenyl]sulfonyl]ethyl hydrogen sulfate, sodium salts

471

D050725/02

Classification Labelling Specific Conc. Limits, M-factors Notes

Index No International Chemical Identification EC No CAS No

Hazard Class and Category Hazard Hazard Suppl. Hazard

Code(s) Statement

Pictogram, Signal statement

Code(s) Word Code(s)

statement Code(s) Code(s)

612-277-00-0 reaction mass of: 4-amino-3-(4- 451-440-9 586372-44-3 Eye Dam. 1 H318 GHS05 H318 ethenesulfonyl-2- Dgr

sulfonatophenylazo)-5-hydroxy-6-(5- {4-chloro-6-[4-(2- sulfonatooxyethanesulfonyl)phenyla mino]-1,3,5-triazin-2-ylamino}-2- sulfonatophenylazo)naphthalene-2,7- disulfonate potassium/sodium; 4-amino-5-hydroxy-6-(5-{4-chloro 6-[4-(2- sulfonatooxyethanesulfonyl)phenyla mino]1,3,5-triazin-2-ylamino}-2- sulfonatophenylazo)-3-(2-sulfonato 4-(2- sulfonatooxyethanesulfonyl)phenyla zo)naphthalene-2,7-disulfonate potassium/sodium

612-278-00-6 ethidium bromide; 214-984-6 1239-45-8 Muta. 2 H341 GHS06 H341

3,8-diamino-1-ethyl-6- Acute Tox. 2 * H330 GHS08 H330 phenylphenantridinium bromide Acute Tox. 4 * H302 Dgr H302

612-279-00-1 (R, S)-2-amino-3,3-dimethylbutane 447-860-7 144177-62-8 Repr. 2 H361f*** GHS08 H361f*** amide STOT RE 2 * H373** H319 GHS07 H373** Eye Irrit. 2 H315 Wng H319

Skin Irrit. 2 H317 H315 Skin Sens. 1 H317

612-280-00-7 3-amino-9-ethyl carbazole; 205-057-7 132-32-1 Carc. 1B H350 GHS08 H350

9-ethylcarbazol-3-ylamine Dgr

612-281-00-2 leucomalachite green; N,N,N',N'- 204-961-9 129-73-7 Carc. 2 H351 GHS08 H351 tetramethyl-4,4'-benzylidenedianiline Muta. 2 H341 Wng H341

472

D050725/02

Classification Labelling Specific Conc. Limits, M-factors Notes

Index No International Chemical Identification EC No CAS No

Hazard Class and Category Hazard Pictogram, Signal Hazard Suppl. Hazard

Code(s) Statement Code(s) Word Code(s) statement statement Code(s) Code(s)

612-282-00-8 octadecylamine 204-695-3 124-30-1 Asp. Tox. 1 H304 GHS05 H304

STOT RE 2 H373 GHS08 H373 M = 10 (gastrointestin (gastrointestin M = 10 al tract, liver, al tract, liver,

immune immune system) system)

Skin Irrit. 2 H315 GHS09 H315 Eye Dam. 1 H318 Dgr H318 Aquatic Acute 1 H400 H410 Aquatic Chronic 1 H410

612-283-00-3 (Z)-octadec-9-enylamine 204-015-5 112-90-3 Acute Tox. 4 H302 GHS05 H302 M = 10

Asp Tox. 1 H304 GHS07 H304 M = 10 STOT SE 3 H335 GHS08 H335 STOT RE 2 H373 (gastro GHS09 H373 (gastrointestinal tract, intestinal tract, liver, immune liver, immune system) system)

Skin Corr. 1B Aquatic H314 Dgr H314 Acute 1 H400 Aquatic Chronic 1 H410 H410

612-284-00-9 amines, hydrogenated tallow alkyl 262-976-6 61788-45-2 Asp Tox. 1 H304 GHS08 H304 M = 10

STOT RE 2 H373 (gastro GHS05 H373 (gastro M = 10 intestinal tract, intestinal tract,

liver, immune liver, immune system) system) H315 H318

Skin Irrit. 2 H315 GHS09 Eye Dam. 1 H318 Dgr Aquatic Acute 1 H400 H410 Aquatic Chronic 1 H410

473

D050725/02

Classification Labelling Specific Conc. Limits, M-factors Notes

Index No International Chemical Identification EC No CAS No

Hazard Class and Category Hazard Pictogram, Signal Hazard Suppl. Hazard

Code(s) Statement statement Code(s) Word Code(s) statement Code(s) Code(s)

612-285-00-4 amines, coco alkyl 262-977-1 61788-46-3 Acute Tox. 4 H302 GHS05 H302 M = 10

Asp. Tox. 1 H304 GHS07 H304 M = 10 STOT SE 3 H335 GHS08 H335 STOT RE 2 H373 (gastro GHS09 H373 (gastrointestinal tract, intestinal tract, liver, immune liver, immune system) system) H314

Skin Corr. 1B Dgr H410 Aquatic Acute 1 H314 Aquatic Chronic 1 H400

H410

612-286-00-X amines, tallow alkyl 263-125-1 61790-33-8 Acute Tox. 4 H302 GHS05 H302 M = 10

Asp. Tox. 1 H304 GHS07 H304 M = 10 STOT RE 2 H373 (gastro GHS08 H373 (gastrointestinal tract, intestinal tract, liver, immune liver, immune system) system) H314

Skin Corr. 1B H314 GHS09 H410 Aquatic Acute 1 H400 Dgr Aquatic Chronic 1 H410

fluazinam (ISO); 3-chloro-N-[3- chloro-2,6-dinitro-4-(trifluor

612-287-00-5 omethyl)phenyl]-5- - 79622-59-6 Repr. 2 H361d GHS08 H361d M = 10

(trifluor-omethyl)pyridin-2-amine Acute Tox. 4 H332 GHS07 H332 M = 10 Eye Dam. 1 H318 GHS05 H318

Skin Sens. 1A H317 GHS09 H317 Aquatic Acute 1 H400 Dgr H410 Aquatic Chronic 1 H410

ethyleneimine;aziridine 613-001-00-1 205-793-9 151-56-4 Flam. Liq. 2 H225 GHS02 H225 D

Carc. 1B H350 GHS06 H350 Muta. 1B H340 GHS08 H340 Acute Tox. 2 * H330 GHS05 H330 Acute Tox. 1 H310 GHS09 H310 Acute Tox. 2 * H300 Dgr H300 Skin Corr. 1B H314 H314 Aquatic Chronic 2 H411 H411

474

D050725/02

Classification Labelling Specific Conc. Limits, M-factors Notes

Index No International Chemical Identification EC No CAS No

Hazard Class and Category Hazard Suppl. Hazard

Code(s) Statement

Pictogram, Signal Hazard statement statement

Code(s) Word Code(s) Code(s) Code(s)

pyridine 613-002-00-7 203-809-9 110-86-1 Flam. Liq. 2 H225 GHS02 H225 *

Acute Tox. 4 * H332 GHS07 H332 Acute Tox. 4 * H312 Dgr H312 Acute Tox. 4 * H302 H302

1,2,3,4-tetranitrocarbazole

613-003-00-2 — 6202-15-9 Expl. 1.1 H201 GHS01 H201

Acute Tox. 4 * H332 GHS07 H332 Acute Tox. 4 * H312 Dgr H312 Acute Tox. 4 * H302 H302

crimidine (ISO);2-chloro-6- methylpyrimidin-4- yldimethylamine

613-004-00-8 208-622-6 535-89-7 Acute Tox. 2 * H300 GHS06 H300

Dgr

desmetryne (ISO);6-isopropylamino-2- 613-007-00-4 methylamino-4-methylthio-1,3,5- 213-800-1 1014-69-3 Acute Tox. 4 * H312 GHS07 H312

triazine Acute Tox. 4 * H302 GHS09 H302 Aquatic Acute 1 H400 Wng H410 Aquatic Chronic 1 H410

dazomet (ISO);tetrahydro-3,5- 613-008-00-X dimethyl-1,3,5- thiadiazine-2-thione 208-576-7 533-74-4 Acute Tox. 4 * H302 GHS07 H302

Eye Irrit. 2 H319 GHS09 H319 Aquatic Acute 1 H400 Wng H410 Aquatic Chronic 1 H410

2,4,6-trichloro-1,3,5-triazine;cyanuric 613-009-00-5 chloride 203-614-9 108-77-0 Acute Tox. 2 * H330 GHS06 H330 EUH014 STOT SE 3; H335:

Acute Tox. 4 * H302 GHS05 H302 C ≥ 5% Skin Corr. 1B H314 Dgr H314 Skin Sens. 1 H317 H317

ametryn (ISO);N-ethyl-N'-isopropyl-6- 613-010-00-0 (methyl-thio)-1,3,5-triazine-2,4- 212-634-7 834-12-8 Acute Tox. 4 * H302 GHS07 H302 M = 100

diamine Aquatic Acute 1 H400 GHS09 H410 Aquatic Chronic 1 H410 Wng

475

D050725/02

Classification Labelling Specific Conc. Limits, M-factors Notes

Index No International Chemical Identification EC No CAS No

Hazard Class and Category Hazard Hazard Suppl. Hazard

Code(s) Statement

Pictogram, Signal

Code(s) Word Code(s)

statement statement Code(s) Code(s)

amitrole (ISO);1,2,4-triazol-3-ylamine

613-011-00-6 200-521-5 61-82-5 Repr. 2 H361d *** GHS08 H361d ***

STOT RE 2 * H373 ** GHS09 H373 ** Aquatic Chronic 2 H411 Wng H411

bentazone (ISO);3-isopropyl-2,1,3- 613-012-00-1 benzothia-diazine-4-one-2,2-dioxide 246-585-8 25057-89-0 Acute Tox. 4 * H302 GHS07 H302

Eye Irrit. 2 H319 Wng H319 Skin Sens. 1 H317 H317 Aquatic Chronic 3 H412 H412

cyanazine (ISO);2-(4-chloro-6- 613-013-00-7 ethylamino-1,3,5- triazine-2-ylamino)- 244-544-9 21725-46-2 Acute Tox. 4 * H302 GHS07 H302

2-methylpropionitrile Aquatic Acute 1 H400 GHS09 H410 Aquatic Chronic 1 H410 Wng

ethoxyquin (ISO); 6-ethoxy-1,2- 613-014-00-2 dihydro-2,2,4-trimethylquinoline 202-075-7 91-53-2 Acute Tox. 4* H302 GHS07 H302

Wng

fenazaflor (ISO); phenyl 5,6-dichloro 613-015-00-8 2-trifluor-omethylbenzimidazole-1- 238-134-9 14255-88-0 Acute Tox. 4* H312 GHS07 H312

carboxylate Acute Tox. 4* H302 GHS09 H302 Aquatic Acute 1 H400 Wng H410 Aquatic Chronic 1 H410

fuberidazole (ISO);2-(2-furyl-)-1H- 613-016-00-3 benzimidazole 223-404-0 3878-19-1 Carc. 2 H351 GHS07 H351

Acute Tox. 4 H302 GHS08 H302 M = 1 STOT RE 2 H373 (heart) GHS09 H373 (heart) Skin Sens. 1 H317 Wng H317 Aquatic Acute 1 H400 H410 Aquatic Chronic 1 H410

bis(8-hydroxyquinolinium) sulphate 613-017-00-9 205-137-1 134-31-6 Acute Tox. 4* H302 GHS07 H302

Wng

476

D050725/02

Classification Labelling Specific Conc. Limits, M-factors Notes

Index No International Chemical Identification EC No CAS No

Hazard Class and Category Hazard Pictogram, Signal Hazard Suppl. Hazard

Code(s) Statement statement statement Code(s) Word Code(s) Code(s) Code(s)

morfamquat (ISO); 1,1'-bis(3,5- 613-018-00-4 dimethylmorpholinocarbonylmethyl)- 7411-47-4 Acute Tox. 4* H302 GHS07 H302

4,4'-bipyridilium ion Eye Irrit. 2 H319 Wng H319 STOT SE 3 H335 H335 Skin Irrit. 2 H315 H315 Aquatic Chronic 3 H412 H412

thioquinox(ISO); 2-thio-1,3- dithiolo(4,5,b)quinoxaline

613-019-00-X 202-272-8 93-75-4 Acute Tox. 4 * H302 GHS07 H302

Wng

tridemorph (ISO); 2,6-dimethyl-4- tridecylmorpholine Repr. 1B H360D *** GHS08 H360D ***

613-020-00-5 246-347-3 24602-86-6 Acute Tox. 4 * H332 GHS07 H332

Acute Tox. 4 * H302 GHS09 H302 Skin Irrit. 2 H315 Dgr H315 Aquatic Acute 1 H400 H410 Aquatic Chronic 1 H410

dithianon (ISO); 5,10-dihydro-5,10- 613-021-00-0 dioxonaphtho(2,3-b)(1,4)dithiazine 222-098-6 3347-22-6 Acute Tox. 4 * H302 GHS07 H302

2,3- dicarbonitrile Aquatic Acute 1 H400 GHS09 H410 Aquatic Chronic 1 H410 Wng

pyrethrins including cinerins, with the exception of those specified elsewhere Acute Tox. 4 * H332 GHS07 H332

613-022-00-6 in this Annex — Acute Tox. 4 * H312 GHS09 H312 A

— Acute Tox. 4 * H302 Wng H302 Aquatic Acute 1 H400 H410 Aquatic Chronic 1 H410

2-methyl-4-oxo-3-(penta-2,4- 613-023-00-1 dienyl)cyclopent-2-enyl [1R- 204-455-8 121-21-1 Acute Tox. 4 * H332 GHS07 H332

[1α[S*(Z)],3β]]-chrysanthemate; Acute Tox. 4 * H312 GHS09 H312 pyrethrin I Acute Tox. 4 * H302 Wng H302 Aquatic Acute 1 H400 H410 Aquatic Chronic 1 H410

2-methyl-4-oxo-3-(penta-2,4- 613-024-00-7 dienyl)cyclopent-2-enyl[1R- 204-462-6 121-29-9 Acute Tox. 4 * H332 GHS07 H332

[1α[S*(Z)](3β)]]-3-(3-methoxy-2- Acute Tox. 4 * H312 GHS09 H312 methyl-3-oxoprop-1-enyl)-2,2- Acute Tox. 4 * H302 Wng H302 dimethylcyclopropanecar- boxylate; Aquatic Acute 1 H400 H410 pyrethrin II Aquatic Chronic 1 H410

477

D050725/02

Classification Labelling Specific Conc. Limits, M-factors Notes

Index No International Chemical Identification EC No CAS No

Hazard Class and Category Hazard Pictogram, Signal Hazard Suppl. Hazard

Code(s) Statement statement Code(s) Word Code(s) statement Code(s) Code(s)

cinerin I; 3-(but-2-enyl)-2-methyl-4- oxocyclopent-2-enyl 2,2-dimethyl-3-

613-025-00-2 (2-methylprop-1- 246-948-0 25402-06-6 Acute Tox. 4 * H302 GHS07 H302 enyl)cyclopropanecarboxylate Aquatic Acute 1 H400 GHS09 H410 Aquatic Chronic 1 H410 Wng

cinerin II;3-(but-2-enyl)-2-methyl-4- 613-026-00-8 oxocyclopent-2-enyl 2,2-dimethyl-3- 204-454-2 121-20-0 Acute Tox. 4 * H302 GHS07 H302

(3-methoxy-2-methyl-3-oxoprop-1- Aquatic Acute 1 H400 GHS09 H410 enyl)cyclo-propanecarboxylate Aquatic Chronic 1 H410 Wng

piperidine

613-027-00-3 203-813-0 110-89-4 Flam. Liq. 2 H225 GHS02 H225 *

Acute Tox. 3 * H331 GHS06 H331 Acute Tox. 3 * H311 GHS05 H311 Skin Corr. 1B H314 Dgr H314

morpholine

613-028-00-9 203-815-1 110-91-8 Flam. Liq. 3 H226 GHS02 H226

Acute Tox. 4 * H332 GHS05 H332 Acute Tox. 4 * H312 GHS07 H312 Acute Tox. 4 * H302 Dg H302 Skin Corr. 1B H314 H314

dichloro-1,3,5-triazinetrione; dichloroisocyanuric acid

613-029-00-4 220-487-5 2782-57-2 Ox. Sol. 2 H272 GHS03 H272 EUH031 T

Acute Tox. 4 * Eye H302 GHS07 H302 Irrit. 2 H319 GHS09 H319 STOT SE 3 H335 Dgr H335 Aquatic Acute 1 H400 H410 Aquatic Chronic 1 H410

 troclosene potassium; [1] troclosene 613-030-00-X sodium [2] 218-828-8 [1] 2244-21-5 [1] Ox. Sol. 2 H272 GHS03 H272 EUH031 *

220-767-7 [2] 2893-78-9 [2] Acute Tox. 4 * Eye H302 GHS07 H302 STOT SE 3; G Irrit. 2 H319 GHS09 H319 H335: C ≥ 10 %

STOT SE 3 H335 Dgr H335 EUH031: C ≥10 % Aquatic Acute 1 H400 H410 Aquatic Chronic 1 H410

478

D050725/02

Classification Labelling Specific Conc. Limits, M-factors Notes

Index No International Chemical Identification EC No CAS No

Hazard Class and Category Hazard Suppl. Hazard

Code(s) Statement

Pictogram, Signal Hazard statement statement

Code(s) Word Code(s) Code(s) Code(s)

troclosene sodium, dihydrate 613-030-01-7 220-767-7 51580-86-0 Acute Tox. 4 * H302 GHS07 H302 EUH031

Eye Irrit. 2 H319 GHS09 H319 STOT SE 3 H335 Wng H335 Aquatic Acute 1 H400 H410 Aquatic Chronic 1 H410

symclosene; trichloroisocyanuric acid; trichloro-1,3,5-triazinetrion

613-031-00-5 201-782-8 87-90-1 Ox. Sol. 2 H272 GHS03 H272 EUH031

Acute Tox. 4 * H302 GHS07 H302 Eye Irrit. 2 H319 GHS09 H319 STOT SE 3 H335 Dgr H335 Aquatic Acute 1 H400 H410 Aquatic Chronic 1 H410

methyl-2,3,5,6-tetrachloro-4- pyridylsulphone;2,3,5,6-tetrachloro-4-

613-032-00-0 (methylsulphonyl)pyridine 236-035-5 13108-52-6 Acute Tox. 4 * H312 GHS07 H312

Acute Tox. 4 * H302 Wng H302 Eye Irrit. 2 H319 H319 Skin Sens. 1 H317 H317

2-methylaziridine;propyleneimine

613-033-00-6 200-878-7 75-55-8 Flam. Liq. 2 H225 GHS02 H225 Carc. 1B;

Carc. 1B H350 GHS06 H350 H350: C ≥ 0,01 % Acute Tox. 2 * H330 GHS08 H330 Acute Tox. 1 H310 GHS05 H310 Acute Tox. 2 * H300 GHS09 H300 Eye Dam. 1 H318 Dgr H318 Aquatic Chronic 2 H411 H411

1,2-dimethylimidazole

613-034-00-1 217-101-2 1739-84-0 Acute Tox. 4 * H302 GHS05 H302

Skin Irrit. 2 H315 GHS07 H315 Eye Dam. 1 H318 Dgr H318

1-methylimidazole

613-035-00-7 210-484-7 616-47-7 Acute Tox. 4 * H312 GHS05 H312

Acute Tox. 4 * H302 GHS07 H302 Skin Corr. 1B H314 Dgr H314

479

D050725/02

Classification Labelling Specific Conc. Limits, M-factors Notes

Index No International Chemical Identification EC No CAS No

Hazard Class and Category Hazard Pictogram, Signal Hazard Suppl. Hazard

Code(s) Statement Code(s) Word Code(s) statement statement Code(s) Code(s)

2-methylpyridine;2-picoline

613-036-00-2 203-643-7 109-06-8 Flam. Liq. 3 H226 GHS02 H226

Acute Tox. 4 * H332 GHS07 H332 Acute Tox. 4 * H312 Wng H312 Acute Tox. 4 * H302 H302 Eye Irrit. 2 H319 H319 STOT SE 3 H335 H335

4-methylpyridine;4-picoline

613-037-00-8 203-626-4 108-89-4 Flam. Liq. 3 H226 GHS02 H226

Acute Tox. 3 * H311 GHS06 H311 Acute Tox. 4 * H332 Dgr H332 Acute Tox. 4 * H302 H302 Eye Irrit. 2 H319 H319 STOT SE 3 H335 H335 Skin Irrit. 2 H315 H315

6-phenyl-1,3,5-triazine-2,4- diyldiamine;6-phenyl-1,3,5-triazine

613-038-00-3 2,4-diamine;benzoguanamine 202-095-6 91-76-9 Acute Tox. 4 * H302 GHS07 H302

Aquatic Chronic 3 H412 Wng H412

ethylene thiourea;imidazolidine-2- thione;2-imidazoline-2-thiol

613-039-00-9 202-506-9 96-45-7 Repr. 1B H360D *** GHS08 H360D ***

Acute Tox. 4 * H302 GHS07 H302 Dgr

azaconazole (ISO);1-{[2-(2,4- dichlorophenyl)-1,3- dioxolan-2-

613-040-00-4 yl]methyl}-1H-1,2.4- triazole 262-102-3 60207-31-0 Acute Tox. 4 * H302 GHS07 H302

Wng

morpholine-4-carbonyl chloride

613-041-00-X 239-213-0 15159-40-7 Carc. 2 H351 GHS08 H351 EUH014

Eye Irrit. 2 H319 Wng H319 Skin Irrit. 2 H315 H315

480

D050725/02

Classification Labelling Specific Conc. Limits, M-factors Notes

Index No International Chemical Identification EC No CAS No

Hazard Class and Category Hazard Pictogram, Signal Hazard Suppl. Hazard

Code(s) Statement statement Code(s) Word Code(s) statement Code(s) Code(s)

imazalil sulphate (ISO) powder;1-[2- (allyloxy)ethyl-2-(2,4-

613-043-00-0 dichlorophenyl)]-1H-imid- azolium 261-351-5 [1] 58594-72-2 [1] Acute Tox. 4 * H302 GHS07 H302 hydrogen sulphate; [1](±)-1-[2- 281-291-3 [2] 83918-57-4 [2] Skin Sens. 1 H317 GHS09 H317 (allyloxy)ethyl-2-(2,4- Aquatic Acute 1 H400 Wng H410 dichlorophenyl)]-1H-imid- azolium Aquatic Chronic 1 H410

hydrogen sulphate [2]

imazalil sulphate (ISO), aqueous solution;1-[2-(allyloxy)ethyl-2-(2,4-

613-043-01-8 dichlorophenyl)]-1H-imid-azolium 261-351-5 [1] 58594-72-2 [1] Acute Tox. 4 * Skin H302 GHS05 H302 Skin Corr. 1B; hydrogen sulphate; [1] (±)-1-[2- 281-291-3 [2] 83918-57-4 [2] Corr. 1B Skin Sens. 1 H314 GHS07 H314 H314: C ≥ 50 % (allyloxy)ethyl-2-(2,4- Aquatic Acute 1 H317 GHS09 H317 Skin Irrit. 2; H315: dichlorophenyl)]-1H-imid- azolium Aquatic Chronic 1 H400 Wng H410 30 % ≤ C < 50 % hydrogen sulphate [2] H410 Eye Dam. 1; H318: 15 % ≤ C < 50 % Eye Irrit. 2; H319: 5% ≤ C < 15 %

captan (ISO);1,2,3,6-tetrahydro-N- 613-044-00-6 (trichloro-methylthio)phthalimide 205-087-0 133-06-2 Carc. 2 H351 GHS06 H351

Acute Tox. 3 * H331 GHS05 H331 M=10 Eye Dam. 1 H318 GHS08 H318 Skin Sens. 1 H317 GHS09 H317 Aquatic Acute 1 H400 Dgr H400

folpet (ISO);N- (trichloromethyl-thio)phthalimide

613-045-00-1 205-088-6 133-07-3 Carc. 2 H351 GHS08 H351 M=10

Acute Tox. 4 * H332 GHS07 H332 Eye Irrit. 2 H319 GHS09 H319 Skin Sens. 1 H317 Wng H317 Aquatic Acute 1 H400 H400

captafol (ISO);1,2,3,6-tetrahydro-N- 613-046-00-7 (1,1,2,2- 219-363-3 2425-06-1 Carc. 1B Skin H350 GHS08 H350

tetrachloroethylthio)phthalimide Sens. 1 H317 GHS09 H317 Aquatic Acute 1 H400 Dgr H410 Aquatic Chronic 1 H410

1-dimethylcarbamoyl-5-methyl 613-047-00-2 pyrazol-3-yl dimethylcarbamate; 211-420-0 644-64-4 Acute Tox. 3 * H301 GHS06 H301

dimetilan (ISO) Acute Tox. 4 * H312 GHS09 H312 Aquatic Acute 1 H400 Dgr H410 Aquatic Chronic 1 H410

481

D050725/02

Classification Labelling Specific Conc. Limits, M-factors Notes

Index No International Chemical Identification EC No CAS No

Hazard Class and Category Hazard Pictogram, Signal Hazard Suppl. Hazard

Code(s) Statement statement Code(s) Word Code(s) statement Code(s) Code(s)

carbendazim (ISO);methyl 613-048-00-8 benzimidazol-2-ylcarbamate 234-232-0 10605-21-7 Muta. 1B Repr. H340 GHS08 H340

1B H360FD GHS09 H360FD Aquatic Acute 1 H400 Dgr H410 Aquatic Chronic 1 H410

benomyl (ISO);methyl 1- 613-049-00-3 (butylcarbamoyl)benzimidazol-2- 241-775-7 17804-35-2 Muta. 1B Repr. H340 GHS08 H340 M = 10

ylcarbamate 1B STOT SE 3 H360FD GHS07 H360FD Skin Irrit. 2 H335 GHS09 H335

Skin Sens. 1 H315 Dgr H315 Aquatic Acute 1 H317 H317 Aquatic Chronic 1 H400 H410 H410

carbadox (INN);methyl 3-(quinoxalin 613-050-00-9 2-ylmethylene)carbazate 1,4-dioxide;2- 229-879-0 6804-07-5 Flam. Sol. 1 H228 GHS02 H228 T

(methoxycarbonylhydrazono-methyl) Carc. 1B H350 GHS08 H350 quinoxaline 1,4-dioxide Acute Tox. 4 * H302 GHS07 H302 Dgr

molinate (ISO);S-ethyl 1- 613-051-00-4 perhydroazepinecarbothioate;S-ethyl 218-661-0 2212-67-1 Carc. 2 H351 GHS08 H351

perhydroazepine-1-carbothioate Repr. 2 H361f *** GHS07 H361f *** M = 100 Acute Tox. 4 * Acute H332 GHS09 H332

Tox. 4 * H302 Wng H302 STOT RE 2 * Skin H373 ** H373 ** Sens. 1 H317 H317 Aquatic Acute 1 H400 H410 Aquatic Chronic 1 H410

trifenmorph (ISO);4-tritylmorpholine

613-052-00-X 215-812-2 1420-06-0 Acute Tox. 4 * H302 GHS07 H302

Aquatic Acute 1 H400 GHS09 H410 Aquatic Chronic 1 H410 Wng

anilazine (ISO);2-chloro-N-(4,6- dichloro-1,3,5- triazin-2-yl)aniline

613-053-00-5 202-910-5 101-05-3 Eye Irrit. 2 H319 GHS07 H319

Skin Irrit. 2 H315 GHS09 H315 Aquatic Acute 1 H400 Wng H410 Aquatic Chronic 1 H410

482

D050725/02

Classification Labelling Specific Conc. Limits, M-factors Notes

Index No International Chemical Identification EC No CAS No

Hazard Class and Category Hazard Pictogram, Signal Hazard Suppl. Hazard

Code(s) Statement statement Code(s) Word Code(s) statement Code(s) Code(s)

thiabendazol (ISO);2-(thiazole-4- yl)benzimidazole

613-054-00-0 205-725-8 148-79-8 Aquatic Acute 1 H400 GHS09 H410

Aquatic Chronic 1 H410 Wng

1,2-dimethyl-3,5-diphenylpyra- zolium methylsulphate; difenzoquat methyl

613-056-00-1 sulfate 256-152-5 43222-48-6 Acute Tox. 4 * H302 GHS09 H302

Aquatic Acute 1 H400 Wng H410 Aquatic Chronic 1 H410

permethrin (ISO);m-phenoxybenzyl 3- 613-058-00-2 (2,2-dichorovinyl)-2,2- 258-067-9 52645-53-1 Acute Tox. 4 * H332 GHS07 H332 M = 1 000

dimethylcyclopro- panecarboxylate Acute Tox. 4 * H302 GHS09 H302 Skin Sens. 1 H317 Wng H317 Aquatic Acute 1 H400 H410 Aquatic Chronic 1 H410

profluralin (ISO);N- 613-059-00-8 (cyclopropylmethyl)-α,α,α- trifluoro 247-656-6 26399-36-0 Eye Irrit. 2 H319 GHS07 H319

2,6-dinitro-N-propyl-p-toluidine Aquatic Acute 1 H400 GHS09 H410 Aquatic Chronic 1 H410 Wng

resmethrin (ISO);5-benzyl-3- 613-060-00-3 furylmethyl (±)-cis-trans 233-940-7 10453-86-8 Acute Tox. 4 * H302 GHS07 H302 M=1000

chrysanthemate Aquatic Acute 1 H400 GHS09 H410 Aquatic Chronic 1 H410 Wng

6-(1α,5aβ,8aβ,9-pentahydroxy-7β- 613-061-00-9 isopropyl-2β,5β,8β- 239-732-2 15662-33-6 Acute Tox. 4 * H312 GHS07 H312

trimethyl-perhydro-8bα,9-epoxy-5,8- Acute Tox. 4 * H302 GHS09 H302 ethanocyclopenta[1,2-b]indenyl) Aquatic Acute 1 H400 Wng H410 pyrrole-2-carboxylate;ryania Aquatic Chronic 1 H410

sabadilla (ISO);veratrine 613-062-00-4 — 8051-02-3 Eye Irrit. 2 H319 GHS07 H319

STOT SE 3 H335 Wng H335 Skin Irrit. 2 H315 H315

secbumeton (ISO);2-sec-butylamino-4- 613-063-00-X ethylamino-6-methoxy-1,3,5-triazine 247-554-1 26259-45-0 Acute Tox. 4 * H302 GHS07 H302

Eye Irrit. 2 H319 GHS09 H319 Aquatic Acute 1 H400 Wng H410 Aquatic Chronic 1 H410

483

D050725/02

Classification Labelling Specific Conc. Limits, M-factors Notes

Index No International Chemical Identification EC No CAS No

Hazard Class and Category Hazard Pictogram, Signal Hazard Suppl. Hazard

Code(s) Statement statement statement Code(s) Word Code(s) Code(s) Code(s)

5-(3,6,9-trioxa-2-undecy 613-064-00-5 loxy)benzo(d)-1,3-dioxolane; sesamex — 51-14-9 Acute Tox. 4 * H302 GHS07 H302

Wng

simetryn (ISO);2,4-bis(ethylamino)-6- 613-065-00-0 methylthio-1,3,5-triazine 213-801-7 1014-70-6 Acute Tox. 4 * H302 GHS07 H302

Aquatic Acute 1 H400 GHS09 H410 Aquatic Chronic 1 H410 Wng

terbumeton (ISO);2-tert-butylamino-4- 613-066-00-6 ethylamino-6-methoxy-1,3,5-triazine 251-637-8 33693-04-8 Acute Tox. 4 * H302 GHS07 H302

Aquatic Acute 1 H400 GHS09 H410 Aquatic Chronic 1 H410 Wng

propazine (ISO);2-chloro-4,6- 613-067-00-1 bis(isopropy-lamino)-1,3,5-triazine 205-359-9 139-40-2 Carc. 2 H351 GHS08 H351

Aquatic Acute 1 H400 GHS09 H410 Aquatic Chronic 1 H410 Wng

atrazine (ISO);2-chloro-4-ethylamine 613-068-00-7 6- isopropylamine-1,3,5-triazine 217-617-8 1912-24-9 STOT RE 2 * H373 ** GHS08 H373 **

Skin Sens. 1 H317 GHS09 H317 Aquatic Acute 1 H400 Wng H410 Aquatic Chronic 1 H410

ε-caprolactam 613-069-00-2 203-313-2 105-60-2 Acute Tox. 4 * H332 GHS07 H332

Acute Tox. 4 * H302 Wng H302 Eye Irrit. 2 H319 H319 STOT SE 3 H335 H335 Skin Irrit. 2 H315 H315

propylenethiourea 613-070-00-8 — 2122-19-2 Repr. 2 H361d *** GHS08 H361d ***

Acute Tox. 4 * H302 GHS07 H302 Aquatic Chronic 3 H412 Wng H412

2-fluoro-5-trifluoromethyl-pyridine 613-071-00-3 400-290-2 69045-82-5 Flam. Liq. 3 H226 GHS02 H226

Skin Sens. 1 H317 GHS07 H317 Aquatic Chronic 3 H412 Wng H412

N,N-bis(2-ethylhexyl)-((1,2,4- triazol 613-072-00-9 1-yl)methyl)amine 401-280-0 91273-04-0 Skin Corr. 1B H314 GHS05 H314

Skin Sens. 1 H317 GHS07 H317 Aquatic Chronic 2 H411 GHS09 H411 Dgr

484

D050725/02

Classification Labelling Specific Conc. Limits, M-factors Notes

Index No International Chemical Identification EC No CAS No

Hazard Class and Category Hazard Pictogram, Signal Hazard Suppl. Hazard

Code(s) Statement statement Code(s) Word Code(s) statement Code(s) Code(s)

N,N-dimethyl-2-(3-(4-chloro- phenyl)- 4,5-dihydropyrazol-1-

613-073-00-4 ylphenylsulphonyl)ethylamine 401-410-6 10357-99-0 STOT RE 2 * H373 ** GHS08 H373 **

Skin Sens. 1 H317 GHS09 H317 Aquatic Chronic 2 H411 Wng H411

3-(3-methylpent-3-yl)isoxazol-5- ylamine

613-074-00-X 401-460-9 82560-06-3 Acute Tox. 3 * H331 GHS06 H331

Acute Tox. 3 * H301 GHS05 H301 Eye Dam. 1 H318 Dgr H318 Aquatic Chronic 3 H412 H412

1,3-dichloro-5-ethyl-5- methyl-imidazolidine-2,4-dione

613-075-00-5 401-570-7 89415-87-2 Ox. Sol. 1 **** H271 GHS03 H271

Acute Tox. 3 * H331 GHS06 H331 Skin Corr. 1B H314 GHS05 H314 Acute Tox. 4 * H302 GHS09 H302 Skin Sens. 1 H317 Dgr H317 Aquatic Acute 1 H400 H400

3-chloro-5-trifluoromethyl-2- pyridylamine

613-076-00-0 401-670-0 79456-26-1 Acute Tox. 4 * H302 GHS07 H302

Aquatic Chronic 3 H412 Wng H412

reaction mass of 5-heptyl-1,2,4-

613-077-00-6 triazol-3-ylamine and 5-nonyl-1,2,4- 401-940-8 Acute Tox. 4 * H302 GHS07 H302

triazol-3-ylamine — Eye Irrit. 2 H319 GHS09 H319 Aquatic Chronic 2 H411 Wng H411

N,N,N,N-tetrakis(4,6-bis(butyl- (N-

613-078-00-1 methyl-2,2,6,6-tetramethyl- piperidin 4-yl)amino)triazin-2- yl)-4,7- 401-990-0 106990-43-6 Skin Sens. 1 H317 GHS07 H317 diazadecane-1,10- diamine Aquatic Chronic 2 H411 GHS09 H411 Wng

4-(1(or 4 or 5 or 6)-methyl-8,9,10-

613-079-00-7 trinorborn-5-en-2- yl)pyridine, reaction mass of isomers 402-520-7 — Acute Tox. 4 * H312 GHS07 H312

Acute Tox. 4 * H302 GHS09 H302 Skin Irrit. 2 H315 Wng H315 Skin Sens. 1 H317 H317 Aquatic Acute 1 H400 H410

Aquatic Chronic 1 H410

485

D050725/02

Classification Labelling Specific Conc. Limits, M-factors Notes

Index No International Chemical Identification EC No CAS No

Hazard Class and Category Hazard Hazard Suppl. Hazard

Code(s) Statement

Pictogram, Signal statement statement

Code(s) Word Code(s) Code(s) Code(s)

3-(bis(2-ethylhexyl)amino

613-080-00-2 methyl)benzothiazole-2(3H)- thione 402-540-6 105254-85-1 Skin Corr. 1B Skin H314 GHS05 H314

Sens. 1 H317 GHS07 H317 Aquatic Acute 1 H400 GHS09 H410

Aquatic Chronic 1 H410 Dgr

1-butyl-2-methylpyridinium bromide

613-081-00-8 402-680-8 26576-84-1 Acute Tox. 4 * H302 GHS07 H302

Aquatic Chronic 3 H412 Wng H412

2-methyl-1-pentylpyridinium bromide

613-082-00-3 402-690-2 — Acute Tox. 4 * H312 GHS07 H312

Acute Tox. 4 * H302 Wng H302 Aquatic Chronic 3 H412 H412

2-(4-(3-(4-chlorophenyl)-2-pyra- zolin

613-083-00-9 1- yl)phenylsulfonyl)ethyldimethylammo 402-120-2 — Skin Corr. 1B STOT H314 GHS08 H314 nium formate RE 2 * Skin Sens. 1 H373 ** GHS05 H373 ** Aquatic Acute 1 H317 GHS07 H317

Aquatic Chronic 1 H400 GHS09 H410 H410 Dgr

2-(4-(3-(4-chlorophenyl)-4,5-

613-084-00-4 dihydropyrazolyl)phenylsulphonyl) ethyldimethylammonium hydrogen 402-490-5 106359-93-7 Eye Irrit. 2 H319 GHS07 H319

phosphonate Aquatic Acute 1 H400 GHS09 H410 Aquatic Chronic 1 H410 Wng

reaction mass of 1,1'-

613-085-00-X (methyl-enebis(4,1- phenylene))dipyrrole-2,5-dione and N- 401-970-1 — Skin Sens. 1 H317 GHS07 H317

(4-(4-(2,5-dioxopyrrol-1- Aquatic Acute 1 H400 GHS09 H410 yl)benzyl)phenyl)acetamide and 1-(4- Aquatic Chronic 1 H410 Wng

(4-(5- oxo-2H-2-furylidenamino)benzyl)phenyl)pyrrole-2,5- dione

caffeine

613-086-00-5 200-362-1 58-08-2 Acute Tox. 4 * H302 GHS07 H302

Wng

486

D050725/02

Classification Labelling Specific Conc. Limits, M-factors Notes

Index No International Chemical Identification EC No CAS No

Hazard Class and Category Hazard Suppl. Hazard

Code(s) Statement

Pictogram, Signal Hazard statement statement

Code(s) Word Code(s) Code(s) Code(s)

tetrahydrothiophene

613-087-00-0 203-728-9 110-01-0 Flam. Liq. 2 H225 GHS02 H225

Acute Tox. 4 * H332 GHS07 H332 Acute Tox. 4 * H312 Dgr H312 Acute Tox. 4 * H302 H302 Eye Irrit. 2 H319 H319 Skin Irrit. 2 H315 H315 Aquatic Chronic 3 H412 H412

1,2-benzisothiazol-3(2H)-one;1,2-

613-088-00-6 benzisothiazolin-3-one 220-120-9 2634-33-5 Acute Tox. 4 * H302 GHS05 H302 Skin Sens. 1;

Skin Irrit. 2 H315 GHS07 H315 H317: C≥0,05 % Eye Dam. 1 H318 GHS09 H318 Skin Sens. 1 H317 Dgr H317 Aquatic Acute 1 H400 H400

diquat dibromide; [1]diquat

613-089-00-1 dichloride; [2]6,7-dihydrodipyrido[1,2- α:2',1'- c]pyrazinediylium 201-579-4 [1] 85-00-7 [1] Acute Tox. 2 * H330 GHS06 H330 dihydroxide [3] 223-714-6 [2] 4032-26-2 [2] STOT RE 1 H372 ** GHS08 H372 ** 301-467-6 [3] 94021-76-8 [3] Acute Tox. 4 * H302 GHS09 H302

Eye Irrit. 2 H319 Dgr H319 STOT SE 3 H335 H335 Skin Irrit. 2 H315 H315 Skin Sens. 1 H317 H317 Aquatic Acute 1 H400 H410 Aquatic Chronic 1 H410

paraquat dichloride;1,1-dimethyl-4,4'-

613-090-00-7 bipyridinium dichloride; [1]paraquat GHS06 H330 dimethylsulfate;1,1-dimethyl-4,4'- 217-615-7 [1] 1910-42-5 [1] Acute Tox. 2 * Acute H330 H311 GHS08 H311

bipyridinium dimethyl sulphate [2] 218-196-3 [2] 2074-50-2 [2] Tox. 3 * Acute Tox. 3 * STOT RE 1 H301 GHS09 H301

Eye Irrit. 2 H372 ** Dgr H372 ** STOT SE 3 H319 H319 Skin Irrit. 2 H335 H335 Aquatic Acute 1 H315 H315

Aquatic Chronic 1 H400 H410 H410

487

D050725/02

Classification Labelling Specific Conc. Limits, M-factors Notes

Index No International Chemical Identification EC No CAS No

Hazard Class and Category Hazard Pictogram, Signal Hazard Suppl. Hazard

Code(s) Statement Code(s) Word Code(s) statement statement Code(s) Code(s)

morfamquat dichloride;

613-091-00-2 [1]morfamquat sulfate [2] 225-062-8 [1] [2] 4636-83-3 [1] Acute Tox. 4 * H302 GHS07 H302

29873-36-7 [2] Eye Irrit. 2 H319 Wng H319 STOT SE 3 H335 H335 Skin Irrit. 2 H315 H315 Aquatic Chronic 3 H412 H412

1,10-phenanthroline

613-092-00-8 200-629-2 66-71-7 Acute Tox. 3 * H301 GHS06 H301

Aquatic Acute 1 H400 GHS09 H410 Aquatic Chronic 1 H410 Dgr

hexasodium 6,13-dichloro-3,10-

613-093-00-3 bis((4-(2,5-disulfonatoanilino)-6- fluoro-1,3,5-triazin-2- ylamino)prop-3- 400-050-7 85153-92-0 Resp. Sens. 1 H334 GHS08 H334

ylamino)-5,12- dioxa-7,14- Skin Sens. 1 H317 Dgr H317

diazapentacene-4,11- disulfonate

4-methoxy-N,6-dimethyl-1,3,5- triazin

613-094-00-9 2-ylamine 401-360-5 5248-39-5 Acute Tox. 4 * STOT RE H302 GHS08 H302

2 * H373 ** GHS07 H373 ** Wng

sodium 3-(2H-benzotriazol-2- yl)-5-

613-095-00-4 sec-butyl-4-hydroxybenzenesulfonate 403-080-9 92484-48-5 Eye Dam. 1 H318 GHS05 H318

Dgr

2-amino-6-ethoxy-4-methyl-amino

613-096-00-X 1,3,5-triazine 403-580-7 62096-63-3 Acute Tox. 4 * H302 GHS07 H302

Wng

7-amino-3-((5-carboxymethyl-4-

613-097-00-5 methyl-1,3-thiazol-2- ylthio)methyl)-8- oxo-5-thia-1- azabicyclo(4.2.0)oct-2- 403-690-5 111298-82-9 Resp. Sens. 1 H334 GHS08 H334 ene-2- carboxylic acid Skin Sens. 1 H317 Dgr H317 Aquatic Chronic 3 H412 H412

488

D050725/02

Classification Labelling Specific Conc. Limits, M-factors Notes

Index No International Chemical Identification EC No CAS No

Hazard Class and Category Hazard Pictogram, Signal Hazard Suppl. Hazard

Code(s) Statement Code(s) Word Code(s) statement statement Code(s) Code(s)

N-(n-octyl)-2-pyrrolidone

613-098-00-0 403-700-8 2687-94-7 Skin Corr. 1B Aquatic H314 GHS05 H314

Chronic 2 H411 GHS09 H411 Dgr

1-dodecyl-2-pyrrolidone

613-099-00-6 403-730-1 2687-96-9 Skin Corr. 1B Skin H314 GHS05 H314

Sens. 1 H317 GHS07 H317 Aquatic Acute 1 H400 GHS09 H410 Aquatic Chronic 1 H410 Dgr

2,9-bis(3-

613-100-00-X (diethylamino)pro-pylsulfamoyl)quino( 2,3-b)acridine-7,14-dione 404-230-6 — Skin Sens. 1 H317 GHS07 H317

Aquatic Chronic 4 H413 Wng H413

N—tert-pentyl-2-

613-101-00-5 benzothiazole-sulfenamide 404-380-2 110799-28-5 Skin Sens. 1 H317 GHS07 H317

Aquatic Chronic 3 H412 Wng H412

dimethomorph (ISO);4-(3-(4-

613-102-00-0 chlorophenyl)-3-(3,4- dimethoxyphenyl)acryloyl)morpholine 404-200-2 110488-70-5 Aquatic Chronic 2 H411 GHS09 H411

sodium 5-n-butylbenzotriazole

613-103-00-6 404-450-2 118685-34-0 Acute Tox. 4 * Skin H302 GHS05 H302

Corr. 1B Skin Sens. 1 H314 GHS07 H314 Aquatic Chronic 2 H317 GHS09 H317

H411 Dgr H411

5-tert-butyl-3-isoxazolylamine

613-104-00-1 hydrochloride 404-840-2 — Acute Tox. 4 * H302 GHS08 H302

STOT RE 2 * Eye H373 ** GHS05 H373 ** Dam. 1 H318 GHS07 H318 Aquatic Chronic 3 H412 Dgr H412

489

D050725/02

Classification Labelling Specific Conc. Limits, M-factors Notes

Index No International Chemical Identification EC No CAS No

Hazard Class and Category Hazard Hazard Suppl. Hazard

Code(s) Statement

Pictogram, Signal statement

Code(s) Word Code(s)

statement Code(s) Code(s)

hexakis(tetramethylammonium) 4,4'-

613-105-00-7 vinylenebis((3-sulfonato-4,1- 405-160-9 124537-30-0

phenylene)imino(6- morpholino-1,3,5- Acute Tox. 3 * Skin

H301 GHS06 H301

triazine-4,2- diyl)imino)bis(5-hydroxy Sens. 1 H317

Dgr H317

6-phenylazonaphthalene-2,7- Aquatic Chronic 3 H412 H412

disulfonate)

tetrapotassium 2-(4-(5-(1-(2,5-

613-106-00-2 disulfonatophenyl)-3-ethoxycar 405-240-3 — Skin Sens. 1 H317 GHS07 H317 bonyl-5-hydroxypyrazol-4- yl)penta Wng

2,4-dienylidene)-3- ethoxycarbonyl-5- oxo-2-pyra- zolin-1-yl)benzene-1,4- disulfonate

hexasodium 2,2'-vinylenebis((3-

613-107-00-8 sulfonato-4,1-pheny- lene)imino(6-(N- cyanoethyl-N-(2- 405-280-1 76508-02-6 Eye Irrit. 2 H319 GHS07 H319

hydroxypropyl)amino)-1,3,5-triazine Wng

4,2-diyl)imino)di-benzene-1,4- disulfonate

benzothiazole-2-thiol

613-108-00-3 205-736-8 149-30-4 Skin Sens. 1 H317 GHS07 H317

Aquatic Acute 1 H400 GHS09 H410

Aquatic Chronic 1 H410 Wng

bis(piperidinothiocarbonyl) disulphide

613-109-00-9 202-328-1 94-37-1 Eye Irrit. 2 H319 GHS07 H319

STOT SE 3 H335 Wng H335

Skin Irrit. 2 H315 H315

Skin Sens. 1 H317 H317

dimepiperate (ISO);S-(1-methyl-1- phenylethyl) piperidine-1-carbothioate

613-110-00-4 262-784-2 61432-55-1 Acute Tox. 4 * H302 GHS07 H302

Aquatic Chronic 2 H411 GHS09 H411

Wng

490

D050725/02

Classification Labelling Specific Conc. Limits, M-factors Notes

Index No International Chemical Identification EC No CAS No

Hazard Class and Category Hazard Hazard Suppl. Hazard

Code(s) Statement

Pictogram, Signal

Code(s) Word Code(s)

statement statement Code(s) Code(s)

1,2,4-triazole

613-111-00-X 206-022-9 288-88-0 Repr. 2 H361d *** GHS08 H361d ***

Acute Tox. 4 * H302 GHS07 H302

Eye Irrit. 2 H319 Wng H319

octhilinone (ISO);2-octyl-2H-

613-112-00-5 isothiazol-3-one 247-761-7 26530-20-1 Acute Tox. 3 * H331 GHS06 H331 Skin Sens. 1; H317: Acute Tox. 3 * H311

GHS05 H311 C≥0,05 % Acute Tox. 4 * H302

Skin Corr. 1B GHS09 H302 H314 Skin Sens. 1 H317 Dgr H314 Aquatic Acute 1 H317 H400 Aquatic Chronic 1 H410 H410

2-(morpholinothio)benzothiazole

613-113-00-0 203-052-4 102-77-2 Eye Irrit. 2 H319 GHS07 H319

Skin Irrit. 2 H315 GHS09 H315

Skin Sens. 1 H317 Wng H317

Aquatic Chronic 2 H411 H411

2,2',2''-(hexahydro-1,3,5- triazine 613-114-00-6 1,3,5-triyl)triethanol;1,3,5-tris(2- 225-208-0 4719-04-4 Acute Tox. 4 * H302 GHS07 H302 Skin Sens. 1;

hydroxyethyl)hexahydro-1,3,5-triazine Skin Sens. 1 H317 Wng H317 H317: C ≥

0,1 %

hymexazol (ISO);3-hydroxy-5- 613-115-00-1 methylisoxazole 233-000-6 10004-44-1 Acute Tox. 4 * H302 GHS05 H302

Eye Dam. 1 H318 GHS07 H318 Aquatic Chronic 3 H412 Dgr H412

tolylfluanid (ISO);dichloro-N- 613-116-00-7 [(dimethylamino)sulphonyl]fluoro-N- 211-986-9 731-27-1 Acute Tox. 2 * H330 GHS06 H330 M=10

(p- STOT RE 1 H372** GHS08 H372** tolyl)methanesulphenamide;[containin Eye Irrit. 2 H319 GHS09 H319 g ≥0.1% (w/w) of particles with an STOT SE 3 H335 Dgr H335 aerodynamic diameter of below 50 Skin Irrit. 2 H315 H315 μm] Skin Sens. 1 H317 H317

Aquatic Acute 1 H400 H400 tolylfluanid (ISO);dichloro-N-

613-116-01-4 [(dimethylamino)sulphonyl]fluoro-N- 211-986-9 731-27-1 Eye Irrit. 2 H319 GHS07 H319 M=10

(p- STOT SE 3 H335 GHS09 H335 tolyl)methanesulphenamide;[containin Skin Irrit. 2 H315 Wng H315 g < 0,1% (w/w) of particles with an Skin Sens. 1 H317 H317 aerodynamic diameter of below 50 Aquatic Acute 1 H400 H400 μm]

491

D050725/02

Classification Labelling Specific Conc. Limits, M-factors Notes

Index No International Chemical Identification EC No CAS No

Hazard Class and Category Hazard Hazard Suppl. Hazard

Code(s) Statement

Pictogram, Signal

Code(s) Word Code(s)

statement statement Code(s) Code(s)

diniconazole (ISO);(E)-β-[(2,4- 613-117-00-2 dichlorophenyl)methylene]-α-(1,1- 76714-88-0 Acute Tox. 4 * H302 GHS07 H302

dimethyl-ethyl)-1H—1,2,4-triazol-1- — Aquatic Acute 1 H400 GHS09 H410 ethanol;(E)-(RS)-1-(2,4- Aquatic Chronic 1 H410 Wng dichlorophenyl)-4,4-dimethyl-2-(1H— 1,2,4- triazol-1-yl)pent-1-en-3-ol

flubenzimine (ISO);N-[3-phenyl-4,5- 613-118-00-8 bis[(trifluoromethyl)imino]thiazolidin 253-703-1 37893-02-0 Eye Irrit. 2 H319 GHS07 H319

2- ylidene]aniline Aquatic Acute 1 H400 GHS09 H410 Aquatic Chronic 1 H410 Wng

(benzothiazol-2-ylthio)methyl 613-119-00-3 thiocyanate;TCMTB 244-445-0 21564-17-0 Acute Tox. 2 * Acute H330 GHS06 H330

Tox. 4 * Eye Irrit. 2 H302 GHS09 H302 Skin Irrit. 2 H319 Dgr H319 Skin Sens. 1 H315 H315 Aquatic Acute 1 H317 H317 Aquatic Chronic 1 H400 H410

H410

bioresmethrin (ISO);(5-benzyl-3-

613-120-00-9 furyl)methyl (1R)-2,2-dimethyl-3-(2- 249-014-0 28434-01-7 Aquatic Acute 1 H400 GHS09 H410 M = 1000 methylprop-1- en-1- Aquatic Chronic 1 H410 Wng

yl)cyclopropanecarboxylate

diclobutrazole (ISO);(R*, R*)-(±)-β- 613-122-00-X [(2,4-dichlorop- henyl)methyl]-α-(1,1- — 75736-33-3 Eye Irrit. 2 H319 GHS07 H319

dimethyl-ethyl)-1H-1,2,4-triazole-1- Aquatic Chronic 2 H411 GHS09 H411 ethanol; (2RS, 3RS)-1-(2,4- Wng dichlorop-henyl)-4,4-dimethyl-2- (1H—1,2,4-triazol-1yl)pentan-3-ol

5,6-dihydro-3H-imidazo[2,1-c]-1,2,4-

613-123-00-5 dithiazole-3-thione;etem 251-684-4 33813-20-6 Acute Tox. 4 * H302 GHS07 H302

Aquatic Acute 1 H400 GHS09 H410 Aquatic Chronic 1 H410 Wng

492

D050725/02

Classification Labelling Specific Conc. Limits, M-factors Notes

Index No International Chemical Identification EC No CAS No

Hazard Class and Category Hazard Hazard Suppl. Hazard

Code(s) Statement

Pictogram, Signal statement statement

Code(s) Word Code(s) Code(s) Code(s)

fenpropimorph (ISO);cis-4-[3-(p-tert-

613-124-00-0 butylphenyl)-2- methylpropyl]-2,6- 266-719-9 67564-91-4 Repr. 2 H361d *** GHS08 H361d *** dimethylmorpholine Acute Tox. 4 * H302 GHS07 H302

Skin Irrit. 2 H315 GHS09 H315 Aquatic Chronic 2 H411 Wng H411

hexythiazox(ISO);trans-5-(4- 613-125-00-6 chlorophenyl)-N- cyclohexyl-4-methyl— 78587-05-0 Aquatic Acute 1 H400 GHS09 H410

2-oxo-3-thiazolidine-carboxamide Aquatic Chronic 1 H410 Wng

imazapyr (ISO);2-[4,5-dihydro-4-

613-126-00-1 methyl-4-(1- methylethyl)-5-oxo-1H- — 81334-34-1 Eye Irrit. 2 H319 GHS07 H319 imidazol-2-yl]-3-pyridine carboxylate Aquatic Chronic 3 H412 Wng H412

1,1-dimethylpiperidinium

613-127-00-7 chloride;mepiquat chloride 246-147-6 24307-26-4 Acute Tox. 4 * H302 GHS07 H302

Aquatic Chronic 3 H412 Wng H412

prochloraz (ISO);N-propyl-N-[2-

613-128-00-2 (2,4,6-trichlorop- henoxy)ethyl]-1H- 266-994-5 67747-09-5 Acute Tox. 4 * H302 GHS07 H302 imidazole-1- carboxamide Aquatic Acute 1 H400 GHS09 H410

Aquatic Chronic 1 H410 Wng

metamitron (ISO);4-amino-3-methyl 613-129-00-8 6-phenyl-1,2,4-triazin-5-one 255-349-3 41394-05-2 Acute Tox. 4 * H302 GHS07 H302

Aquatic Acute 1 H400 GHS09 H400 Wng

pyroquilon (ISO);1,2,5,6-

613-131-00-9 tetrahydropyrrolo[3,2,1- ij]quinolin-4- — 57369-32-1 Acute Tox. 4 * H302 GHS07 H302 one Aquatic Chronic 3 H412 Wng H412

hexazinone (ISO);3-cyclohexyl-6-

613-132-00-4 dimethylamino-1-methyl-1,2,3,4- tetrahydro-1,3,5-triazine-2,4-dione 257-074-4 51235-04-2 Acute Tox. 4 * Eye Irrit. 2 H302 GHS07 H302

Aquatic Acute 1 H319 GHS09 H319

Aquatic Chronic 1 H400 Wng H410 H410

493

D050725/02

Classification Labelling Specific Conc. Limits, M-factors Notes

Index No International Chemical Identification EC No CAS No

Hazard Class and Category Hazard Suppl. Hazard

Code(s) Statement

Pictogram, Signal Hazard statement statement

Code(s) Word Code(s) Code(s) Code(s)

myclobutanil(ISO);2-(4-chlorophenyl)-

613-134-00-5 2-(1H-1,2,4- triazol-1- ylmethyl)hexanenitrile — 88671-89-0 Repr. 2 H361d *** GHS08 H361d ***

Acute Tox. 4 * H302 GHS07 H302 Eye Irrit. 2 H319 GHS09 H319 Aquatic Chronic 2 H411 Wng H411

di(benzothiazol-2-yl) disulphide

613-135-00-0 204-424-9 120-78-5 Skin Sens. 1 H317 GHS07 H317 EUH031

Aquatic Acute 1 H400 GHS09 H410 Aquatic Chronic 1 H410 Wng

N-cyclohexylbenzothiazole-2-

613-136-00-6 sulphenamide 202-411-2 95-33-0 Skin Sens. 1 H317 GHS07 H317

Aquatic Acute 1 H400 GHS09 H410 Aquatic Chronic 1 H410 Wng

methabenzthiazuron (ISO);1-(1,3- 613-137-00-1 benzothiazol-2-yl)1,3- dimethylurea 242-505-0 18691-97-9 Aquatic Acute 1 H400 GHS09 H410

Aquatic Chronic 1 H410 Wng

quinoxyfen (ISO);5,7-dichloro-4-(4- fluorophenoxy)quinoline

613-138-00-7 — 124495-18-7 Skin Sens. 1 H317 GHS07 H317

Aquatic Acute 1 H400 GHS09 H410 Aquatic Chronic 1 H410 Wng

metsulfuron-methyl (ISO); methyl-2- {[(4-methoxy-6- methyl-1,3,5-triazin

613-139-00-2 2-yl)carbamoyl]sulfamoyl}benzoate — 74223-64-6 Aquatic Acute 1 H400 GHS09 H410 M = 1000

Aquatic Chronic 1 H410 Wng

cycloheximide (ISO);4-{(2R)-2-

613-140-00-8 [(1S,3S,5S)-3,5- dimethyl-2- 200-636-0 66-81-9 Muta. 2 H341 GHS06 H341 oxocyclohexyl]-2- Repr. 1B H360D *** GHS08 H360D *** hydroxyethyl}piperidine-2,6- dione Acute Tox. 2 * H300 GHS09 H300

Aquatic Chronic 2 H411 Dgr H411

1,4-diamino-2-(2-butyltetrazol-5-yl)-3- cyanoanthraquinone

613-141-00-3 401-470-3 93686-63-6 Aquatic Chronic 4 H413 — H413

494

D050725/02

Classification Labelling Specific Conc. Limits, M-factors Notes

Index No International Chemical Identification EC No CAS No

Hazard Class and Category Hazard Hazard Suppl. Hazard

Code(s) Statement

Pictogram, Signal statement

Code(s) Word Code(s)

statement Code(s) Code(s)

trans—N-methyl-2-styryl-[4'- aminomethine-(1-acetyl-1-(2-

613-142-00-9 methoxyphenyl)acetamido)]pyridinium acetate 405-860-4 — Skin Sens. 1 H317 GHS07 H317

Aquatic Chronic 2 H411 GHS09 H411

Wng

1-(3-phenylpropyl)-2- methyl-pyridinium bromide

613-143-00-4 405-930-4 10551-42-5 Acute Tox. 4 * H302 GHS07 H302

Eye Irrit. 2 H319 Wng H319

Aquatic Chronic 3 H412 H412

reaction products of: poly(vinyl

613-144-00-X acetate), partially hydrolyzed, with (E)- 2-(4-formylstyryl)-3,4- 406-460-2 125139-08-4 Aquatic Chronic 3 H412 — H412

dimethylthiazoliummethylsulfate

(S)-3-benzyloxycarbonyl-1,2,3,4-

613-145-00-5 tetrahydro-isoquino-linium 4- methylbenzenesulfonate 406-960-0 77497-97-3 Aquatic Chronic 2 H411 GHS09 H411

N-ethyl-N-methylpiperidinium iodide

613-146-00-0 407-780-5 4186-71-4 Acute Tox. 4 * H302 GHS07 H302

Aquatic Chronic 2 H411 GHS09 H411

Wng

4-[2-(1-methyl-2-(4-

613-147-00-6 morpholinyl)ethoxy)ethyl]morpholine 407-940-4 111681-72-2 Eye Dam. 1 H318 GHS05 H318

Dgr

tetrasodium 1,2-bis(4-fluoro-6- [5-(1-

613-148-00-1 amino-2-sulfonatoanthra- chinon-4- ylamino)-2,4,6- trimethyl-3- 411-240-4 143683-23-2 Skin Sens. 1 H317 GHS07 H317

sulfonatopheny- lamino]-1,3,5-triazin Aquatic Chronic 3 H412 Wng H412

2- ylamino)ethane

495

D050725/02

Classification Labelling Specific Conc. Limits, M-factors Notes

Index No International Chemical Identification EC No CAS No

Hazard Class and Category Hazard Pictogram, Signal Hazard Suppl. Hazard

Code(s) Statement statement statement Code(s) Word Code(s) Code(s) Code(s)

2,2'-[3,3'-(piperazine-1,4-diyl)di

613-150-00-2 propyl]bis(1H-benzimidazo[2,1— b]benzo[l,m,n][3,8]ph-enanthroline 406-295-6 — Aquatic Chronic 4 H413 — H413

1,3,6-trione

1-(3-mesyloxy-5-trityloxy-methyl-2-D- threofuryl)thymine

613-151-00-8 406-360-9 104218-44-2 Aquatic Chronic 4 H413 — H413

phenyl N-(4,6-dimethoxypyrimidin-2- yl)carbamate

613-152-00-3 406-600-2 89392-03-0 Skin Sens. 1 H317 GHS07 H317

Aquatic Chronic 2 H411 GHS09 H411

Wng 2,3,5-trichloropyridine

613-153-00-9 407-270-2 16063-70-0 Aquatic Chronic 3 H412 — H412

2-amino-4-chloro-6- methoxy-pyrimidine

613-154-00-4 410-050-9 5734-64-5 Acute Tox. 4 * H302 GHS07 H302

Wng

5-chloro-2,3-difluoropyridine

613-155-00-X 410-090-7 89402-43-7 Flam. Liq. 3 H226 GHS02 H226

Acute Tox. 4 * H302 GHS07 H302 Aquatic Chronic 3 H412 Wng H412

2-butyl-4-chloro-5-formylimidazole

613-156-00-5 410-260-0 83857-96-9 Skin Sens. 1 H317 GHS07 H317

Aquatic Chronic 2 H411 GHS09 H411

Wng

2,4-diamino-5-

613-157-00-0 methoxymethyl-pyrimidine 410-330-0 54236-98-5 Acute Tox. 4 * H302 GHS08 H302

STOT RE 2 * H373 ** GHS07 H373 ** Eye Irrit. 2 H319 Wng H319

496

D050725/02

Classification Labelling Specific Conc. Limits, M-factors Notes

Index No International Chemical Identification EC No CAS No

Hazard Class and Category Hazard Suppl. Hazard

Code(s) Statement

Pictogram, Signal Hazard statement statement

Code(s) Word Code(s) Code(s) Code(s)

2,3-dichloro-5-trifluoromethyl

613-158-00-6 pyridine 410-340-5 69045-84-7 Acute Tox. 4 * H332 GHS05 H332

Acute Tox. 4 * H302 GHS07 H302 Eye Dam. 1 H318 GHS09 H318

Skin Sens. 1 H317 Dgr H317

Aquatic Chronic 2 H411 H411

613-159-00-1 fenazaquin (ISO);4-[2-[4-(1,1- dimethyl-ethyl)phenyl]- 410-580-0 120928-09-8 Acute Tox. 3 * H301 GHS06 H301 ethoxy]quinazoline Acute Tox. 4 * H332 GHS09 H332 Aquatic Acute 1 H400 Dgr H410

Aquatic Chronic 1 H410

613-160-00-7 (1S)-2-methyl-2,5- diazobicyclo[2.2.1]heptanes 411-000-9 125224-62-6 Skin Sens. 1 H317 GHS07 H317

dihydrobromide Wng

(2,4-diaminopteridin-6-yl)methanol

613-161-00-2 hydrobromide 430-620-0 76145-91-0 STOT RE 2 * H373** GHS08 H373**

Skin Sens. 1 H317 GHS07 H317 Aquatic Chronic 3 H412 Wng H412

(6R-trans)-1-((7-ammonio-2-

613-162-00-8 carboxylato-8-oxo-5-thia-1- azabicyclo-[4.2.0]oct-2-en-3- 423-260-0 100988-63-4 Muta. 2 H341 GHS08 H341

yl)methyl)pyridinium iodide Skin Sens. 1 H317 GHS07 H317 Aquatic Chronic 2 H411 GHS09 H411

Wng

azimsulfuron (ISO);1-(4,6-

613-163-00-3 dimethoxypyrimidin-2-yl)-3-[1- — 120162-55-2 Aquatic Acute 1 H400 GHS09 H410 M=1000 methyl-4-(2-methyl-2H- tetrazol-5- Aquatic Chronic 1 H410 Wng

yl)pyrazol-5-ylsulfonyl]urea

613-164-00-9 flufenacet (ISO);N-(4-fluorophenyl)-N- isopropyl-2-(5-trifluoromethyl— 142459-58-3 Acute Tox. 4 * H302 GHS08 H302 M=100

[1,3,4]thiadiazol-2-yloxy)acetamide STOT RE 2 * H373** GHS07 H373** Skin Sens. 1 H317 GHS09 H317

Aquatic Acute 1 H400 Wng H410 Aquatic Chronic 1 H410

497

D050725/02

Classification Labelling Specific Conc. Limits, M-factors Notes

Index No International Chemical Identification EC No CAS No

Hazard Class and Category Hazard Pictogram, Signal Hazard Suppl. Hazard

Code(s) Statement statement Code(s) Word Code(s) statement Code(s) Code(s)

613-165-00-4 flupyrsulfuron-methylsodium(ISO);methyl 2-[[(4,6- — 144740-54-5 Aquatic Acute 1 H400 GHS09 H410 M=100

dimethoxypyrimidin-2- Aquatic Chronic 1 H410 Wng

ylcarbamoyl)sulfamoyl]-6- trifluoromethyl]nicotinate, monosodium salt

613-167-00-5 reaction mass of: 5-chloro-2- methyl-4- isothiazolin-3-one [EC no. 247-500- 55965-84-9

7]and 2-methyl-2H -isothiazol-3- one — Acute Tox. 3 * GHS06 H331 Skin Corr. 1B;

[EC no. 220-239-6] (3:1); reaction Acute Tox. 3 *

H331

mass of: 5-chloro-2- methyl-4- Acute Tox. 3 * H311 GHS05 H311

H314: C ≥0,6%

isothiazolin-3-one [EC no. 247-500- Skin Corr. 1B H301 GHS09 H301

Skin Irrit. 2; H315: 0,06% ≤ C < 0,6%

7]and 2-methyl-4-isothiazolin-3- one H314 Dgr H314

[EC no. 220-239-6] (3:1) Skin Sens. 1 Aquatic Acute 1 H317 H317 Eye Irrit. 2; H319: 0,06% ≤ C < 0,6%

Aquatic Chronic 1 H400 H410 H410 Skin Sens. 1; H317:

C ≥ 0,0015 %

1-vinyl-2-pyrrolidone 613-168-00-0 201-800-4 88-12-0 Carc. 2 H351 GHS06 H351

Acute Tox. 4 * H332 GHS05 H332

Acute Tox. 4 * H312 GHS09 H312 D

Acute Tox. 4 * H302 Dgr H302

STOT RE 2 * H373 ** H373 ** STOT SE 3 H335 H335 Eye Dam. 1 H318 H318

9-vinylcarbazole

613-169-00-6 216-055-0 1484-13-5 Muta. 2 H341 GHS08 H341 M=100

Acute Tox. 4 * H312 GHS07 H312 Acute Tox. 4 * H302 GHS09 H302

Skin Irrit. 2 H315 Wng H315

Skin Sens. 1 H317 H317

Aquatic Acute 1 H400 H410

Aquatic Chronic 1 H410

2,2-ethylmethylthiazolidine

613-170-00-1 404-500-3 694-64-4 Acute Tox. 4 * H302 GHS05 H302

Eye Dam. 1 H318 GHS07 H318

Skin Sens. 1

Aquatic Chronic 2 H317 GHS09 H317 H411 Dgr H411

498

D050725/02

Classification Labelling Specific Conc. Limits, M-factors Notes

Index No International Chemical Identification EC No CAS No

Hazard Class and Category Hazard Suppl. Hazard

Code(s) Statement

Pictogram, Signal Hazard statement statement

Code(s) Word Code(s) Code(s) Code(s)

hexaconazole (ISO);(RS)-2-(2,4- dichlorophenyl)-1-(1H-1,2,4-triazol-1-

613-171-00-7 yl)hexan-2- ol 413-050-7 79983-71-4 Acute Tox. 4 * H302 GHS07 H302

Skin Sens. 1 H317 GHS09 H317 Aquatic Chronic 2 H411 Wng H411

5-chloro-1,3-dihydro-2H-indol-2-one

613-172-00-2 412-200-9 17630-75-0 Repr. 2 H361f *** GHS08 H361f ***

Acute Tox. 4 * H302 GHS07 H302

Skin Sens. 1 H317 Wng H317 Aquatic Chronic 3 H412 H412

fluquinconazole (ISO);3-(2,4-

613-173-00-8 dichlorophenyl)-6-fluoro-2-(1H-1,2,4- 411-960-9 136426-54-5

triazol-1-yl)quinazolin-4-(3H)-one Acute Tox. 3 * H331 GHS06 H331 Acute Tox. 3 * H301 GHS08 H301

STOT RE 1 H372 ** GHS09 H372 **

Acute Tox. 4 * H312 Dgr H312

Skin Irrit. 2 H315 H315

Aquatic Acute 1 H400 H410

Aquatic Chronic 1 H410

613-174-00-3 tetraconazole (ISO); 407-760-6 112281-77-3 Acute Tox. 4 * H332 GHS07 H332

(±) 2-(2,4-dichlorophenyl)-3-(1H- Acute Tox. 4 * H302 GHS09 H302 1,2,4-triazol-1-yl)propyl-1,1,2,2- Aquatic Chronic 2 H411 Wng H411 tetrafluoroethylether

613-175-00-9 epoxiconazole (ISO); (2RS,3SR)-3-(2- 406-850-2 133855-98-8 Carc. 2 H351 GHS08 H351 chlorophenyl)-2-(4-fluorophenyl)- Repr. 1B H360Df GHS09 H360Df [(1H-1,2,4-triazol-1-yl)methyl]oxirane Aquatic Chronic 2 H411 Dgr H411

613-176-00-4 2-methyl-2-azabicyclo[2.2.1]heptane 404-810-9 4524-95-2 Flam. Liq. 3 H226 GHS02 H226

Acute Tox. 4 * H312 GHS08 H312 Acute Tox. 4 * H302 GHS05 H302 STOT RE 2 * H373 ** GHS07 H373 ** Skin Corr. 1B H314 Dgr H314

499

D050725/02

Classification Labelling Specific Conc. Limits, M-factors Notes

Index No International Chemical Identification EC No CAS No

Hazard Class and Category Hazard Hazard Suppl. Hazard

Code(s) Statement

Pictogram, Signal

Code(s) Word Code(s)

statement statement Code(s) Code(s)

613-177-00-X 8-amino-7-methylquinoline 412-760-4 5470-82-6 Acute Tox. 4 * H312 GHS07 H312

Acute Tox. 4 * H302 GHS09 H302 Skin Sens. 1 H317 Wng H317 Aquatic Chronic 2 H411 H411

613-178-00-5 4-ethyl-2-methyl-2-isopentyl-1,3- 410-470-2 137796-06-6 Skin Corr. 1B H314 GHS05 H314 STOT SE 3; H335: oxazolidine Skin Sens. 1 H317 GHS07 H317 C ≥ 5%

Dgr

613-179-00-0 lithium 3-oxo-1,2(2H)-benzisothiazol 411-690-1 111337-53-2 Acute Tox. 4 * H302 GHS05 H302

2-ide Skin Corr. 1B H314 GHS07 H314 Skin Sens. 1 H317 Dgr H317 Aquatic Chronic 2 H411 H411

613-180-00-6 N-(1,1-dimethylethyl)bis(2- 407-430-1 3741-80-8 Aquatic Acute 1 H400 GHS09 H410 benzothiazolesulfen)amide Aquatic Chronic 1 H410 Wng

613-181-00-1 5,5-dimethyl-perhydro-pyrimidin-2- 405-090-9 67485-29-4 STOT RE 1 H372 ** GHS08 H372 ** one α-(4-trifluoromethylstyryl)-α-(4- Acute Tox. 4 * H302 GHS07 H302

trifluoromethyl)cinnamylidenehydrazo Eye Irrit. 2 H319 GHS09 H319 ne Aquatic Acute 1 H400 Dgr H410

Aquatic Chronic 1 H410

613-182-00-7 1-(1-naphthylmethyl)quinolinium 406-220-7 65322-65-8 Carc. 2 H351 GHS08 H351 chloride Muta. 2 H341 GHS05 H341 Acute Tox. 4 * H302 GHS07 H302 Skin Irrit. 2 H315 Dgr H315 Eye Dam. 1 H318 H318 Aquatic Chronic 3 H412 H412

500

D050725/02

Classification Labelling Specific Conc. Limits, M-factors Notes

Index No International Chemical Identification EC No CAS No

Hazard Class and Category Hazard Hazard Suppl. Hazard

Code(s) Statement

Pictogram, Signal statement statement

Code(s) Word Code(s) Code(s) Code(s)

613-183-00-2 reaction mass of: 5-(N- 413-640-4 STOT RE 2 * H373 ** GHS08 H373 ** methylperfluorooctylsulfonamido)meth — Aquatic Acute 1 H400 GHS09 H410

yl-3-octadecyl-1,3-oxazolidin-2-one; 5- Aquatic Chronic 1 H410 Wng (N- methylperfluoroheptylsulfonamido)met hyl-3-octadecyl-1,3-oxazolidin-2-one

613-184-00-8 nitrilotriethyleneammoniopropane-2-ol 413-670-8 — Eye Irrit. 2 H319 GHS07 H319

2-ethylhexanoate Skin Sens. 1 H317 Wng H317

613-185-00-3 2,3,5,6-tetrahydro-2-methyl-2H- 407-630-9 82633-79-2 Acute Tox. 3 * H301 GHS06 H301 cyclopenta[d]-1,2-thiazol-3-one Eye Dam. 1 H318 GHS05 H318

Skin Sens. 1 H317 GHS09 H317 Aquatic Acute 1 H400 Dgr H410 Aquatic Chronic 1 H410

613-186-00-9 (2R,3R)-3-((R)-1-(tert- 408-050-9 76855-69-1 Eye Irrit. 2 H319 GHS07 H319 butyldimethylsiloxy)ethyl)-4- Skin Sens. 1 H317 GHS09 H317 oxoazetidin-2-yl acetate Aquatic Chronic 2 H411 Wng H411

613-187-00-4 5-(2-amino-5-cyano-6-[2-(2- 410-530-8 — Skin Sens. 1 H317 GHS07 H317 hydroxyethoxy)ethylamino]-4- Wng

methylpyridin-3-ylazo)-3-methyl-2,4- dicarbonitrilethiophene

613-188-00-X 1-(3-(4-fluorophenoxy)propyl)3- 411-500-7 116256-11-2 Acute Tox. 4 * H302 GHS05 H302 methoxy-4-piperidinone Eye Dam. 1 H318 GHS07 H318 Skin Sens. 1 H317 GHS09 H317 Aquatic Chronic 2 H411 Dgr H411

613-189-00-5 1,4,7,10-tetrakis(p-toluensulfonyl)- 414-030-0 52667-88-6 Skin Sens. 1 H317 GHS07 H317

1,4,7,10-tetraazacyclododecane Aquatic Acute 1 H400 GHS09 H410 Aquatic Chronic 1 H410 Wng

501

D050725/02

Classification Labelling Specific Conc. Limits, M-factors Notes

Index No International Chemical Identification EC No CAS No

Hazard Class and Category Hazard Hazard Suppl. Hazard

Code(s) Statement

Pictogram, Signal statement

Code(s) Word Code(s)

statement Code(s) Code(s)

613-190-00-0 disodium 1-amino-4-(2-(5-chloro-6- 414-040-5 149530-93-8 Acute Tox. 4 * H302 GHS07 H302 fluoro-pyrimidin-4-ylamino-methyl)-4- Skin Sens. 1 H317 Wng H317 methyl-6-sulfo-phenylamino)-9,10-

dioxo-9,10-dihydro-anthracene-2- sulfonate

613-191-00-6 3-ethyl-2-methyl-2-(3-methylbutyl)- 421-150-7 143860-04-2 Repr. 1B H360F *** GHS08 H360F ***

1,3-oxazolidine Skin Corr. 1B H314 GHS05 H314 Aquatic Acute 1 H400 GHS09 H410 Aquatic Chronic 1 H410 Dgr

613-192-00-1 3-benzyl-exo-6-nitro-2,4-dioxo-3-aza 426-750-2 151860-15-0 Skin Sens. 1 H317 GHS07 H317 cis-bicyclo[3.1.0]hexane Aquatic Chronic 3 H412 Wng H412

613-193-00-7 pentakis[3- 414-930-3 — Aquatic Chronic 2 H411 GHS09 H411

(dimethylammonio)propylsulfamoyl]- [(6-hydroxy-4,4,8,8-tetramethyl-4,8- diazoniaundecane-1,11- diyldisulfamoyl)di[phthalocyaninecopp er(II)]] heptalactate

613-194-00-2 6,13-dichloro-3,10-bis{2-[4-fluoro-6- 418-000-8 163062-28-0 Eye Dam. 1 H318 GHS05 H318

(2-sulfophenylamino)-1,3,5-triazin-2- Dgr

ylamino]propylamino}benzo[5,6][1,4] oxazino[2,3-.b.]phenoxazine-4,11- disulphonic acid, lithium-, sodium salt

613-195-00-8 2,2-(1,4-phenylene)bis((4H—3,1- 418-280-1 18600-59-4 Skin Sens. 1 H317 GHS07 H317 benzoxazine-4-one) Aquatic Chronic 4 H413 Wng H413

502

D050725/02

Classification Labelling Specific Conc. Limits, M-factors Notes

Index No International Chemical Identification EC No CAS No

Hazard Class and Category Hazard Suppl. Hazard

Code(s) Statement

Pictogram, Signal Hazard statement statement

Code(s) Word Code(s) Code(s) Code(s)

613-196-00-3 5-[[4-chloro-6-[[2-[[4-fluoro-6-[[5- 418-380-5 168113-78-8 Eye Dam. 1 H318 GHS05 H318 hydroxy-6-[(4-methoxy-2- Dgr

sulfophenyl)azo]-7-sulfo-2- naphthalenyl]amino]-1,3,5-triazin-2- yl]amino]-1-methylethyl]amino]-1,3,5- triazin-2-yl]amino]-3-[[4- (ethenylsulfonyl)phenyl]azo]-4- hydroxy-naphtalene-2,7-disulfonic acid, sodium salt

613-197-00-9 reaction mass of: 2,4,6- 420-390-1 187547-46-2 Skin Sens. 1 H317 GHS07 H317 tri(butylcarbamoyl)-1,3,5-triazine; Aquatic Chronic 2 H411 GHS09 H411 2,4,6-tri(methylcarbamoyl)-1,3,5- Wng

triazine; [(2-butyl-4,6-dimethyl)tricarbamoyl]- 1,3,5-triazine; [(2,4-dibutyl-6-methyl)tricarbamoyl]- 1,3,5-triazine

613-198-00-4 2-amino-4-dimethylamino-6- 415-500-8 145963-84-4 Acute Tox. 4 * H302 GHS08 H302 trifluoroethoxy-1,3,5-triazine STOT RE 2 * H373** GHS07 H373** Aquatic Chronic 3 H412 Wng H412

613-199-00-X reaction mass of: 1,3,5-tris(3- 421-550-1 — Carc. 1B H350 GHS08 H350 aminomethylphenyl)-1,3,5- Repr. 1B H360D *** Dgr H360D *** (1H,3H,5H)-triazine-2,4,6 trione; Skin Sens. 1 H317 H317 reaction mass of oligomers of Aquatic Chronic 3 H412 H412

3,5-bis(3-aminomethylphenyl)1- poly[3,5-bis(3-aminomethylphenyl)- 2,4,6-trioxo-1,3,5-(1H,3H,5H)-triazin 1-yl]-1,3,5(1H,3H,5H)-triazine-2,4,6- trione

503

D050725/02

Classification Labelling Specific Conc. Limits, M-factors Notes

Index No International Chemical Identification EC No CAS No

Hazard Class and Category Hazard Pictogram, Signal Hazard Suppl. Hazard

Code(s) Statement statement statement Code(s) Word Code(s) Code(s) Code(s)

613-200-00-3 reaction product of: copper, (29H,31H- 420-980-7 — Eye Dam. 1 H318 GHS05 H318 phthalocyaninato(2-)- Dgr

N29,N30,N31,N32)-, chlorosulfuric acid and 3-(2- sulfooxyethylsulfonyl)aniline, sodium salts

613-201-00-9 (R)-5-bromo-3-(1-methyl-2- 422-390-5 143322-57-0 Repr. 2 H361f *** GHS08 H361f *** EUH070 pyrrolidinyl methyl)-1H-indole STOT RE 1 H372 ** GHS07 H372 **

Acute Tox. 4 * H332 GHS09 H332 Acute Tox. 4 * H302 Dgr H302 Skin Sens. 1 H317 H317 Aquatic Acute 1 H400 H410 Aquatic Chronic 1 H410

613-202-00-4 pymetrozine (ISO); — 123312-89-0 Carc. 2 H351 GHS08 H351

(E)-4,5-dihydro-6-methyl-4-(3- Aquatic Chronic 3 H412 Wng H412

pyridylmethyleneamino)-1,2,4-triazin 3(2H)-one

613-203-00-X pyraflufen-ethyl (ISO); -[1] 129630-19-9 [1] Aquatic Acute 1 H400 GHS09 H410 M=1000

2-chloro-5-(4-chloro-5- -[2] 129630-17-7 [2] Aquatic Chronic 1 H410 Wng

difluoromethoxy-1-methylpyrazol-3- yl)-4-fluorophenoxyacetic acid ethyl ester; [1] pyraflufen (ISO); 2-chloro-5-(4-chloro-5- difluoromethoxy-1-methylpyrazol-3- yl)-4-fluorophenoxyacetic acid [2]

613-204-00-5 oxadiargyl (ISO); 254-637-6 39807-15-3 Repr. 2 H361d*** GHS08 H361d*** M = 1000

3-[2,4-dichloro-5-(2- STOT RE 2 * H373** GHS09 H373** propynyloxy)phenyl]-5-(1,1- Aquatic Acute 1 H400 Wng H410 dimethylethyl)-1,3,4-oxadiazol-2(3H)- Aquatic Chronic 1 H410 one

504

D050725/02

Classification Labelling Specific Conc. Limits, M-factors Notes

Index No International Chemical Identification EC No CAS No

Hazard Class and Category Hazard Hazard Suppl. Hazard

Code(s) Statement

Pictogram, Signal statement statement

Code(s) Word Code(s) Code(s) Code(s)

613-205-00-0 propiconazole(ISO); 262-104-4 60207-90-1 Acute Tox. 4 * H302 GHS07 H302

(±) 1-[2-(2,4-dichlorophenyl)-4-propyl Skin Sens. 1 H317 GHS09 H317 1,3-dioxolan-2-ylmethyl]-1H—1,2,4- Aquatic Acute 1 H400 Wng H410 triazole Aquatic Chronic 1 H410

613-206-00-6 fenamidone (ISO); — 161326-34-7 Aquatic Acute 1 H400 GHS09 H410

(S)-5-methyl-2-methylthio-5-phenyl-3- Aquatic Chronic 1 H410 Wng phenylamino-3,5-dihydroimidazol-4- one

613-208-00-7 imazamox (ISO); — 114311-32-9 Aquatic Acute 1 H400 GHS09 H410

(RS)-2-(4-isopropyl-4-methyl-5-oxo-2- Aquatic Chronic 1 H410 Wng imidazolin-2-yl)-5- methoxymethylnicotinic acid

613-209-00-2 cis-1-(3-chloropropyl)-2,6-dimethyl 417-430-3 63645-17-0 Acute Tox. 3 * H301 GHS06 H301 piperidin hydrochloride STOT RE 2 * H373 ** GHS08 H373 ** Skin Sens. 1 H317 GHS09 H317 Aquatic Chronic 2 H411 Dgr H411

613-210-00-8 2-(3-chloropropyl)-2,5,5-trimethyl-1,3- 417-650-1 88128-57-8 STOT RE 2 * H373 ** GHS08 H373 ** dioxane Aquatic Chronic 3 H412 Wng H412

613-211-00-3 N-methyl-4-(p- 418-240-3 74401-04-0 Skin Sens. 1 H317 GHS07 H317 formylstyryl)pyridinium methylsulfate Aquatic Chronic 3 H412 Wng H412

613-212-00-9 4-[4-(2-ethylhexyloxy)phenyl](1,4- 418-320-8 133467-41-1 Acute Tox. 4 * H302 GHS07 H302 thiazinane-1,1-dioxide) Aquatic Acute 1 H400 GHS09 H410 Aquatic Chronic 1 H410 Wng

613-213-00-4 cis-1-benzoyl-4-[(4- 416-040-0 120807-02-5 Aquatic Chronic 3 H412 — H412 methylsulfonyl)oxy]-L-proline

505

D050725/02

Classification Labelling Specific Conc. Limits, M-factors Notes

Index No International Chemical Identification EC No CAS No

Hazard Class and Category Hazard Hazard Suppl. Hazard

Code(s) Statement

Pictogram, Signal

Code(s) Word Code(s)

statement statement Code(s) Code(s)

613-214-00-X N,N-di-n-butyl-2-(1,2-dihydro-3- 416-260-7 147613-95-4 Aquatic Chronic 4 H413 — H413 hydroxy-6-isopropyl-2-quinolylidene)-

1,3-dioxoindan-5-carboxamide

613-215-00-5 2-chloromethyl-3,4- 416-440-5 72830-09-2 Acute Tox. 4 * H312 GHS08 H312 dimethoxypyridinium chloride Acute Tox. 4 * H302 GHS05 H302 STOT RE 2 * H373 ** GHS07 H373 ** Skin Irrit. 2 H315 GHS09 H315 Eye Dam. 1 H318 Dgr H318 Skin Sens. 1 H317 H317 Aquatic Chronic 2 H411 H411

613-216-00-0 6-tert-butyl-7-(6-diethylamino-2- 416-490-8 162208-01-7 Aquatic Acute 1 H400 GHS09 H410 methyl-3-pyridylimino)-3-(3- Aquatic Chronic 1 H410 Wng

methylphenyl)pyrazolo[3,2- c][1,2,4]triazole

613-217-00-6 4-[3-(3,5-di-tert-butyl-4- 416-770-1 73754-27-5 Aquatic Chronic 4 H413 — H413 hydroxyphenyl)propionyloxy]-1-[2-[3-

(3,5-di-tert-butyl-4- hydrophenyl)propionyloxy]ethyl]- 2,2,6,6-tetramethylpiperidine

613-218-00-1 6-hydroxyindole 417-020-4 2380-86-1 Acute Tox. 4 * H302 GHS05 H302

Eye Dam. 1 H318 GHS07 H318 Skin Sens. 1 H317 GHS09 H317 Aquatic Chronic 2 H411 Dgr H411

613-219-00-7 7a-ethyl-3,5-bis(1-methylethyl)- 417-140-7 79185-77-6 Skin Irrit. 2 H315 GHS07 H315

2,3,4,5-tetrahydrooxazolo[3,4-c]- Aquatic Chronic 2 H411 GHS09 H411 2,3,4,5-tetrahydrooxazole Wng

613-220-00-2 trans-(4S,6S)-5,6-dihydro-6-methyl 417-290-3 147086-81-5 Acute Tox. 4 * H302 GHS07 H302

4H-thieno[2,3-b]thiopyran-4-ol, 7,7- Wng dioxide

506

D050725/02

Classification Labelling Specific Conc. Limits, M-factors Notes

Index No International Chemical Identification EC No CAS No

Hazard Class and Category Hazard Pictogram, Signal Hazard Suppl. Hazard

Code(s) Statement Code(s) Word Code(s) statement statement Code(s) Code(s)

613-221-00-8 2-chloro-5-methyl-pyridine 418-050-0 18368-64-4 Acute Tox. 4 * H312 GHS07 H312

Acute Tox. 4 * H302 Wng H302 Skin Irrit. 2 H315 H315 Aquatic Chronic 3 H412 H412

613-222-00-3 4-(1-oxo-2-propenyl)-morpholine 418-140-1 5117-12-4 Acute Tox. 4 * H302 GHS08 H302

STOT RE 2 * H373 ** GHS05 H373 ** Eye Dam. 1 H318 GHS07 H318 Skin Sens. 1 H317 Dgr H317

613-223-00-9 N-isopropyl-3-(4-fluorophenyl)-1H- 418-790-4 93957-49-4 Aquatic Chronic 4 H413 — H413

indole

613-224-00-4 2,5-dimercaptomethyl-1,4-dithiane 419-770-8 136122-15-1 Acute Tox. 4 * H302 GHS05 H302

Skin Corr. 1B H314 GHS07 H314 Skin Sens. 1 H317 GHS09 H317 Aquatic Acute 1 H400 Dgr H410 Aquatic Chronic 1 H410

613-225-00-X reaction mass of:[2-(anthraquinon-1- 421-290-9 — STOT RE 2 * H373 ** GHS08 H373 ** ylamino)-6-[(5-benzoylamino)- Aquatic Chronic 4 H413 Wng H413

anthraquinone-1-ylamino]-4- phenyl]-1,3,5-triazine; 2,6-bis-[(5-benzoylamino)- anthraquinon-1-ylamino]-4-phenyl 1,3,5-triazine.

613-226-00-5 1-(2-(ethyl(4-(4-(4-(4-(ethyl(2- 420-950-3 163831-67-2 Eye Dam. 1 H318 GHS05 H318 pyridinoethyl)amino)-2- Aquatic Acute 1 H400 GHS09 H410 methylphenylazo)benzoylamino)- Aquatic Chronic 1 H410 Dgr

phenylazo)-3- methylphenyl)amino)ethyl)- pyridinium dichloride

507

D050725/02

Classification Labelling Specific Conc. Limits, M-factors Notes

Index No International Chemical Identification EC No CAS No

Hazard Class and Category Hazard Pictogram, Signal Hazard Suppl. Hazard

Code(s) Statement Code(s) Word Code(s) statement statement Code(s) Code(s)

613-227-00-0 (±)-[(R*,R*) and (R*,S*)]-6-fluoro 419-600-2 99199-90-3 Skin Sens. 1 H317 GHS07 H317

3,4-dihydro-2-oxiranyl-2H-1- Aquatic Chronic 2 H411 GHS09 H411 benzopyran Wng

613-228-00-6 (±)-(R*,S*)-6-fluoro-3,4-dihydro-2- 419-630-6 793669-26-8 Aquatic Chronic 2 H411 GHS09 H411 oxiranyl-2H-1-benzopyran

613-229-00-1 1-acetyl-4-(3-dodecyl-2,5-dioxo-1- 411-930-5 106917-31-1 Skin Irrit. 2 H315 GHS07 H315 pyrrolidinyl)-2,2,6,6- Skin Sens. 1 H317 GHS09 H317 tetramethylpiperidine Aquatic Acute 1 H400 Wng H410 Aquatic Chronic 1 H410

613-230-00-7 florasulam (ISO); — 145701-23-1 Aquatic Acute 1 H400 GHS09 H410

2',6',8-trifluoro-5-methoxy-5- Aquatic Chronic 1 H410 Wng triazolo[1,5-c]; pyrimidine-2-sulfonanilide

613-231-00-2 2,6-diamino-3-((pyridine-3- 421-430-9 28365-08-4 Acute Tox. 4 * H302 GHS08 H302 yl)azo)pyridine STOT RE 2 * H373** GHS07 H373** Aquatic Chronic 2 H411 GHS09 H411 Wng

613-232-00-8 3-(benzo[b]thien-2-yl)-5,6-dihydro 431-030-6 163269-30-5 Acute Tox. 3 * H331 GHS06 H331

1,4,2-oxathiazine-4-oxide STOT RE 2 * H373** GHS05 H373** Eye Dam. 1 H318 GHS08 H318

Aquatic Acute 1 H400 GHS09 H410 Aquatic Chronic 1 H410 Dgr

613-233-00-3 4,4'-(oxy-(bismethylene))-bis-1,3- 423-230-7 56552-15-9 Eye Dam. 1 H318 GHS05 H318 dioxolane Dgr

508

D050725/02

Classification Labelling Specific Conc. Limits, M-factors Notes

Index No International Chemical Identification EC No CAS No

Hazard Class and Category Hazard Pictogram, Signal Hazard Suppl. Hazard

Code(s) Statement Code(s) Word Code(s) statement statement Code(s) Code(s)

613-234-00-9 imidazo[1,2-b]pyridazin 431-510-5 18087-70-2 Acute Tox. 4 * H302 GHS07 H302 hydrochloride Eye Irrit. 2 H319 Wng H319

613-235-00-4 2,3-dihydro-2,2-dimethyl-1H- 424-060-6 6364-17-6 Acute Tox. 4* H302 GHS08 H302 perimidine STOT RE 2 * H373** GHS07 H373** Skin Sens. 1 H317 GHS09 H317 Aquatic Acute 1 H400 Wng H410 Aquatic Chronic 1 H410

613-236-00-X 2-chloro-3-trifluoromethylpyridine 424-520-6 65753-47-1 Acute Tox. 3 * H311 GHS06 H311

Acute Tox. 3 * H301 GHS05 H301 STOT RE 1 H372** GHS08 H372** Skin Corr. 1B H314 Dgr H314 Aquatic Chronic 3 H412 H412

613-237-00-5 6-tert-butyl-3-(3- 424-950-4 133949-92-5 Aquatic Chronic 4 H413 — H413 dodecylsulfonyl)propyl-7H-1,2,4-

triazolo[3.4b][1,3,4]thiadiazine

613-238-00-0 sodium 2-[[4-[(4,6-dichloro-1,3,5- 430-890-1 81992-66-7 Skin Sens. 1 H317 GHS07 H317 triazin-2- Aquatic Acute 1 H400 GHS09 H410 yl)amino]phenyl]sulfonyl]ethyl sulfate Aquatic Chronic 1 H410 Wng

613-239-00-6 2-[3-(methylamino)propyl]-1H- 425-760-4 64137-52-6 Eye Dam. 1 H318 GHS05 H318 benzimidazole Aquatic Chronic 3 H412 Dgr H412

613-241-00-7 3-(2H-tetrazol-5-yl)pyridine 426-810-8 3250-74-6 Eye Dam. 1 H318 GHS05 H318

Dgr

509

D050725/02

Classification Labelling Specific Conc. Limits, M-factors Notes

Index No International Chemical Identification EC No CAS No

Hazard Class and Category Hazard Pictogram, Signal Hazard Suppl. Hazard

Code(s) Statement Code(s) Word Code(s) statement statement Code(s) Code(s)

613-242-00-2 reaction products of 3,10-bis((2- 426-860-0 191877-09-5 Eye Dam. 1 H318 GHS05 H318 aminopropyl)amino)-6,13-dichloro Dgr

4,11-triphenodioxazinedisulfonic acid with 2-amino-1,4-benzenedisulfonic acid, 2-((4-aminophenyl)sulfonyl)ethyl hydrogen sulfate and 2,4,6-trifluoro 1,3,5-triazine, sodium salts

613-243-00-8 4,4'-(1,6- 427-350-0 182235-14-9 Aquatic Chronic 2 H411 GHS09 H411 hexamethylenebis(formylimino))bis(2,

2,6,6-tetramethyl-1-oxylpiperidine)

613-244-00-3 5,7-dichloro-4-hydroxyquinoline 427-420-0 21873-52-9 Aquatic Chronic 2 H411 GHS09 H411

613-245-00-9 2-fluoro-6-trifluoromethylpyridine 428-100-3 94239-04-0 Flam. Liq. 3 H226 GHS02 H226 Acute Tox. 4 * H332 GHS07 H332 Acute Tox. 4 * H302 Wng H302 Aquatic Chronic 3 H412 H412

613-246-00-4 2-hydroxymethyl-3-methyl-4-(2,2,2- 428-200-7 103577-66-8 Aquatic Chronic 3 H412 — H412 trifluoroethoxy)pyridine

613-247-00-X 3-(2-methoxy-4- 428-910-7 107786-36-7 Aquatic Chronic 4 H413 — H413 methoxycarboxybenzyl)-5-nitroindole

613-248-00-5 3,4-dimethyl-1H-pyrazole 429-130-1 2820-37-3 Acute Tox. 4 * H302 GHS05 H302 Eye Dam. 1 H318 GHS07 H318 Aquatic Chronic 3 H412 Dgr H412

613-249-00-0 1-(2-hydroxyethyl)-1H-pyrazol-4,5- 429-300-3 155601-30-2 Eye Dam. 1 H318 GHS05 H318 diyldiammoniumsulfate Skin Sens. 1 H317 GHS07 H317 Aquatic Chronic 2 H411 GHS09 H411 Dgr

510

D050725/02

Classification Labelling Specific Conc. Limits, M-factors Notes

Index No International Chemical Identification EC No CAS No

Hazard Class and Category Hazard Pictogram, Signal Hazard Suppl. Hazard

Code(s) Statement statement statement Code(s) Word Code(s) Code(s) Code(s)

613-250-00-6 reaction mass of: carbonato-bis-N- 429-990-6 — Eye Dam. 1 H318 GHS05 H318 ethyl-2-isopropyl-1,3-oxazolidine; Skin Sens. 1 H317 GHS07 H317 methyl carbonato-N-ethyl-2-isopropyl Aquatic Chronic 3 H412 Dgr H412 1,3-oxazolidine;

2-isopropyl-N-hydroxyethyl 1,3- oxazolidine

613-251-00-1 (R)-3-[(1-methylpyrrolidin-2- 430-560-5 180637-89-2 Acute Tox. 4 * H302 GHS05 H302 yl)methyl]-5-[2- STOT RE 2 * H373** GHS08 H373** (phenylsulfonyl)ethenyl]-1H-indole Eye Dam. 1 H318 GHS07 H318 Skin Sens. 1 H317 Dgr H317

613-253-00-2 2,2-dialkyl-4-hydroxymethyl1,3- 430-580-4 — Skin Irrit. 2 H315 GHS07 H315 EUH019 dioxolane; Aquatic Chronic 2 H411 GHS09 H411

reaction products with ethylene oxide Wng

(alkyl is C 1-12 and the sum to C , 13

average degree of ethoxylation is 3,5)

613-254-00-8 forchlorfenuron (ISO); — 68157-60-8 Carc. 2 H351 GHS08 H351

1-(2-chloro-4-pyridyl)-3-phenylurea Aquatic Chronic 2 H411 GHS09 H411 Wng

613-255-00-3 reaction mass of isomers of: sodium 424-270-8 — Eye Dam. 1 H318 GHS05 H318

[(2-hydroxyethylsulfamoyl){][}2-(2- Dgr piperazin-1- ylethylamino)ethylsulfamoyl][2-(4- aminoethylpiperazine-1- yl)ethylsulfamoyl{](sulfamoyl)[}(sulfo natophthalocyaninato)]copper(II)

613-256-00-9 3'5'-anhydro thymidine 425-810-5 38313-48-3 Aquatic Chronic 3 H412 — H412

511

D050725/02

Classification Labelling Specific Conc. Limits, M-factors Notes

Index No International Chemical Identification EC No CAS No

Hazard Class and Category Hazard Hazard Suppl. Hazard

Code(s) Statement

Pictogram, Signal statement

Code(s) Word Code(s)

statement Code(s) Code(s)

613-257-00-4 2-phthalimidoethyl N-[4-(2-cyano-4- 426-400-9 170222-39-6 Skin Sens. 1 H317 GHS07 H317 nitrophenylazo)phenyl]-N-methyl-β- Aquatic Chronic 4 H413 Wng H413 alaninate

613-258-00-X reaction mass of: 4-chloro-7- 427-730-6 202420-04-0 Skin Corr. 1B H314 GHS05 H314 methylbenzotriazole sodium salt; Aquatic Chronic 3 H412 Dgr H412 4-chloro-5-methylbenzotriazole

sodium salt; 5-chloro-4-methylbenzotriazole sodium salt

613-259-00-5 reaction mass of: [2,4-dioxo-(2- 428-790-6 72963-72-5 Acute Tox. 4 * H302 GHS07 H302 propyn-1-yl)imidazolidin-3- Aquatic Acute 1 H400 GHS09 H410 yl]methyl(1R)-cis-chrysanthemate; Aquatic Chronic 1 H410 Wng

[2,4-dioxo-(2-propyn-1- yl)imidazolidin-3-yl]methyl(1R)-trans- chrysanthemate

613-260-00-0 (±)-4-(3-chlorophenyl)-6-[(4- 430-730-9 — Eye Dam. 1 H318 GHS05 H318 chlorophenyl)hydroxy(1-methyl-1H- Aquatic Acute 1 H400 GHS09 H410 imidazol-5-yl)methyl]-1-methyl-2(1H)- Aquatic Chronic 1 H410 Dgr

quinolin

613-261-00-6 pyrazole-1-carboxamidine 429-520-1 4023-02-3 Acute Tox. 4 * H302 GHS05 H302 monohydrochloride STOT RE 2 * H373** H318 GHS08 H373** Eye Dam. 1 H317 GHS07 H318 Skin Sens. 1 H412 Dgr H317 Aquatic Chronic 3 H412

512

D050725/02

Classification Labelling Specific Conc. Limits, M-factors Notes

Index No International Chemical Identification EC No CAS No

Hazard Class and Category Hazard Hazard Suppl. Hazard

Code(s) Statement

Pictogram, Signal

Code(s) Word Code(s)

statement statement Code(s) Code(s)

613-262-00-1 disodium (E)-1,2-bis-(4-(4- 427-310-2 180850-95-7 Eye Dam. 1 H318 GHS05 H318 methylamino-6-(4- Dgr

methylcarbamoylphenylamino)-1,3,5- triazin-2-ylamino)phenyl-2- sulfonato)ethene

613-263-00-7 monosodium 3-cyano-5-fluoro-6- 429-570-2 Skin Sens. 1 H317 GHS07 H317 hydroxypyridine-2-olate — Wng

613-266-00-3 2-chloro-5-chloromethylthiazole 429-830-5 105827-91-6 Acute Tox. 3 * H311 GHS06 H311

Skin Corr. 1B H314 GHS05 H314 Acute Tox. 4 * H302 GHS09 H302 Skin Sens. 1 H317 Dgr H317 Aquatic Chronic 2 H411 H411

613-267-00-9 thiamethoxam (ISO); 428-650-4 153719-23-4 Acute Tox. 4 * H302 GHS07 H302

3-(2-chloro-thiazol-5-ylmethyl)-5- Aquatic Acute 1 H400 GHS09 H410 M=10 methyl[1,3,5]oxadiazinan-4-ylidene-N- Aquatic Chronic 1 H410 Wng nitroamine

613-268-00-4 (4aS-cis-)-6-benzyl 425-930-8 151213-39-7 Skin Corr. 1B H314 GHS05 H314 octahydropyrrolo[3.4-b]pyridine Acute Tox. 4 * H332 GHS08 H332 Acute Tox. 4 * H302 GHS07 H302 STOT RE 2 * H373** GHS09 H373** Aquatic Chronic 2 H411 Dgr H411

613-269-00-X 2-thiazolidinylidenecyanamide 427-720-1 26364-65-8 Acute Tox. 4* H302 GHS08 H302

STOT RE 2 * H373** GHS07 H373** Aquatic Chronic 3 H412 Wng H412

613-270-00-5 5-amino-N-(2,6-dichloro-3- 428-150-6 113171-13-4 Aquatic Chronic 3 H412 H412 methylphenyl)-1H-1,2,4-triazole-3- —

sulfonamide

513

D050725/02

Classification Labelling Specific Conc. Limits, M-factors Notes

Index No International Chemical Identification EC No CAS No

Hazard Class and Category Hazard Hazard Suppl. Hazard

Code(s) Statement

Pictogram, Signal

Code(s) Word Code(s)

statement statement Code(s) Code(s)

613-271-00-0 tritosulfuron (ISO) (containing ≤0,02% — 142469-14-5 Skin Sens. 1 H317 GHS07 H317 M=10

AMTT); Aquatic Acute 1 H400 GHS09 H410 1-[4-methoxy-6-(trifluoromethyl)- Aquatic Chronic 1 H410 Wng 1,3,5-triazin-2-yl]-3-[2- (trifluoromethyl)benzenesulfonyl]urea (containing ≤ 0,02% AMTT)

613-272-00-6 pyraclostrobin (ISO); — — Acute Tox. 3 * H331 GHS06 H331 M=100 methyl N-{2-[1-(4-chlorophenyl)-1H- Skin Irrit. 2 H315 GHS09 H315

pyrazol-3-yloxymethyl]phenyl}(N- Aquatic Acute 1 H400 Dgr H410 methoxy)carbamate Aquatic Chronic 1 H410

613-273-00-1 tetrahydro-3-methyl-5-((2- 427-600-9 192439-46-6 Aquatic Chronic 2 H411 GHS09 H411 phenylthio)thiazol-5-ylmethyl)-[4H]-

1,3,5-oxadiazinan-4-ylidene-N- nitroamine

613-274-00-7 2,6-dichloro-1- 427-400-1 140623-89-8 Skin Corr. 1B H314 GHS05 H314 fluoropyridiniumtetrafluoroborate Acute Tox. 4 * H302 GHS07 H302 Skin Sens. 1 H317 GHS09 H317 Aquatic Acute 1 H400 Dgr H410 Aquatic Chronic 1 H410

613-275-00-2 3-(2-chloroethyl)-6,7,8,9-tetra-hydro 424-530-0 93076-03-0 Acute Tox. 3 * H301 GHS06 H301

2-methyl-4H-pyrido[1,2-a] pyrimidin STOT SE 2 H371** GHS05 H371** 4-one monohydrochloride STOT RE 2 * H373** GHS08 H373** Eye Dam. 1 H318 GHS09 H318 Skin Sens. 1 H317 Dgr H317 Aquatic Chronic 2 H411 H411

613-276-00-8 1-(2-chlorophenyl)-1,2-dihydro-5H- 426-110-2 98377-35-6 Skin Sens. 1 H317 GHS07 H317 tetrazol-5-one Aquatic Chronic 3 H412 Wng H412

514

D050725/02

Classification Labelling Specific Conc. Limits, M-factors Notes

Index No International Chemical Identification EC No CAS No

Hazard Class and Category Hazard Pictogram, Signal Hazard Suppl. Hazard

Code(s) Statement Code(s) Word Code(s) statement statement Code(s) Code(s)

613-277-00-3 (4-(6-diethylamino-2-methylpyridin-3- 427-070-9 Aquatic Chronic 4 H413 H413 yl)imino-4,5-dihydro-3-methyl-1-(4- — —

methylphenyl)-1H-pyrazol-5-one

613-278-00-9 (3-aminophenyl)pyridin-3- 428-230-0 79568-06-2 STOT RE 2 * H373** GHS08 H373** ylmethanone Aquatic Acute 1 H400 GHS09 H410

Aquatic Chronic 1 H410 Wng

613-279-00-4 2-ethyl-2,3-dihydro-2-methyl-1H- 424-380-6 43057-68-7 Acute Tox. 4 * H302 GHS08 H302 perimidine STOT RE 2 * H373** GHS07 H373** Aquatic Acute 1 H400 GHS09 H410 Aquatic Chronic 1 H410 Wng

613-280-00-X tetrahydro-1,3-dimethyl-1H-pyrimidin 230-625-6 7226-23-5 Repr. 2 H361f*** GHS05 H361f***

2-one; Acute Tox. 4 * H302 GHS08 H302 dimethyl propyleneurea Eye Dam. 1 H318 GHS07 H318 Dgr

613-281-00-5 quinoline 202-051-6 91-22-5 Carc. 1B Muta. 2 H350 GHS08 H350

Acute Tox. 4 * H341 GHS07 H341 Acute Tox. 4 * H312 GHS09 H312 Eye Irrit. 2 H302 Dgr H302 Skin Irrit. 2 H319 H319 Aquatic Chronic 2 H315 H315 H411 H411

613-282-00-0 triticonazole (ISO); — 131983-72-7 Aquatic Chronic 2 H411 GHS09 H411

(RS)-(E)-5-(4-chlorobenzylidene)-2,2- dimethyl-1-(1H-1,2,4-triazol-1- methyl)cyclopentanol

515

D050725/02

Classification Labelling Specific Conc. Limits, M-factors Notes

Index No International Chemical Identification EC No CAS No

Hazard Class and Category Hazard Pictogram, Signal Hazard Suppl. Hazard

Code(s) Statement statement statement Code(s) Word Code(s) Code(s) Code(s)

613-283-00-6 ketoconazole; 265-667-4 65277-42-1 Repr. 1B H360F*** GHS06 H360F***

1-[4-[4-[[(2SR, 4RS)-2-(2,4- Acute Tox. 3 * H301 GHS08 H301 dichlorophenyl)-2-(imidazol-1- STOT RE 2 * H373** GHS09 H373** ylmethyl)-1,3-dioxolan-4- Aquatic Acute 1 H400 Dgr H410 yl]methoxy]phenyl]piperazin-1- Aquatic Chronic 1 H410 yl]ethanone

613-284-00-1 metconazole (ISO); — 125116-23-6 Repr. 2 H361d*** GHS08 H361d***

(1RS, 5RS;1RS, 5SR)-5-(4- Acute Tox. 4 * H302 GHS07 H302 chlorobenzyl)-2,2-dimethyl-1-(1H- Aquatic Chronic 2 H411 GHS09 H411 1,2,4-triazol-1-ylmethyl)cyclopentanol Wng

613-285-00-7 1-hydroxybenzotriazole, anhydrous; 219-989-7 [1] 2592-95-2 [1] Expl. 1.3 H203 GHS01 H203

[1] 219-989-7 [2] 123333-53-9 [2] Dgr 1-hydroxybenzotriazole, monohydrated [2]

613-286-00-2 potassium 1-methyl-3- 418-260-2 183196-57-8 Skin Sens. 1 H317 GHS07 H317 morpholinocarbonyl-4-[3-(1-methyl-3- Wng

morpholinocarbonyl-5-oxo-2- pyrazolin-4-ylidene)-1- propenyl]pyrazole-5-olate; [containing < 0,5 % N,N- dimethylformamide (EC no 200-679-5)]

613-286-01-X potassium 1-methyl-3- 418-260-2 183196-57-8 Repr. 1B H360D*** GHS08 H360D*** morpholinocarbonyl-4-[3-(1-methyl-3- Skin Sens. 1 H317 GHS07 H317

morpholinocarbonyl-5-oxo-2- Dgr pyrazolin-4-ylidene)-1- propenyl]pyrazole-5-olate; [containing ≥ 0,5% N,N- dimethylformamide (EC No 200-679- 5)]

516

D050725/02

Classification Labelling Specific Conc. Limits, M-factors Notes

Index No International Chemical Identification EC No CAS No

Hazard Class and Category Hazard Hazard Suppl. Hazard

Code(s) Statement

Pictogram, Signal statement statement

Code(s) Word Code(s) Code(s) Code(s)

613-287-00-8 1-(3-iodo-4-aminobenzyl)-1H-1,2,4- 419-540-7 160194-26-3 Acute Tox. 4 * H302 GHS07 H302 triazole Skin Sens. 1 H317 GHS09 H317 Aquatic Chronic 2 H411 Wng H411

613-288-00-3 1,3-bis(dimethylcarbamoyl)- 420-930-4 135756-61-5 Acute Tox. 4 * H302 GHS05 H302 imidazolium chloride Eye Dam. 1 H318 GHS07 H318 Aquatic Chronic 3 H412 Dgr H412

613-289-00-9 3-(4-chloro-2-fluoro-5-methylphenyl)- 432-020-4 142623-48-1 Aquatic Acute 1 H400 GHS09 H410

1-methyl-5-(trifluoromethyl)-1H- Aquatic Chronic 1 H410 Wng pyrazole

613-290-00-4 4-hydroxy-7-(2-aminoethyl)-1,3- 432-470-1 189012-93-9 Eye Dam. 1 H318 GHS05 H318 benzothiazol-2(3H)-one hydrochloride Skin Sens. 1 H317 GHS07 H317 Aquatic Acute 1 H400 GHS09 H410 Aquatic Chronic 1 H410 Dgr

613-291-00-X 2,4-dihydro-4-(4-(4-(4- 434-820-9 106461-41-0 STOT RE 2 * H373** GHS08 H373** hydroxyphenyl)-1-piperazinyl)phenyl)- Aquatic Acute 1 H400 GHS09 H410

2-(1-methylpropyl)-3H-1,2,4-triazol-3- Aquatic Chronic 1 H410 Wng one

613-292-00-5 N,N',N''-tris(2-methyl-2,3- 435-010-8 26157-73-3 Muta. 2 H341 GHS08 H341 epoxypropyl)-perhydro-2,4,6-oxo Aquatic Chronic 3 H412 Wng H412 1,3,5-triazine

613-293-00-0 2-(4-tert-butylphenyl)-6-cyano-5- 448-050-6 444065-11-6 Aquatic Chronic 4 H413 — H413

[bis(ethoxycarbonyl methyl)carbamoyloxy]-1H- pyrrolo[1,2-b][1,2,4] triazole-7- carboxylic acid 2,6-di-tert-butyl-4- methylcyclohexylester

613-294-00-6 2-hexyldecanoic acid [4-(6-tert-butyl 448-260-8 379268-96-9 Aquatic Chronic 4 H413 — H413

7-chloro-1H-pyrazolo[1,5- b][1,2,4]triazol-2- yl)phenylcarbamoyl]methylester

517

D050725/02

Classification Labelling Specific Conc. Limits, M-factors Notes

Index No International Chemical Identification EC No CAS No

Hazard Class and Category Hazard Pictogram, Signal Hazard Suppl. Hazard

Code(s) Statement statement statement Code(s) Word Code(s) Code(s) Code(s)

613-295-00-1 11-amino-3-chloro-6,11-dihydro-5,5- 448-720-8 363138-44-7 Acute Tox. 4 * H302 GHS05 H302 dioxo-6-methyl-dibenzo[c, Eye Dam. 1 H318 GHS07 H318 f][1,2]thiazepine hydrochloride Aquatic Chronic 3 H412 Dgr H412

613-296-00-7 pentapotassium 2-(4-(5-[1-(2,5- 418-270-7 — Skin Sens. 1 H317 GHS07 H317 disulfonatophenyl)-4,5-dihydro-3- Aquatic Chronic 3 H412 Wng H412 methylcarbamoyl-5-oxopyrazol-4-

ylidene]-3-methyl-1,3-pentadienyl)-3- methylcarbamoyl-5-oxidopyrazol 1yl)benzene-1,4-disulfonate

613-297-00-2 5-(2-bromophenyl)-2-tert-butyl-2H- 420-820-6 — Flam. Liq. 3 H226 GHS02 H226 tetrazole Acute Tox. 4 * H302 GHS07 H302 Aquatic Chronic 2 H411 GHS09 H411 Wng

613-298-00-8 bis-(6-hydroxy-4-methyl-5-(3- 421-560-6 — STOT RE 2 * H373** GHS05 H373** methylimidazolium-1-yl)-3-(4- Eye Dam. 1 H318 GHS08 H318

phenylazo)-1H-pyridin-2-one)ethylene Aquatic Chronic 2 H411 GHS09 H411 dilactate Dgr

518

D050725/02

Classification Labelling Specific Conc. Limits, M-factors Notes

Index No International Chemical Identification EC No CAS No

Hazard Class and Category Hazard Pictogram, Signal Hazard Suppl. Hazard

Code(s) Statement statement Code(s) Word Code(s) statement Code(s) Code(s)

613-299-00-3 main component 1 (isomer 1): 422-610-1 Eye Dam. 1 H318 GHS05 H318

2-{6-fluoro-4-[3-(2,5-disulfo— Dgr phenylazo)-4-hydroxy-2-sulfonapht-7- ylamino]-1,3,5-triazin-2-ylamino}-3- {6-fluoro-4-[3-(1,5-disulfonaphth-2- ylazo)-4-hydroxy-2-sulfonaphth-7- ylamino]-1,3,5-triazin-2-ylamino}- propane sodium salt; main component 1 (isomer 2): 2-{6-fluoro-4-[3-(2,5- disulfophenylazo)-4-hydroxy-2- sulfonaphth-7-ylamino]-1,3,5-triazin-2- ylamino}-3-{6-fluoro-4-[3(2,5-disulfophenylazo)-4-hydroxy-2-sulfonaphth- 7-ylamino]-1,3,5-triazin-2-ylamino}- propane sodium salt; main component 2: 2,3-bis-{6-fluoro 4-[3-(2,5-disulfo-phenylazo)-4- hydroxy-2-sulfonaphth-7-ylamino]- 1,3,5-triazin-2-ylamino}-propane sodium salt; main component 3: 2,3-bis-{6-fluoro 4-[3-(1,5-disulfonaphth-2-ylazo)-4- hydroxy-2-sulfonaphth-7-ylamino]- 1,3,5-triazin-2-ylamino}-propane sodium salt

613-300-00-7 1-imidazol-1-yl-octadecan-2-ol 434-120-3 — Skin Sens. 1 H317 GHS07 H317

Aquatic Chronic 4 H413 Wng H413

613-301-00-2 dimethyl-1-{[2-methoxy-5-(2-methyl 443-910-7 Aquatic Chronic 4 H413 H413 butoxycarbonyl)phenylcarbamoyl]-[2- — —

octadecyl-1,1-dioxo-1,2,4- benzothiadiazin-3-yl]methyl} imidazole-4,5-dicarboxylate

519

D050725/02

Classification Labelling Specific Conc. Limits, M-factors Notes

Index No International Chemical Identification EC No CAS No

Hazard Class and Category Hazard Hazard Suppl. Hazard

Code(s) Statement

Pictogram, Signal statement statement

Code(s) Word Code(s) Code(s) Code(s)

613-302-00-8 disodium 2-(5-carbamoyl-1-ethyl-2- 432-980-4 243858-60-8 Eye Dam. 1 H318 GHS05 H318 hydroxy-4-methyl-6-oxo-1,6-dihydro Dgr

pyridine-3-ylazo)-4-(4-fluoro-6-(4-(2- sulfonyloxy-ethylsulfonyl)- phenylamino)-1,3,5-triazine-2- ylamino)benzene sulfonate

613-303-00-3 2-(1-methyl-2-(4- 429-800-1 95737-68-1 Aquatic Acute 1 H400 GHS09 H410 phenoxyphenoxy)ethoxy)pyridine Aquatic Chronic 1 H410 Wng

613-304-00-9 5,6-dihydroxy-2,3-dihydro-1H- 421-170-6 138937-28-7 Acute Tox. 4 * H302 GHS05 H302 indolium bromide Eye Dam. 1 H318 GHS07 H318 Dgr

613-305-00-4 2-(2-hydroxy-4-octyloxyphenyl)-2H- 448-630-9 3147-77-1 Aquatic Chronic 4 H413 H413 benzotriazole —

613-306-00-X (2,5-dioxopyrrolidin-1-yl)-9H-fluoren 433-520-5 82911-69-1 Acute Tox. 4 * H302 GHS07 H302

9-ylmethyl carbonate Skin Sens. 1 H317 GHS09 H317 Aquatic Chronic 2 H411 Wng H411

613-307-00-5 clothianidin (ISO); — 210880-92-5 Acute Tox. 4 * H302 GHS07 H302 M=10

3-[(2-chloro-1,3-thiazol-5-yl)methyl]- Aquatic Acute 1 H400 GHS09 H410 2-methyl-1-nitroguanidine Aquatic Chronic 1 H410 Wng

613-308-00-0 2-amino-5-methylthiazole 423-800-5 7305-71-7 Acute Tox. 4 * H302 GHS08 H302

STOT RE 2 * H373** GHS07 H373** Aquatic Acute 1 H400 GHS09 H410 Aquatic Chronic 1 H410 Wng

613-309-00-6 1-methyl-3-phenyl-1-piperazine 431-180-2 5271-27-2 Acute Tox. 4 * H312 GHS05 H312

Acute Tox. 4 * H302 GHS07 H302 Skin Irrit. 2 H315 Dgr H315 Eye Dam. 1 H318 H318 Aquatic Chronic 3 H412 H412

520

D050725/02

Classification Labelling Specific Conc. Limits, M-factors Notes

Index No International Chemical Identification EC No CAS No

Hazard Class and Category Hazard Pictogram, Signal Hazard Suppl. Hazard

Code(s) Statement statement Code(s) Word Code(s) statement Code(s) Code(s)

613-310-00-1 (-)(3S, 4R)-4-(4-fluorophenyl)-3-(3,4- 432-360-3 105813-13-6 Acute Tox. 4 * H302 GHS07 H302 methylenedioxy-phenoxymethyl)-N- Skin Sens. 1 H317 GHS09 H317 benzylpiperidine hydrochloride Aquatic Acute 1 H400 Wng H410 Aquatic Chronic 1 H410

613-311-00-7 methyl-5-nitrophenyl-guanidine 435-500-1 152460-07-6 Acute Tox. 4 * H302 GHS07 H302

Eye Irrit. 2 H319 Wng H319 Skin Sens. 1 H317 H317 Aquatic Chronic 3 H412 H412

613-312-00-2 2-(4-methyl-2-phenyl-1- 420-200-5 — Acute Tox. 4 * H302 GHS05 H302 piperazinyl)benzenemethanol Eye Dam. 1 H318 GHS07 H318 monohydrochloride Skin Sens. 1 H317 Dgr H317 Aquatic Chronic 3 H412 H412

613-313-00-8 2-(4-(4-(3-pyridinyl)-1H-imidazol-1- 442-780-9 173838-67-0 Aquatic Chronic 3 H412 — H412 yl)butyl)-1H-isoindole-1,3(2H)-dione

613-314-00-3 4-decyloxazolidin-2-one; 443-770-7 7693-82-5 Aquatic Acute 1 H400 GHS09 H410

4-decyl-1,3-oxazolidin-2-one Aquatic Chronic 1 H410 Wng

613-315-00-9 tetrapotassium 4-[5-[3-carboxylato-4,5- 430-390-1 — Acute Tox. 4 * H332 GHS07 H332 dihydro-5-oxo1-(4- Aquatic Chronic 3 H412 Wng H412 sulfonatophenyl)pyrazol-4-ylidene]-3-

(piperidinocarbonyl)penta-1,3- dienylidene]-5-hydroxy-1-(4- sulfonatophenyl)pyrazole-3- carboxylate

613-316-00-4 trimethylopropane tri(3- 257-765-0 52234-82-9 Muta. 2 H341 GHS05 H341 aziridinylpropanoate); Eye Dam. 1 H318 GHS08 H318 (TAZ) Skin Sens. 1 H317 GHS07 H317 Dgr

613-317-00-X penconazole (ISO); 1-[2-(2,4- 266-275-6 66246-88-6 Repr. 2 H361d GHS08 H361d M = 1 dichlorophenyl)pentyl]-1H-1,2,4- Acute Tox. 4 H302 GHS07 H302 M = 1 triazole Aquatic Acute 1 H400 GHS09 H410

Aquatic Chronic 1 H410 Wng

521

D050725/02

Classification Labelling Specific Conc. Limits, M-factors Notes

Index No International Chemical Identification EC No CAS No

Hazard Class and Category Hazard Pictogram, Signal Hazard Suppl. Hazard

Code(s) Statement statement Code(s) Word Code(s) statement Code(s) Code(s)

614-002-00-X salts of nicotine — — Acute Tox. 2 * H330 GHS06 H330 A

Acute Tox. 1 H310 GHS09 H310 Acute Tox. 2 * H300 Dgr H300 Aquatic Chronic 2 H411 H411

614-003-00-5 strychnine 200-319-7 57-24-9 Acute Tox. 1 H310 GHS06 H310

Acute Tox. 2 * H300 GHS09 H300 Aquatic Acute 1 H400 Dgr H410 Aquatic Chronic 1 H410

614-004-00-0 salts of strychnine — — Acute Tox. 2 * H330 GHS06 H330 A

Acute Tox. 2 * H300 GHS09 H300 Aquatic Acute 1 H400 Dgr H410 Aquatic Chronic 1 H410

614-005-00-6 colchicine 200-598-5 64-86-8 Muta. 1B H340 GHS06 H340

Acute Tox. 2 * H300 GHS08 H300 Dgr

614-006-00-1 brucine; 206-614-7 357-57-3 Acute Tox. 2 * H330 GHS06 H330

2,3-dimethoxystrychnine Acute Tox. 2 * H300 Dgr H300 Aquatic Chronic 3 H412 H412

614-007-00-7 brucine sulphate; [1] 225-432-9 [1] 4845-99-2 [1] Acute Tox. 2 * H330 GHS06 H330 A brucine nitrate; [2] 227-317-9 [2] 5786-97-0 [2] Acute Tox. 2 * H300 Dgr H300

strychnidin-10-one, 2,3-dimethoxy-, 269-439-5 [3] 68239-26-9 [3] Aquatic Chronic 3 H412 H412 mono[(R)-1-methylheptyl 1,2- 269-710-8 [4] 68310-42-9 [4] benzenedicarboxylate]; [3] strychnidin-10-one, 2,3-dimethoxy-, compd.with (S) mono(1-methylheptyl)- 1,2-benzenedicarboxylate (1:1) [4]

614-008-00-2 aconitine 206-121-7 302-27-2 Acute Tox. 2 * H330 GHS06 H330

Acute Tox. 2 * H300 Dgr H300

614-009-00-8 salts of aconitine — — Acute Tox. 2 * H330 GHS06 H330 A

Acute Tox. 2 * H300 Dgr H300

614-010-00-3 atropine 200-104-8 51-55-8 Acute Tox. 2 * H330 GHS06 H330

Acute Tox. 2 * H300 Dgr H300

522

D050725/02

Classification Labelling Specific Conc. Limits, M-factors Notes

Index No International Chemical Identification EC No CAS No

Hazard Class and Category Hazard Pictogram, Signal Hazard Suppl. Hazard

Code(s) Statement statement Code(s) Word Code(s) statement Code(s) Code(s)

614-011-00-9 salts of atropine — — Acute Tox. 2 * H330 GHS06 H330 A

Acute Tox. 2 * H300 Dgr H300

614-012-00-4 hyoscyamine 202-933-0 101-31-5 Acute Tox. 2 * H330 GHS06 H330

Acute Tox. 2 * H300 Dgr H300

614-013-00-X salts of hyoscyamine — — Acute Tox. 2 * H330 GHS06 H330 A

Acute Tox. 2 * H300 Dgr H300

614-014-00-5 hyoscine 200-090-3 51-34-3 Acute Tox. 2 * H330 GHS06 H330

Acute Tox. 1 H310 Dgr H310 Acute Tox. 2 * H300 H300

614-015-00-0 salts of hyoscine — — Acute Tox. 2 * H330 GHS06 H330 A

Acute Tox. 1 H310 Dgr H310 Acute Tox. 2 * H300 H300

614-016-00-6 pilocarpine 202-128-4 92-13-7 Acute Tox. 2 * H330 GHS06 H330

Acute Tox. 2 * H300 Dgr H300

614-017-00-1 salts of pilocarpine — — Acute Tox. 2 * H330 GHS06 H330 A

Acute Tox. 2 * H300 Dgr H300

614-018-00-7 papaverine 200-397-2 58-74-2 Acute Tox. 4 * H302 GHS07 H302

Wng

614-019-00-2 salts of papaverine — — Acute Tox. 4 * H302 GHS07 H302 A

Wng

614-020-00-8 physostigmine 200-332-8 57-47-6 Acute Tox. 2 * H330 GHS06 H330

Acute Tox. 2 * H300 Dgr H300

614-021-00-3 salts of physostigmine — — Acute Tox. 2 * H330 GHS06 H330 A

Acute Tox. 2 * H300 Dgr H300

523

D050725/02

Classification Labelling Specific Conc. Limits, M-factors Notes

Index No International Chemical Identification EC No CAS No

Hazard Class and Category Hazard Pictogram, Signal Hazard Suppl. Hazard

Code(s) Statement Code(s) Word Code(s) statement statement Code(s) Code(s)

614-022-00-9 digitoxin 200-760-5 71-63-6 Acute Tox. 3 * H331 GHS06 H331

Acute Tox. 3 * H301 GHS08 H301 STOT RE 2 * H373 ** Dgr H373 **

614-023-00-4 ephedrine 206-080-5 299-42-3 Acute Tox. 4 * H302 GHS07 H302

Wng

614-024-00-X salts of ephedrine — — Acute Tox. 4 * H302 GHS07 H302 A

Wng

614-025-00-5 ouabain 211-139-3 630-60-4 Acute Tox. 3 * H331 GHS06 H331

Acute Tox. 3 * H301 GHS08 H301 STOT RE 2 * H373 ** Dgr H373 **

614-026-00-0 strophantin-K 234-239-9 11005-63-3 Acute Tox. 3 * H331 GHS06 H331

Acute Tox. 3 * H301 GHS08 H301 STOT RE 2 * H373 ** Dgr H373 **

614-027-00-6 bufa-4,20,22-trienolide, 6-(acetyloxy)- 208-077-4 507-60-8 Acute Tox. 2 * H300 GHS06 H300

3-(β-D-glucopyranosyloxy)-8,14- Dgr dihydroxy-, (3β, 6β)-; red squill; scilliroside

614-028-00-1 reaction mass of: 2-ethylhexyl mono 414-420-0 — Eye Dam. 1 H318 GHS05 H318

D-glucopyranoside; Dgr 2-ethylhexyl di-D-glucopyranoside

614-029-00-7 constitutional isomers of penta-O- 419-640-0 68784-14-5 Acute Tox. 4 * H302 GHS07 H302 allyl-β-D-fructofuranosyl-α-D- Wng

glucopyranoside; constitutional isomers of hexa-O-allylβ-D-fructofuranosyl-α-D- glucopyranoside; constitutional isomers of hepta-O- allyl-β-D-fructofuransoyl-α-D- glucopyranoside

524

D050725/02

Classification Labelling Specific Conc. Limits, M-factors Notes

Index No International Chemical Identification EC No CAS No

Hazard Class and Category Hazard Pictogram, Signal Hazard Suppl. Hazard

Code(s) Statement statement Code(s) Word Code(s) statement Code(s) Code(s)

615-001-00-7 methyl isocyanate 210-866-3 624-83-9 Flam. Liq. 2 H225 GHS02 H225

Repr. 2 H361d*** GHS06 H361d*** Acute Tox. 2 * H330 GHS05 H330 Acute Tox. 3 * H311 GHS08 H311 Acute Tox. 3 * H301 Dgr H301 Resp. Sens. 1 H334 H334 Skin Sens. 1 H317 H317 STOT SE 3 H335 H335 Skin Irrit. 2 H315 H315 Eye Dam. 1 H318 H318

615-002-00-2 methyl isothiocyanate 209-132-5 556-61-6 Acute Tox. 3 * H331 GHS06 H331

Acute Tox. 3 * H301 GHS05 H301 Skin Corr. 1B H314 GHS09 H314 Skin Sens. 1 H317 Dgr H317 Aquatic Acute 1 H400 H410 Aquatic Chronic 1 H410

615-003-00-8 thiocyanic acid 207-337-4 463-56-9 Acute Tox. 4 * H332 GHS07 H332 EUH032

Acute Tox. 4 * H312 Wng H312 Acute Tox. 4 * H302 H302 Aquatic Chronic 3 H412 H412

615-004-00-3 salts of thiocyanic acid, with the Acute Tox. 4 * H332 GHS07 H332 EUH032 A exception of those specified elsewhere — — Acute Tox. 4 * H312 Wng H312

in this Annex Acute Tox. 4 * H302 H302 Aquatic Chronic 3 H412 H412

615-005-00-9 4,4'-methylenediphenyl diisocyanate; 202-966-0 [1] 101-68-8 [1] Carc. 2 H351 GHS08 H351 Eye Irrit. 2; H319: C2 diphenylmethane-4,4'-diisocyanate; [1] 219-799-4 [2] 2536-05-2 [2] Acute Tox. 4 * H332 GHS07 H332 C ≥ 5 % Skin Irrit.

2,2'-methylenediphenyl diisocyanate; 227-534-9 [3] 5873-54-1 [3] STOT RE 2 * H373** Dgr H373** 2; H315: C ≥ 5 % diphenylmethane-2,2'-diisocyanate; [2] 247-714-0 [4] 26447-40-5 [4] Eye Irrit. 2 H319 H319 Resp. Sens. 1; H334: o-(p-isocyanatobenzyl)phenyl STOT SE 3 H335 H335 C ≥ 0,1% isocyanate; Skin Irrit. 2 H315 H315 STOT SE 3; H335: diphenylmethane-2,4'-diisocyanate; [3] Resp. Sens. 1 H334 H334 C ≥ 5 % methylenediphenyl diisocyanate [4] Skin Sens. 1 H317 H317

525

D050725/02

Classification Labelling Specific Conc. Limits, M-factors Notes

Index No International Chemical Identification EC No CAS No

Hazard Class and Category Hazard Pictogram, Signal Hazard Suppl. Hazard

Code(s) Statement statement Code(s) Word Code(s) statement Code(s) Code(s)

615-006-00-4 2-methyl-m-phenylene diisocyanate; 202-039-0 [1] 91-08-7 [1] Carc. 2 H351 GHS06 H351 Resp. Sens. 1; C toluene-2,4-di-isocyanate; [1] 209-544-5 [2] 584-84-9 [2] Acute Tox. 2 * H330 GHS08 H330 H334: C ≥

4-methyl-m-phenylene diisocyanate; 247-722-4 [3] 26471-62-5 [3] Eye Irrit. 2 H319 Dgr H319 0,1 % toluene-2,6-di-isocyanate; [2] STOT SE 3 H335 H335 m-tolylidene diisocyanate; Skin Irrit. 2 H315 H315 toluene-diisocyanate [3] Resp. Sens. 1 H334 H334 Skin Sens. 1 H317 H317 Aquatic Chronic 3 H412 H412

615-007-00-X 1,5-naphthylene diisocyanate 221-641-4 3173-72-6 Acute Tox. 4 * H332 GHS08 H332

Eye Irrit. 2 H319 GHS07 H319 STOT SE 3 H335 Dgr H335 Skin Irrit. 2 H315 H315 Resp. Sens. 1 H334 H334 Aquatic Chronic 3 H412 H412

615-008-00-5 3-isocyanatomethyl-3,5,5- 223-861-6 4098-71-9 Acute Tox. 3 * H331 GHS06 H331 * trimethylcyclohexyl isocyanate; Eye Irrit. 2 H319 GHS08 H319 Resp. Sens. 1; H334: 2 isophorone di-isocyanate STOT SE 3 H335 GHS09 H335 C ≥0,5 % Skin Irrit. 2 H315 Dgr H315 Skin Sens.1; H317: Resp. Sens. 1 H334 H334 C ≥0,5% Skin Sens. 1 H317 H317

Aquatic Chronic 2 H411 H411

615-009-00-0 4,4'-methylenedi(cyclohexyl 225-863-2 5124-30-1 Acute Tox. 3 * H331 GHS06 H331 * 2 isocyanate); dicyclohexylmethane-4,4'- Eye Irrit. 2 H319 GHS08 H319 Resp. Sens. 1;

di-isocyanate STOT SE 3 H335 Dgr H335 H334: C ≥0,5% Skin Irrit. 2 H315 H315 Skin Sens. 1; H317: Resp. Sens. 1 H334 H334 C ≥0,5%

Skin Sens. 1 H317 H317

526

D050725/02

Classification Labelling Specific Conc. Limits, M-factors Notes

Index No International Chemical Identification EC No CAS No

Hazard Class and Category Hazard Pictogram, Signal Hazard Suppl. Hazard

Code(s) Statement statement statement Code(s) Word Code(s) Code(s) Code(s)

615-010-00-6 2,2,4-trimethylhexamethylene-1,6-di 241-001-8 [1] 16938-22-0 [1] Acute Tox. 3 * H331 GHS06 H331 * C2 isocyanate; [1] 239-714-4 [2] 15646-96-5 [2] Eye Irrit. 2 H319 GHS08 H319 Resp. Sens. 1; H334:

2,4,4-trimethylhexamethylene-1,6-di STOT SE 3 H335 Dgr H335 C ≥0,5% isocyanate [2] Skin Irrit. 2 H315 H315 Skin Sens. 1; H317: Resp. Sens. 1 H334 H334 C ≥0,5%

615-011-00-1 hexamethylene-di-isocyanate 212-485-8 822-06-0 Acute Tox. 3 * H331 GHS06 H331 * 2

Eye Irrit. 2 H319 GHS08 H319 Resp. Sens. 1; H334: STOT SE 3 H335 Dgr H335 C ≥ Skin Irrit. 2 H315 H315 0,5 % Resp. Sens. 1 H334 H334 Skin Sens. 1; H317: Skin Sens. 1 H317 H317 C ≥0,5%

615-012-00-7 4-isocyanatosulphonyltoluene; 223-810-8 4083-64-1 Eye Irrit. 2 H319 GHS08 H319 EUH014 Eye Irrit.; tosyl isocyanate STOT SE 3 H335 GHS07 H335 H319: C ≥ 5 % Skin Irrit. 2 H315 Dgr H315 STOT SE 3; H335: Resp. Sens. 1 H334 H334 C ≥ 5% Skin Irrit. 2; H315: C ≥ 5%

615-014-00-8 tris(1-dodecyl-3-methyl-2- — 7276-58-6 Acute Tox. 4 * H302 GHS07 H302 phenylbenzimidazolium)hexacyanoferr Wng

ate

615-015-00-3 1,7,7-trimethylbicyclo(2,2,1)hept-2-yl 204-081-5 115-31-1 Acute Tox. 4 * H302 GHS07 H302 thiocyanatoacetate; Aquatic Acute 1 H400 GHS09 H410 isobornyl thiocyanoacetate Aquatic Chronic 1 H410 Wng

615-016-00-9 potassium cyanate 209-676-3 590-28-3 Acute Tox. 4 * H302 GHS07 H302

Wng

615-017-00-4 calcium cyanamide 205-861-8 156-62-7 Acute Tox. 4 * H302 GHS05 H302

STOT SE 3 H335 GHS07 H335 Eye Dam. 1 H318 Dgr H318

527

D050725/02

Classification Labelling Specific Conc. Limits, M-factors Notes

Index No International Chemical Identification EC No CAS No

Hazard Class and Category Hazard Pictogram, Signal Hazard Suppl. Hazard

Code(s) Statement statement Code(s) Word Code(s) statement Code(s) Code(s)

615-018-00-X 2-(2-butoxyethoxy)ethyl thiocyanate 203-985-7 112-56-1 Flam. Liq. 3 H226 GHS02 H226

Acute Tox. 3 * H311 GHS06 H311 Acute Tox. 3 * H301 Dgr H301

615-019-00-5 dicyclohexylcarbodiimide 208-704-1 538-75-0 Acute Tox. 3 * H311 GHS06 H311

Acute Tox. 4 * H302 GHS05 H302 Eye Dam. 1 H318 H38 Skin Sens. 1 H317 Dgr H317

615-020-00-0 methylene dithiocyanate 228-652-3 6317-18-6 Acute Tox. 2 * H330 GHS06 H330

Acute Tox. 3 * H301 GHS05 H301 Skin Corr. 1B H314 GHS09 H314 Skin Sens. 1 H317 Dgr H317 Aquatic Acute 1 H400 H400

615-021-00-6 1,3,5-tris(oxiranylmethyl)-1,3,5- 219-514-3 2451-62-9 Muta. 1B H340 GHS06 H340 triazine-2,4,6(1H,3H,5H)-trione; Acute Tox. 3 * H331 GHS08 H331 Acute Tox. 3 * H301 GHS05 H301

TGIC STOT RE 2 * H373 ** Dgr H373 ** Eye Dam. 1 H318 H318

Skin Sens. 1 H317 H317 Aquatic Chronic 3 H412 H412

615-022-00-1 methyl 3-isocyanatosulfonyl-2- 410-550-7 79277-18-2 STOT RE 2 * H373** GHS08 H373** EUH014 thiophene-carboxylate Resp. Sens. 1 H334 H334

Skin Sens. 1 H317 Dgr H317

615-023-00-7 2-(isocyanatosulfonylmethyl)benzoic 410-900-9 83056-32-0 Flam. Liq. 3 H226 GHS02 H226 EUH014 acid methyl ester; (alt.):methyl 2- Muta. 2 H341 GHS08 H341

(isocyanatosulfonylmethyl)benzoate Acute Tox. 4 * H332 GHS05 H332 STOT RE 2 * H373 ** GHS07 H373 ** Eye Dam. 1 H318 Dgr H318 Resp. Sens. 1 H334 H334

528

D050725/02

Classification Labelling Specific Conc. Limits, M-factors Notes

Index No International Chemical Identification EC No CAS No

Hazard Class and Category Hazard Pictogram, Signal Hazard Suppl. Hazard

Code(s) Statement statement Code(s) Word Code(s) statement Code(s) Code(s)

615-024-00-2 2-phenylethylisocyanate 413-080-0 1943-82-4 Acute Tox. 3 * H331 GHS06 H331

Acute Tox. 4 * H302 GHS08 H302 Skin Corr. 1A H314 GHS05 H314 Resp. Sens. 1 H334 GHS09 H334 Skin Sens. 1 H317 Dgr H317 Aquatic Chronic 2 H411 H411

615-025-00-8 4,4'-ethylidenediphenyl dicyanate 405-740-1 47073-92-7 Acute Tox. 4 * H332 GHS08 H332

Acute Tox. 4 * H302 GHS05 H302 STOT RE 2 * H373 ** GHS07 H373 ** Eye Dam. 1 H318 GHS09 H318 Aquatic Acute 1 H400 Dgr H410 Aquatic Chronic 1 H410

615-026-00-3 4,4'-methylenebis(2,6-dimethylphenyl 405-790-4 101657-77-6 Skin Sens. 1 H317 GHS07 H317 cyanate) Aquatic Chronic 3 H412 Wng H412

615-028-00-4 ethyl 2-(isocyanatosulfonyl)benzoate 410-220-2 77375-79-2 Acute Tox. 4 * H302 GHS05 H302 EUH014

STOT RE 2 * H373** GHS08 H373** Eye Dam. 1 H318 GHS07 H318 Resp. Sens. 1 H334 Dgr H334 Skin Sens. 1 H317 H317

615-029-00-X 2,5-bis-isocyanatomethyl 411-280-2 — Acute Tox. 2 * H330 GHS06 H330 bicyclo[2.2.1]heptane Acute Tox. 4 * H302 GHS08 H302 Skin Corr. 1B H314 GHS05 H314 Resp. Sens. 1 H334 Dgr H334 Skin Sens. 1 H317 H317 Aquatic Chronic 3 H412 H412

615-030-00-5 alkali salts and alkali earth salts of Acute Tox. 4 * H332 GHS07 H332 thiocyanic acid, with the exception of Acute Tox. 4 * H312 Wng H312 A those specified elsewhere in this Acute Tox. 4 * H302 H302 Annex Aquatic Chronic 3 H412 H412

— —

529

D050725/02

Classification Labelling Specific Conc. Limits, M-factors Notes

Index No International Chemical Identification EC No CAS No

Hazard Class and Category Hazard Hazard Suppl. Hazard

Code(s) Statement

Pictogram, Signal statement

Code(s) Word Code(s)

statement Code(s) Code(s)

615-031-00-0 thallium thiocyanate 222-571-7 3535-84-0 Acute Tox. 2 * H330 GHS06 H330

Acute Tox. 2 * H300 GHS08 H300 Acute Tox. 4 * H312 GHS09 H312 STOT RE 2 H373** Dgr H373** Aquatic Chronic 2 H411 H411

615-032-00-6 metal salts of thiocyanic acid, with the — — Acute Tox. 4 * H332 GHS07 H332 A exception of those specified elsewhere Acute Tox. 4 * H312 GHS09 H312

in this Annex Acute Tox. 4 * H302 Wng H302 Aquatic Acute 1 H400 H410 Aquatic Chronic 1 H410

615-033-00-1 reaction product of 430-980-9 Aquatic Chronic 4 H413 H413 diphenylmethanediisocyanate, — —

octylamine, oleylamine and cyclohexylamine (1:1.58:0.32:0097)

615-034-00-7 reaction product of 430-750-8 Aquatic Chronic 4 H413 H413

diphenylmethanediisocyanate, — —

octylamine, 4-ethoxyaniline and ethylenediamine (1:0,37:1,53:0,05)

615-035-00-2 reaction product of 430-930-6 122886-55-9 Aquatic Chronic 4 H413 H413 diphenylmethanediisocyanate, —

octylamine and oleylamine (molar ratio 1:1.86:0.14)

615-036-00-8 reaction product of 430-940-0 Aquatic Chronic 4 H413 H413

diphenylmethanediisocyanate, — —

toluenediisocyanate (reaction of isomers: 65% 2,4-and 35% 2,6-diisocyanate), octylamine, oleylamine and 4- ethoxyaniline (molar ratio 4:1:7:1:2)

530

D050725/02

Classification Labelling Specific Conc. Limits, M-factors Notes

Index No International Chemical Identification EC No CAS No

Hazard Class and Category Hazard Pictogram, Signal Hazard Suppl. Hazard

Code(s) Statement Code(s) Word Code(s) statement statement Code(s) Code(s)

615-037-00-3 reaction product of 430-950-5 Aquatic Chronic 4 H413 H413 diphenylmethanediisocyanate, — —

toluenediisocyanate (reaction mass of isomers: 65% 2,4-and 35% 2,6- diisocyanate), octylamine and oleylamine (molar ratio 4:1:9:1)

615-038-00-9 reaction product of toluenediisocyanate 430-960-1 Aquatic Chronic 4 H413 H413

(reaction mass of isomers: 65% 2,4- — — and 35% 2,6-diisocyanate) and aniline (molarratio 1:2)

615-039-00-4 reaction product of 430-970-4 — Aquatic Chronic 4 H413 — H413 diphenylmethanediisocyanate,

toluenediisocyanate (reaction mass of isomers: 65% 2,4-and 35% 2,6- diisocyanate), octylamine, oleylamine and 4-ethoxyaniline (molar ratio 3.88:1:6.38:0.47:2.91)

615-044-00-1 4-chlorophenylisocyanate 203-176-9 104-12-1 Acute Tox. 2 * H330 GHS06 H330

Acute Tox. 4 * H302 GHS05 H302 STOT SE 3 H335 GHS08 H335 Skin Irrit. 2 H315 GHS09 H315 Eye Dam. 1 H318 Dgr H318 Resp. Sens. 1 H334 H334 Aquatic Acute 1 H400 H410 Aquatic Chronic 1 H410

615-045-00-7 4,4'-methylene bis(3-chloro-2,6-di 420-530-1 — Resp. Sens. 1 H334 GHS08 H334 ethylphenylisocyanate) Skin Sens. 1 H317 Dgr H317

Aquatic Chronic 4 H413 H413

616-001-00-X N,N-dimethylformamide; 200-679-5 68-12-2 Repr. 1B H360D *** GHS08 H360D *** dimethyl formamide Acute Tox. 4 * H332 GHS07 H332

Acute Tox. 4 * H312 Dgr H312 Eye Irrit. 2 H319 H319

531

D050725/02

Classification Labelling Specific Conc. Limits, M-factors Notes

Index No International Chemical Identification EC No CAS No

Hazard Class and Category Hazard Suppl. Hazard

Code(s) Statement

Pictogram, Signal Hazard statement statement

Code(s) Word Code(s) Code(s) Code(s)

616-002-00-5 2-fluoroacetamide 211-363-1 640-19-7 Acute Tox. 2 * H300 GHS06 H300

Acute Tox. 3 * H311 Dgr H311

616-003-00-0 acrylamide; 201-173-7 79-06-1 Carc. 1B H350 GHS06 H350 D prop-2-enamide Muta. 1B Repr. 2 H340 GHS08 H340

Acute Tox. 3 * H361f *** Dgr H361f *** STOT RE 1 H301 H301 Acute Tox. 4 * H372 ** H372 ** Acute Tox. 4 * H332 H332 Eye Irrit. 2 H312 H312 Skin Irrit. 2 H319 H319 Skin Sens. 1 H315 H315 H317 H317

616-004-00-6 allidochlor (ISO); 202-270-7 93-71-0 Acute Tox. 4 * H312 GHS07 H312

N,N-diallylchloroacetamide Acute Tox. 4 * H302 GHS09 H302 Eye Irrit. 2 H319 Wng H319 Skin Irrit. 2 H315 H315 Aquatic Chronic 2 H411 H411

616-005-00-1 chlorthiamid (ISO); 217-637-7 1918-13-4 Acute Tox. 4 * H302 GHS07 H302

2,6-dichloro (thiobenzamide) Wng

616-007-00-2 diphenamid (ISO); 213-482-4 957-51-7 Acute Tox. 4 * H302 GHS07 H302

N,N-dimethyl-2,2-diphenylacetamide Aquatic Chronic 3 H412 Wng H412

616-008-00-8 propachlor (ISO); 217-638-2 1918-16-7 Acute Tox. 4 * H302 GHS07 H302

2-chloro-N-isopropylacetanilide; Eye Irrit. 2 H319 GHS09 H319 α-chloro-N-isopropylacetanilide Skin Sens. 1 H317 Wng H317 Aquatic Acute 1 H400 H410 Aquatic Chronic 1 H410

616-009-00-3 propanil (ISO); 211-914-6 709-98-8 Acute Tox. 4 * H302 GHS07 H302 M=10

3',4'-dichloropropionanilide Aquatic Acute 1 H400 GHS09 H400 Wng

532

D050725/02

Classification Labelling Specific Conc. Limits, M-factors Notes

Index No International Chemical Identification EC No CAS No

Hazard Class and Category Hazard Hazard Suppl. Hazard

Code(s) Statement

Pictogram, Signal statement statement

Code(s) Word Code(s) Code(s) Code(s)

616-010-00-9 tosylchloramide sodium 204-854-7 127-65-1 Acute Tox. 4 * H302 GHS08 H302 EUH031

Skin Corr. 1B H314 GHS05 H314 Resp. Sens. 1 H334 GHS07 H334 Dg

616-012-00-X N- 211-952-3 719-96-0 Skin Irrit. 2 H315 GHS07 H315

(dichlorofluoromethylthio)phthalimide; Wng N- (fluorodichloromethylthio)phthalimide

616-013-00-5 butyraldehyde oxime 203-792-8 110-69-0 Acute Tox. 3 * H311 GHS06 H311

Acute Tox. 4 * H302 Dgr H302 Eye Irrit. 2 H319 H319

616-014-00-0 2-butanone oxime; 202-496-6 96-29-7 Carc. 2 H351 GHS08 H351 ethyl methyl ketoxime; Acute Tox. 4 * H312 GHS05 H312 ethyl methyl ketone oxime Eye Dam. 1 H318 GHS07 H318 Skin Sens. 1 H317 Dgr H317

616-015-00-6 alachlor (ISO); 240-110-8 15972-60-8 Carc. 2 H351 GHS08 H351 M=10

2-chloro-2',6'-diethyl-N- Acute Tox. 4 * H302 GHS07 H302 (methoxymethyl)acetanilide Skin Sens. 1 H317 GHS09 H317 Aquatic Acute 1 H400 Wng H410 Aquatic Chronic 1 H410

616-016-00-1 1-(3,4-dichlorophenylimino) — 5836-73-7 Acute Tox. 2 * H300 GHS06 H300 thiosemicarbazide Dgr

616-017-00-7 cartap hydrochloride 239-309-2 15263-52-2 Acute Tox. 4 * H312 GHS07 H312

Acute Tox. 4 * H302 GHS09 H302 Aquatic Acute 1 H400 Wng H410 Aquatic Chronic 1 H410

533

D050725/02

Classification Labelling Specific Conc. Limits, M-factors Notes

Index No International Chemical Identification EC No CAS No

Hazard Class and Category Hazard Pictogram, Signal Hazard Suppl. Hazard

Code(s) Statement statement Code(s) Word Code(s) statement Code(s) Code(s)

616-018-00-2 N,N-diethyl-m-toluamide; 205-149-7 134-62-3 Acute Tox. 4 * H302 GHS07 H302 deet Eye Irrit. 2 H319 Wng H319 Skin Irrit. 2 H315 H315 Aquatic Chronic 3 H412 H412

616-019-00-8 perfluidone (ISO); 253-718-3 37924-13-3 Acute Tox. 4 * H302 GHS07 H302

1,1,1-trifluoro-N-(4-phenylsulphonyl Eye Irrit. 2 H319 Wng H319 o-tolyl)methanesulphonamide;

616-020-00-3 tebuthiuron (ISO); 251-793-7 34014-18-1 Acute Tox. 4 * H302 GHS07 H302

1-(5-tert-butyl-1,3,4-thiadiazol-2-yl)- Aquatic Acute 1 H400 GHS09 H410 1,3-dimethylurea Aquatic Chronic 1 H410 Wng

616-021-00-9 thiazafluron (ISO); 246-901-4 25366-23-8 Acute Tox. 4 * H302 GHS07 H302

1,3-dimethyl-1-(5-trifluoromethyl Aquatic Acute 1 H400 GHS09 H410 1,3,4-thiadiazol-2-yl)urea Aquatic Chronic 1 H410 Wng

616-022-00-4 acetamide 200-473-5 60-35-5 Carc. 2 H351 GHS08 H351

Wng

616-023-00-X N-hexadecyl(or octadecyl)-N- 401-980-6 — Skin Irrit. 2 H315 GHS07 H315 hexadecyl (or octadecyl)benzamide Skin Sens. 1 H317 Wng H317

616-024-00-5 2-(4,4-dimethyl-2,5-dioxooxazolidin-1- 402-260-4 54942-74-4 Aquatic Chronic 4 H413 — H413 yl)-2-chloro-5-(2-(2,4-di-tert-

pentylphenoxy)butyramido)-4,4- dimethyl-3-oxovaleranilide

616-025-00-0 valinamide 402-840-7 20108-78-5 Repr. 2 H361f *** GHS08 H361f ***

Eye Irrit. 2 H319 Wng H319 Skin Sens. 1 H317 H317

616-026-00-6 thioacetamide 200-541-4 62-55-5 Carc. 1B H350 GHS08 H350

Acute Tox. 4 * H302 GHS07 H302 Eye Irrit. 2 H319 Dgr H319 Skin Irrit. 2 H315 H315 Aquatic Chronic 3 H412 H412

534

D050725/02

Classification Labelling Specific Conc. Limits, M-factors Notes